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    Image forming method
    1.
    发明授权
    Image forming method 失效
    图像形成方法

    公开(公告)号：US5736293A

    公开(公告)日：1998-04-07

    申请号：US736205

    申请日：1996-10-25

    申请人： Hiroyuki Hirai ,  Michio Ono ,  Takashi Nakamura

    发明人： Hiroyuki Hirai ,  Michio Ono ,  Takashi Nakamura

    IPC分类号： G03C8/28 ,  G03C1/42 ,  G03C1/498 ,  G03C5/29 ,  G03C8/36 ,  G03C8/40 ,  G03C8/56 ,  G03C5/30 ,  G03C8/06

    CPC分类号： G03C8/408 ,  G03C1/49827

    摘要： An image forming method comprising the steps of: (a) superposing a heat development photosensitive material on a sheet after or simultaneously with imagewise exposing the heat development photosensitive material, wherein the photosensitive material comprises a support having thereon at least a photosensitive silver halide, a hydrophilic binder and a slightly water-soluble basic metal compound, and the sheet comprises a support having thereon at least a compound which forms a complex with the metal ion constituting the basic metal compound, a solvent for a silver halide and a physical development nucleus; and (b) heat developing the laminate in the presence of a reducing agent and water to form an image on either or both of the photosensitive material and the sheet, wherein the reducing agent comprises a 1-phenyl-3-pyrazolidone compound and a dihydroxybenzene compound having an inorganic value of not less than 215 and an organic value of from 120 to 400.

    摘要翻译： 一种图像形成方法，包括以下步骤：（a）将成像感光材料叠加在成像曝光所述显影感光材料之后或同时曝光所述热显影感光材料，其中所述感光材料包括至少具有感光卤化银的支撑体， 亲水性粘合剂和轻微水溶性碱性金属化合物，并且该片材包含其上至少具有与构成碱性金属化合物的金属离子形成络合物的化合物，卤化银溶剂和物理显影核的载体; 和（b）在还原剂和水的存在下对层压体进行热显影，以在感光材料和片材之一或两者上形成图像，其中还原剂包括1-苯基-3-吡唑烷酮化合物和二羟基苯 化合物，其无机值不小于215，有机值为120-400。

    Peel apart diffusion transfer compound film unit with crosslinkable layer and borate
    2.
    发明授权
    Peel apart diffusion transfer compound film unit with crosslinkable layer and borate 失效
    剥离扩散转移复合膜单元与交联层和硼酸盐

    公开(公告)号：US5593809A

    公开(公告)日：1997-01-14

    申请号：US568964

    申请日：1995-12-07

    申请人： Gia Y. Kim ,  Lloyd D. Taylor ,  Kenneth C. Waterman

    发明人： Gia Y. Kim ,  Lloyd D. Taylor ,  Kenneth C. Waterman

    IPC分类号： G03C8/36 ,  G03C8/24 ,  G03C8/32 ,  G03C8/50 ,  G03C8/52 ,  G03C8/26 ,  G03C8/28 ,  G03C8/56

    CPC分类号： G03C8/52

    摘要： There are described a diffusion transfer photographic film unit of the type wherein an image-receiving element is designed to be separated from a photosensitive element after photoexposure and processing and a photographic process which utilizes the film unit. The photographic film unit comprises a photosensitive element including a support carrying at least one silver halide emulsion, an image-receiving element comprising a support, an image-receiving layer and, optionally, an overcoat layer and/or a strip-coat layer. At least one of the image-receiving layer, overcoat layer or strip-coat layer includes a "crosslinkable material" which is crosslinked during processing. The film unit further includes means for providing an aqueous alkaline processing composition to the photosensitive element and the image-receiving element for developing an image. The aqueous alkaline processing composition includes a borate compound for crosslinking the crosslinkable material of the image-receiving element during processing.

    摘要翻译： 描述了这种类型的扩散转印照相胶片单元，其中图像接收元件设计成在曝光和处理之后与感光元件分离，以及利用胶片单元的照相处理。 摄影胶片单元包括一个感光元件，它包括载有至少一种卤化银乳剂的载体，包含载体的图像接收元件，图像接收层，以及任选的外涂层和/或带状涂层。 图像接收层，外涂层或带状涂层中的至少一个包括在加工过程中交联的“可交联材料”。 膜单元还包括用于向感光元件提供水性碱性处理组合物的装置和用于显影图像的图像接收元件。 含水碱性处理组合物包括用于在加工期间交联图像接收元件的可交联材料的硼酸盐化合物。

