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    Process for the manufacture of paper or cardboard which is sized under alkaline or neutral conditions with anionic hydrophobic sizing agents and cationic retention aids
    86.
    发明授权
    Process for the manufacture of paper or cardboard which is sized under alkaline or neutral conditions with anionic hydrophobic sizing agents and cationic retention aids 失效
    在碱性或中性条件下用阴离子疏水施胶剂和阳离子助留剂制造纸或纸板的方法

    公开(公告)号：US4737239A

    公开(公告)日：1988-04-12

    申请号：US773708

    申请日：1985-09-09

    申请人： Michael Bernheim ,  Hubert Meindl ,  Peter Rohringer

    发明人： Michael Bernheim ,  Hubert Meindl ,  Peter Rohringer

    IPC分类号： C07C233/05 ,  C07C233/09 ,  C07C233/65 ,  C07C235/06 ,  D21H17/03 ,  D21H17/07 ,  D21H17/56 ,  D21H3/08

    CPC分类号： D21H17/07

    摘要： Sizing agents devoid of anhydride groups, some of which are known and others are novel compounds, and which carry a single N,N-C.sub.6 -C.sub.22 alkyl(or alkenyl)amide group as hydrophobic substituent and at least one anionic group, in particular N,N-C.sub.6 -C.sub.22 dialkyl or N,N-C.sub.6 -C.sub.22 dialkenyl partial amides of a dicarboxylic acid, tricarboxylic acid or sulfocarboxylic acid, or the salts thereof, are particularly suitable, together with commercially available retention aids, for use in a process for pulp-sizing paper or cardboard at a pH of at least 6.5 of the fibre suspension, in the absence of e.g. aluminium sulfate, or in a process for surface-sizing paper.

    摘要翻译： 不含酸酐基团的上浆剂，其中一些是已知的，其它的是新型化合物，并且其具有单个N，N-C 6 -C 22烷基（或烯基）酰胺基团作为疏水性取代基和至少一个阴离子基团，特别是N， 二羧酸，三羧酸或磺基羧酸的N-C6-C22二烷基或N，N-C6-C22二烯基部分酰胺或其盐特别适用于市售的助留剂，用于纸浆 - 在不存在例如纤维悬浮液的至少6.5的pH下调节纸或纸板 硫酸铝，或在表面上光纸的过程中。

    Organic-inorganic composites of neutralized polyelectrolyte complexes
    89.
    发明授权
    Organic-inorganic composites of neutralized polyelectrolyte complexes 失效
    中和聚电解质复合物的有机 - 无机复合材料

    公开(公告)号：US4455382A

    公开(公告)日：1984-06-19

    申请号：US461672

    申请日：1983-01-27

    申请人： Shy-Hsien Wu

    发明人： Shy-Hsien Wu

    IPC分类号： C09K3/00 ,  B05D5/12 ,  B32B7/02 ,  C03C10/16 ,  C03C17/28 ,  C04B14/20 ,  C04B30/00 ,  C08F8/00 ,  C09D201/00 ,  D01F9/08 ,  D21H13/00 ,  D21H13/44 ,  D21H17/03 ,  D21H17/63 ,  D21H17/67 ,  D21H19/00 ,  H01B3/30 ,  C03C3/22 ,  C09C1/02

    CPC分类号： C04B30/00 ,  C03C10/16 ,  C04B14/208 ,  D21H13/44 ,  Y10S106/03 ,  Y10T428/2911

    摘要： This invention is directed to the preparation of neutralized polyelectrolyte complexes exhibiting hydrophobic behavior containing crystals of an organic polycation exchanged lithium and/or sodium water-swelling mica. The process for making such products comprises:(1) forming a glass-ceramic body containing crystals selected from the group of fluorhectorite, hydroxyl hectorite, boron fluorphlogopite, hydroxyl boron phlogopite, and solid solutions among those and between those and other structurally-compatible species selected from the group of talc, fluortalc, polylithionite, fluorpolylithionite, phlogopite, and fluorphlogopite;(2) contacting that body with a polar liquid to cause swelling and disintegration of the body accompanied with the formation of a gel; and(3) contacting said gel with a source of organic polycations to cause a reaction between the Li.sup.+ and/or Na.sup.+ ions from the interlayer of the crystals and to neutralize the charge density of the crystals, thereby forming neutralized polyelectrolyte complex, said organic polycations being selected from the group of(a) a primary amine solubilized with acid,(b) a secondary amine solubilized with acid,(c) a tertiary amine solubilized with acid,(d) a quaternary ammonium acid salt,(e) a quaternary phosphonium acid salt, and(f) a ternary sulfonium acid salt.

    摘要翻译： 本发明涉及制备含有有机聚阳离子交换的锂和/或钠水溶性云母的晶体的疏水行为的中和聚电解质络合物。 制造这种产品的方法包括：（1）形成包含选自氟代锂蒙脱石，羟基锂蒙脱石，氟氟云母，羟基硼金云母的晶体的玻璃陶瓷体，以及那些和其它结构相容的物质之间的固溶体 选自滑石粉，氟软脂，聚连硫石，氟磷酸亚铁锂，金云母和氟云母; （2）使该身体与极性液体接触，引起伴随凝胶形成的身体的肿胀和分解; 和（3）使所述凝胶与有机聚阳离子源接触以引起来自晶体中间层的Li +和/或Na +离子之间的反应并中和晶体的电荷密度，从而形成中和的聚电解质络合物，所述有机聚阳离子 选自（a）用酸溶解的伯胺，（b）用酸溶解的仲胺，（c）用酸溶解的叔胺，（d）季铵盐，（e）季铵盐 鏻酸盐，和（f）三元锍酸盐。