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    Method of preparing carboxylic acid functionalized polymers
    71.
    发明申请
    Method of preparing carboxylic acid functionalized polymers 审中-公开
    制备羧酸官能化聚合物的方法

    公开(公告)号：US20050214250A1

    公开(公告)日：2005-09-29

    申请号：US10982303

    申请日：2004-11-04

    Applicant: J. Harris ,  Antoni Kozlowski ,  Lihong Guo

    Inventor： J. Harris ,  Antoni Kozlowski ,  Lihong Guo

    IPC: A61K31/765 ,  C08F8/00 ,  C08F251/00 ,  C08F261/04 ,  C08F265/00 ,  C08F271/00 ,  C08F283/06 ,  C08F283/10 ,  C08F289/00 ,  C08F291/00 ,  C08G65/30 ,  C08G65/332

    CPC classification number: C08G63/91 ,  A61K31/765 ,  C08F251/00 ,  C08F261/04 ,  C08F265/00 ,  C08F271/00 ,  C08F283/06 ,  C08F289/00 ,  C08F291/00 ,  C08G65/30 ,  C08G65/332 ,  C08G65/3322 ,  C08G65/3346

    Abstract: Methods for preparing water soluble, non-peptidic polymers carrying carboxyl functional groups, particularly carboxylic acid functionalized poly(ethylene glycol) (PEG) polymers, are disclosed, as are the products of these methods. In general, an ester reagent R(C═O)OR′, where R′ is a tertiary group and R comprises a functional group X, is reacted with a water soluble, non-peptidic polymer POLY-Y, where Y is a functional group which reacts with X to form a covalent bond, to form a tertiary ester of the polymer, which is then treated with a strong base in aqueous solution, to form a carboxylate salt of the polymer. Typically, this carboxylate salt is then treated with an inorganic acid in aqueous solution, to convert the carboxylate salt to a carboxylic acid, thereby forming a carboxylic acid functionalized polymer.

    Abstract translation: 公开了用于制备携带羧基官能团的水溶性非肽聚合物，特别是羧酸官能化聚（乙二醇）（PEG）聚合物）的方法，以及这些方法的产物。 通常，其中R'是叔基并且R包含官能团X的酯试剂R（CO）OR'与水溶性非肽聚合物POLY-Y反应，其中Y是官能团， 与X反应形成共价键，形成聚合物的叔酯，然后用强碱在水溶液中处理，形成聚合物的羧酸盐。 通常，该羧酸盐然后用水溶液中的无机酸处理，以将羧酸盐转化为羧酸，从而形成羧酸官能化聚合物。

    Selective modification of pendent functionalities of polymers
    72.
    发明授权
    Selective modification of pendent functionalities of polymers 失效
    聚合物悬挂功能的选择性修饰

    公开(公告)号：US06916868B2

    公开(公告)日：2005-07-12

    申请号：US10350202

    申请日：2003-01-23

    Applicant: John Kemnitzer ,  George Brode ,  Robert Minasyan ,  Timothy Malaney

    Inventor： John Kemnitzer ,  George Brode ,  Robert Minasyan ,  Timothy Malaney

    IPC: C08G63/91 ,  C08G64/42 ,  C08G85/00

    CPC classification number: C08G64/42 ,  C08G63/91 ,  C08G85/004

    Abstract: A process for selectively modifying pendent functionalities of a polymer containing the pendent functionalities and hydrolytically unstable backbone functionalities is provided. The process includes: (a) providing the polymer in a solvent system (preferably an ether-containing solvent system) adapted to maintain the polymer in a dissolved or partially dissolved state, wherein the pendent functionalities of the polymer are more accessible than the hydrolytically unstable backbone functionalities; and (b) adding at least one additive to the solvent system to selectively modify at least one of the pendent functionalities. The process is especially well suited for specifically acid hydrolyzing pendent esters of PDTE.

    Abstract translation: 提供了选择性地修饰含有侧链官能团和水解不稳定的骨架官能团的聚合物的侧挂功能的方法。 该方法包括：（a）将聚合物提供在适于维持聚合物处于溶解或部分溶解状态的溶剂系统（优选含醚溶剂体系）中，其中聚合物的侧悬官能团比水解不稳定 骨干功能; 和（b）向所述溶剂体系中加入至少一种添加剂以选择性地修饰至少一种侧挂官能团。 该方法特别适用于PDTE的具体酸性水解侧链酯。

    Method of treating polyester polymer and polyester polymer reduced in low-boiling component content
    73.
    发明申请
    Method of treating polyester polymer and polyester polymer reduced in low-boiling component content 审中-公开
    处理聚酯聚合物和聚酯聚合物的方法降低了低沸点组分含量

    公开(公告)号：US20050075464A1

    公开(公告)日：2005-04-07

    申请号：US10500275

    申请日：2003-01-08

    Applicant: Jun Watanabe

    Inventor： Jun Watanabe

    IPC: C08G63/08 ,  C08G63/60 ,  C08G63/80 ,  C08G63/90 ,  C08G63/91 ,  C08L101/16 ,  C08G63/88

    CPC classification number: C08G63/80 ,  B29C48/022 ,  B29C48/04 ,  B29C48/05 ,  B29C48/287 ,  C08G63/08 ,  C08G63/60 ,  C08G63/90 ,  C08G63/91

    Abstract: A method for treating a polyester polymer according to the present invention is to heat a polyester polymer (C), which is obtained by ring-opening polymerization of a polymer (A) having hydroxyl and/or ester bonds and cyclic esters (B) containing ε-caprolactone, in a solid state at a temperature that is not lower than 115° C. and lower than 170° C. and is lower than the melting point of the polyester polymer (C) in order to remove an organic low-boiling component (v) from the polymer (C) obtained by the polymerization. According to the present invention, there is obtained a polyester polymer in which ε-caprolactone and caprolactone dimer in polyester polymers are fully removed without causing deterioration or change of the physical properties of resins and further without causing deterioration of their colors and a decrease in cost effectiveness.