    Photographic image forming process utilizing a barrier layer for diffusible dye containment
    3.
    发明授权
    Photographic image forming process utilizing a barrier layer for diffusible dye containment 失效
    用于扩散染料容纳的阻挡层的照相成像方法

    公开(公告)号：US5441854A

    公开(公告)日：1995-08-15

    申请号：US276294

    申请日：1994-07-18

    申请人： John Texter ,  Wayne A. Bowman ,  Glenn T. Pearce

    发明人： John Texter ,  Wayne A. Bowman ,  Glenn T. Pearce

    IPC分类号： G03C8/00 ,  G03C8/44 ,  G03C8/52 ,  G03C8/10 ,  G03C8/20 ,  G03C8/32 ,  G03C8/56

    CPC分类号： G03C8/44 ,  G03C8/52 ,  Y10S430/14

    摘要： A process is disclosed for forming a color photographic image comprising the steps of:(a) providing an integral element comprising one and only one dimensionally stable layer comprising a reflection base or transparent base coating support, and coated thereon in reactive association an imaging layer comprising radiation sensitive silver halide, a diffusible dye forming layer comprising a diffusible dye forming compound, and a barrier layer overlaying said diffusible dye forming layer;(b) exposing this integral element to actinic radiation(c) processing this integral element by contacting this element to an external bath containing compounds selected from the group consisting of color developer compounds, compounds which activate the release of incorporated color developers, and compounds which activate development by incorporated dye developers; and(d) washing this integral element to remove compounds imbibed in step (c). The diffusible dye forming layer is the same or different than the imaging layer. The barrier layer comprises a polymer that allows the passage of solutions for processing this integral element when this element is contacted with an external processing bath. This barrier layer impedes the diffusion of the diffusible dye formed from the diffusible-dye forming compound out of this integral element.

    摘要翻译： 公开了一种用于形成彩色摄影图像的方法，其包括以下步骤：（a）提供包括一个且仅一维尺寸稳定的层的整体元件，其包含反射基底或透明基底涂层支撑体，并且以反应性缔合的方式涂覆在其上，成像层包括 辐射敏感卤化银，包含可扩散染料形成化合物的可扩散染料形成层和覆盖所述可扩散染料形成层的阻挡层; （b）将该积分元件暴露于光化辐射（c）通过使该元件与包含选自以下的化合物的外部浴接触来处理该积分元素：彩色显影剂化合物，激活掺入的显色剂的释放的化合物，以及化合物 通过合并染料开发商激活发展; 和（d）洗涤该积分元素以除去步骤（c）中所吸收的化合物。 可扩散染料形成层与成像层相同或不同。 阻挡层包括聚合物，当该元件与外部处理槽接触时，该聚合物允许通过用于处理该整体元件的溶液。 该阻挡层妨碍由可扩散染料形成化合物形成的可扩散染料从该整体元件扩散。

    Polymeric phosphonium mordant and photographic element containing the same
    5.
    发明授权
    Polymeric phosphonium mordant and photographic element containing the same 失效
    聚合物絮凝剂和含有它们的摄影元素

    公开(公告)号：US4855211A

    公开(公告)日：1989-08-08

    申请号：US228173

    申请日：1988-08-04

    申请人： Wilhelmus Janssens ,  Daniel M. Timmerman ,  Daniel A. Claeys

    发明人： Wilhelmus Janssens ,  Daniel M. Timmerman ,  Daniel A. Claeys

    IPC分类号： C08F212/14 ,  C07F9/54 ,  C08F12/00 ,  C08F30/02 ,  C08F230/02 ,  G03C8/56

    CPC分类号： G03C8/56 ,  C07F9/5456 ,  C08F30/02 ,  Y10S430/142 ,  Y10S525/916

    摘要： Phosphonium mordanting polymer, that is capable of fixing acid dyes and that comprises randomly distributed recurring units corresponding to the general formula (I) ##STR1## wherein: A represents a unit that is derived from a copolymerizable monomer capable of quenching singlet oxygen e.g. N-vinylimidazole or 2-methyl-1-vinylimidazole;B represents a unit that is derived from a copolymerizable monomer having a hydrophobic character e.g. acrylonitrile or methacrylonitrile;n represents an integer of from 1 to about 12;each of R.sub.1, R.sub.2 and R.sub.3 (same or different) represents a C.sub.1 -C.sub.8 alkyl group e.g. n-butyl, a substituted C.sub.1 -C.sub.8 alkyl group e.g. a methylol group, a cyanoethyl group or an aralkyl group, a cycloalkyl group, an aryl group e.g. phenyl, or a substituted aryl group;X.sup.- represents an acid anion e.g. a halogen anion e.g. Cl.sup.-, Br.sup.- or I.sup.-, or an anion derived from an inorganic acid e.g. NO.sub.3.sup.-, HSO.sub.4.sup.-, SO.sub.4.sup.--, H.sub.2 PO.sub.4.sup.-, HPO.sub.4.sup.-- or PO.sub.4.sup.---;x represents from about 5 mole % to about 80 mole %;y represents from about 20 mole % to about 95 mole % andz represents from about 0 mole % to about 65 mole %.

