WATER-MEDIATED PREPARATIONS OF POLYMERIC MATERIALS
    81.
    发明申请
    WATER-MEDIATED PREPARATIONS OF POLYMERIC MATERIALS 有权
    聚合材料的水介导制备

    公开(公告)号:US20150344618A1

    公开(公告)日:2015-12-03

    申请号:US14725654

    申请日:2015-05-29

    Abstract: A process is provided for preparing a polymeric material through a water-mediated polymerization process that includes combining an alcohol monomer and an aqueous solution in a vessel, adding an acid monomer to the vessel, removing water from the vessel and producing the polymeric material from the vessel, wherein the polymeric material comprises a polyester of the alcohol monomer and the acid monomer. The methods described herein are particularly suitable for polymerization of poly(glycerol sebacate).

    Abstract translation: 提供了一种通过水介导的聚合方法制备聚合材料的方法,其包括将醇单体和水溶液组合在容器中,向容器中加入酸单体,从容器中除去水并从 容器,其中聚合物材料包含醇单体和酸单体的聚酯。 本文所述的方法特别适用于聚(甘油癸二酸酯)的聚合。

    Method for manufacturing biodegradable copolymer by split-injecting aromatic dicarboxylic acid compound
    82.
    发明授权
    Method for manufacturing biodegradable copolymer by split-injecting aromatic dicarboxylic acid compound 有权
    通过分散注入芳族二羧酸化合物制造可生物降解的共聚物的方法

    公开(公告)号:US09187595B2

    公开(公告)日:2015-11-17

    申请号:US14402516

    申请日:2013-05-13

    CPC classification number: C08G63/183 C08G63/12 C08G63/181 C08G63/78

    Abstract: There is provided a method of preparation for a biodegradable co-polyester, the method including: forming an oligomer through a primary esterification reaction between a hydroxy group of an aliphatic dihydroxy compound and a carboxylic group of an aliphatic dicarboxylic acid compound; performing a secondary esterification reaction between the formed oligomer and an aromatic dicarboxylic acid compound; and performing a polycondensation reaction in a vacuum, in which sequentially divided addition of the aromatic dicarboxylic acid compound is performed and the weight ratio of the aromatic dicarboxylic acid compound with respect to the oligomer for each time of the sequentially divided addition is from 2:8 to 5:5. The method efficiently increases a solubility of aromatic dicarboxylic acid, thereby increasing a reaction rate and reducing a side reaction.

    Abstract translation: 提供了一种可生物降解的共聚酯的制备方法,其包括:通过脂肪族二羟基化合物的羟基与脂肪族二羧酸化合物的羧基之间的一次酯化反应形成低聚物; 在形成的低聚物和芳族二羧酸化合物之间进行二次酯化反应; 在真空中进行缩聚反应,其中进行依次分配的芳族二羧酸化合物的添加,并且芳香族二羧酸化合物相对于低聚物的重量比分别为2:8 至5:5。 该方法有效地提高芳族二羧酸的溶解度,从而提高反应速度并减少副反应。

    Complex polyol polyesters
    84.
    发明申请
    Complex polyol polyesters 审中-公开
    复合多元醇多酯

    公开(公告)号:US20150196479A1

    公开(公告)日:2015-07-16

    申请号:US13999068

    申请日:2014-01-10

    Abstract: The present invention is directed to a series of polyesters that are made by the reaction of a diacid with a pre-formed mono-hydroxy, di-hydroxy and optionally a tri-hydroxy ester of polyols selected from pentaerythritol, dipentearythritol trimethylolpropane and mixtures thereof. When reacted in the sequence shown, that is pre-formation of the mono-ester, di-ester and tri-ester, selection of the proper ratio of one to the other and then and only then reacted with the diacid, do these polyesters remain free of a gel and form cosmetically elegant oil phases.

    Abstract translation: 本发明涉及一系列聚酯,其通过二酸与预先形成的单羟基,二羟基和任选的选自季戊四醇,二戊二醇三羟甲基丙烷和其混合物的多元醇的三羟基酯的反应制备。 当按照所示序列进行反应时,即单酯,二酯和三酯的预形成,选择适当的比例,然后再与二酸反应,这些聚酯是否保留 没有凝胶,并形成美丽优雅的油相。

    PRESSURE-SENSITIVE ADHESIVE COMPOSITION AND PRESSURE-SENSITIVE ADHESIVE SHEET
    87.
    发明申请
    PRESSURE-SENSITIVE ADHESIVE COMPOSITION AND PRESSURE-SENSITIVE ADHESIVE SHEET 有权
    压敏胶粘组合物和压敏粘合片

    公开(公告)号:US20150050493A1

    公开(公告)日:2015-02-19

    申请号:US14385194

    申请日:2013-03-07

    Abstract: Provided are: a polyester-based pressure-sensitive adhesive composition which can be produced even from plant-derived raw materials with no need of using a costly silicone-based pressure-sensitive adhesive or the like and which is usable for producing a pressure-sensitive adhesive sheet excellent in wettability to an adherend, light peelability (removability), anti-staining property (little adhesive residues), and workability, and to provide a pressure-sensitive adhesive sheet using the composition. A polyester-based pressure-sensitive adhesive composition comprising a polyester obtained by condensation polymerization of at least a carboxylic acid component and a diol component, and a crosslinking agent, wherein the carboxylic acid component contains a dicarboxylic acid having a side chain in an amount of 50 to 90% by weight and a tricarboxylic acid having a side chain in an amount of 10 to 50% by weight, and wherein the polyester has a weight average molecular weight of 5000 to 150000.

    Abstract translation: 本发明提供:即使不需要使用昂贵的硅氧烷系粘合剂等也可以从植物性原料制造的聚酯系粘合剂组合物,可用于制造压敏粘合剂 对被粘物的润湿性,耐光剥离性(可除去性),抗污染性(少量粘合剂残留)和加工性优异的粘合片,以及提供使用该组合物的压敏粘合片。 一种聚酯类压敏粘合剂组合物,其包含通过至少一种羧酸组分和二醇组分的缩聚获得的聚酯和一种交联剂,其中所述羧酸组分含有侧链的二羧酸量为 50〜90重量%,侧链的三羧酸的量为10〜50重量%,其中,所述聚酯的重均分子量为5000〜150000。

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