    摘要翻译： 鏻媒染聚合物，其能够固定酸性染料并且包含对应于通式（I）的无规分布的重复单元其中：A表示衍生自能够淬灭单线态氧的可共聚单体的单元 例如 N-乙烯基咪唑或2-甲基-1-乙烯基咪唑; B表示衍生自具有疏水性的可共聚单体的单元， 丙烯腈或甲基丙烯腈; n表示1〜12的整数， R 1，R 2和R 3（相同或不同）各自表示C 1 -C 8烷基。 正丁基，取代的C 1 -C 8烷基，例如 羟甲基，氰乙基或芳烷基，环烷基，芳基例如。 苯基或取代的芳基; X-表示酸性阴离子例如 卤素阴离子 Cl-，Br-或I-，或衍生自无机酸的阴离子例如。 NO331，HSO4-，SO4-，H 2 PO 4 - ，HPO 4 - 或PO 4 - ; x表示约5摩尔％至约80摩尔％; y表示约20摩尔％至约95摩尔％，z表示约0摩尔％至约65摩尔％。

    Photographic element with polymeric imidazole dye mordant
    6.
    发明授权
    Photographic element with polymeric imidazole dye mordant 失效
    具有聚合咪唑染料媒染剂的摄影元件

    公开(公告)号：US4766052A

    公开(公告)日：1988-08-23

    申请号：US86245

    申请日：1987-08-17

    申请人： Taku Nakamura ,  Koichi Nakamura ,  Hiroshi Hayashi

    发明人： Taku Nakamura ,  Koichi Nakamura ,  Hiroshi Hayashi

    IPC分类号： C08F16/00 ,  C08F16/16 ,  C08F18/00 ,  C08F26/00 ,  C08F26/06 ,  C08F212/14 ,  C08F216/16 ,  C08F218/00 ,  C08F218/02 ,  C08F218/04 ,  C08F226/02 ,  C08F226/06 ,  G03C1/825 ,  G03C7/00 ,  G03C8/56 ,  G03C5/54

    CPC分类号： C08F212/14 ,  C08F226/06 ,  G03C8/56 ,  Y10S430/142

    摘要： A photographic element containing a polymer comprising a recurring unit of general formula (I) and at least one recurring unit selected from the group of units of general formulae (II), (III) and IV) ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 each represents a hydrogen atom or an alkyl group of 1 to 6 carbon atoms; L represents a divalent linking group of 1 to 20 carbon atoms; and m is 0 or 1; ##STR2## wherein R.sub.1a represents a hydrogen atom or an alkyl group of 1 to 6 carbon atoms; R.sub.4 is an alkyl group, an aryl group or an aralkyl group; and n is 0 or 1; ##STR3## wherein R.sub.1a is as defined in general formula (II); R.sub.5 and R.sub.6 each represents a hydrogen atom or an alkyl group, an alkoxy group, an aryl group or an aralkyl group; and p and q each is equal to 0 or 1; and ##STR4## wherein R.sub.1a is as defined in general formula (II); and D is a divalent linking group necessary for the formation of a 5- to 7-membered ring with the nitrogen atom and carbonyl group.

    摘要翻译： 含有包含通式（I）的重复单元的聚合物和选自通式（II），（III）和IV）的单元的至少一个重复单元的照相元件。其中R1， R2和R3各自表示氢原子或1〜6个碳原子的烷基; L表示1〜20个碳原子的二价连接基团; m为0或1; （II）其中R 1a表示氢原子或1至6个碳原子的烷基; R4是烷基，芳基或芳烷基; 并且n为0或1; （III）其中R1a如通式（II）中所定义; R5和R6各自表示氢原子或烷基，烷氧基，芳基或芳烷基; 并且p和q各自等于0或1; （IV）其中R 1a如通式（II）中所定义; D是与氮原子和羰基形成5-至7-元环所必需的二价连接基团。

    Copolymeric mordants and photographic products and processes containing same
    7.
    发明授权
    Copolymeric mordants and photographic products and processes containing same 失效
    共聚媒染剂和含有它们的摄影产品和方法

    公开(公告)号：US4563411A

    公开(公告)日：1986-01-07

    申请号：US641766

    申请日：1984-08-17

    申请人： Irena Y. Bronstein-Bonte

    发明人： Irena Y. Bronstein-Bonte

    IPC分类号： G03C8/56 ,  G03C1/40 ,  G03C5/54

    CPC分类号： G03C8/56 ,  Y10S430/142 ,  Y10T428/31855 ,  Y10T428/31935

    摘要： Copolymeric mordant materials containing recurring units according to the following formula are disclosed: ##STR1## In such copolymers, each of R.sup.1, R.sup.2 and R.sup.3 can independently be alkyl; substituted-alkyl; cycloalkyl; aryl; aralkyl; alkaryl; or at least two of R.sup.1, R.sup.2 and R.sup.3, together with the quaternary nitrogen atom to which they are bonded, can complete a saturated or unsaturated, substituted or unsubstituted nitrogen-containing heterocyclic ring; X is an anion; each R.sup.4 is alkyl of from 1 to 6 carbon atoms; R.sup.5 is a divalent alkylene of from 1 to 8 carbon atoms; R.sup.6 is hydrogen, amino, phenyl or alkyl of from 1 to 4 carbon atoms; R.sup.7 is hydrogen or methyl; and m is an integer 1 or 2. The molar ratio of a:b can range from about 0.1:1 to about 10:1, e.g., about 0.3:1 to about 3:1.The copolymeric mordant materials can be utilized as image-receiving layers in photographic products and processes of the diffusion transfer type. The mordants are especially adapted to the production of dye images exhibiting favorable maximum density (D.sub.max) and rates of dye transfer properties.

    摘要翻译： 公开了含有根据下式的重复单元的共聚媒染材料：在这种共聚物中，R 1，R 2和R 3中的每一个可以独立地为烷基; 取代烷基; 环烷基 芳基; 芳烷基 烷芳基 或R 1，R 2和R 3中的至少两个与它们所键合的季氮原子一起可以完成饱和或不饱和的，取代或未取代的含氮杂环; X是阴离子; 每个R 4是具有1至6个碳原子的烷基; R5是1至8个碳原子的二价亚烷基; R6是氢，氨基，苯基或具有1至4个碳原子的烷基; R7是氢或甲基; 且m为1或2的整数.a：b的摩尔比范围为约0.1:1至约10:1，例如约0.3:1至约3:1。 共聚媒染材料可用作照相产品中的图像接收层和扩散转移型的方法。 媒染剂特别适用于生产显示有利的最大密度（Dmax）和染料转移性能的染料图像。

    Image-receiving element for the dye diffusion transfer process with metal complex of diazabicyclooctane
    8.
    发明授权
    Image-receiving element for the dye diffusion transfer process with metal complex of diazabicyclooctane 失效
    用二氮杂双环辛烷的金属络合物进行染料扩散转移过程的图像接收元件

    公开(公告)号：US4383021A

    公开(公告)日：1983-05-10

    申请号：US347510

    申请日：1982-02-10

    申请人： Peter Bergthaller ,  Guenter Helling ,  Jurgen Strauss

    发明人： Peter Bergthaller ,  Guenter Helling ,  Jurgen Strauss

    IPC分类号： G03C8/56 ,  G03C8/08 ,  G03C8/24 ,  G03C1/40 ,  G03C1/10 ,  G03C5/54

    CPC分类号： G03C8/246 ,  G03C8/08 ,  Y10S430/142

    摘要： Nickel complexes of diazabicyclooctane derivatives of one of the following formulae I and II are useful metallizing agents for the formation of metal complexed image dyes in image receiving elements for the dye diffusion transfer process ##STR1## In these formulae R.sup.1 represents an n-functional aliphatic hydrocarbon radical optionally containing carbocyclic or heterocyclic groups, carbonyl groups, sulphonyl groups and/or heteroatoms (O, S, N) as intermediate members;R.sup.2 and R.sup.3 represent hydrogen or alkyl;A.sup..crclbar. represents an anion; andn represents a number of from 1 to 5.

    摘要翻译： 下式I和II之一的二氮杂双环辛烷衍生物的镍络合物是用于在用于染料扩散转移过程的图像接收元件中形成金属络合的图像染料的有用的金属化剂。在这些式中，R 1表示n官能脂族烃 任选地含有碳环或杂环基团的羰基，羰基，磺酰基和/或杂原子（O，S，N）作为中间成员; R2和R3代表氢或烷基; A（ - ）表示阴离子; n表示1〜5的数。