    Abstract translation: 根据本发明的聚酯聚合物的处理方法是加热通过具有羟基和/或酯键的聚合物（A）的开环聚合得到的聚酯聚合物（C）和含有 ε-己内酯，在不​​低于115℃且低于170℃的温度下处于固态，并且低于聚酯聚合物（C）的熔点以除去有机低沸点 组分（v）由聚合物（C）获得。 根据本发明，得到聚酯聚合物中的ε-己内酯和己内酯二聚体被完全除去而不会引起树脂的物理性能的劣化或变化而进一步降低其颜色和降低成本的聚酯聚合物 有效性

    Biodegradable recycled polyester resin and production process therefor
    75.
    发明授权
    Biodegradable recycled polyester resin and production process therefor 失效
    可生物降解的回收聚酯树脂及其生产工艺

    公开(公告)号：US06730709B2

    公开(公告)日：2004-05-04

    申请号：US09864813

    申请日：2001-05-24

    Applicant: Hiroshi Itoh ,  Kazumi Fujioka

    Inventor： Hiroshi Itoh ,  Kazumi Fujioka

    IPC: C08J1104

    CPC classification number: C08G63/91 ,  C08G63/16 ,  C08G81/00

    Abstract: The present invention provides a biodegradable recycled polyester resin and a production process therefor, wherein the polyester resin is inexpensive and economical due to use of recycled aromatic polyesters, and further, can solve problems of wastes by affording biodegradability to the aromatic polyester which has so far been assumed to have no biodegradability. The biodegradable recycled polyester resin, according to the present invention, is obtained by a process including the step of carrying out a reaction of a recycled aromatic polyester (A) with an aliphatic polyester (B) having a number-average molecular weight of 3,000 to 300,000 in a reaction ratio (weight ratio) of (A)/(B)=95/5 to 5/95, thereby affording biodegradability to the recycled aromatic polyester (A).

    Abstract translation: 本发明提供一种可生物降解的再生聚酯树脂及其制造方法，其中，通过使用再循环芳族聚酯，聚酯树脂廉价且经济，并且通过向迄今为止的芳香族聚酯提供生物降解性，可以解决废物问题 被认为没有生物降解性。 根据本发明的可生物降解的再生聚酯树脂通过包括以下步骤的方法获得：将再循环的芳族聚酯（A）与数均分子量为3,000的脂肪族聚酯（B）进行反应的步骤， （A）/（B）= 95/5〜5/95的反应比（重量比）为300,000，从而为再循环芳族聚酯（A）提供生物降解性。

    Hyperbranched polyol macromolecule, method of making same, and coating composition including same
    77.
    发明授权
    Hyperbranched polyol macromolecule, method of making same, and coating composition including same 失效

    公开(公告)号：US06649705B2

    公开(公告)日：2003-11-18

    申请号：US10040819

    申请日：2002-01-07

    Applicant: Swaminathan Ramesh

    Inventor： Swaminathan Ramesh

    IPC: C08G6378

    CPC classification number: C08G83/005 ,  C08G63/123 ,  C08G63/60 ,  C08G63/91 ,  C09D167/00 ,  C09D201/005 ,  Y10S977/754 ,  C08L2666/36 ,  C08L61/04

    Abstract: A hyperbranched polyester polyol macromolecule, having a plurality of both embedded and exterior hydroxyl groups thereon, may be synthesized in a polymerization reaction having several steps. The hyperbranched polyol includes a central nucleus, a first chain extension, an intermediate substituent and a second chain extension. The central nucleus is a hydrocarbon structure with a plurality of oxygen atoms. The first chain extender is attached to the central nucleus and includes a carboxylic ester group and a plurality of hydroxyl groups. The intermediate substituent is attached to the first chain extender, and is a polyfunctional carboxylic acid or anhydride thereof. The preferred intermediate substituent is a cyclic compound. The second chain extension is attached to the intermediate substituent. The preferred second chain extension includes a glycidyl ester or epoxy. Methods of making a hyperbranched polyester polyol are also disclosed. Coating compositions in which the hyperbranched polyol is reacted with an aminoplast or with an isocyanate are also encompassed by the invention.

    Organic anti-reflective coating compositions for advanced microlithography
    79.
    发明申请
    Organic anti-reflective coating compositions for advanced microlithography 有权
    用于先进微光刻的有机抗反射涂料组合物

    公开(公告)号：US20030162125A1

    公开(公告)日：2003-08-28

    申请号：US10062790

    申请日：2002-02-01

    Inventor： Shreeram V. Deshpande

    IPC: G03C001/76

    CPC classification number: C08G59/32 ,  C08F8/14 ,  C08G59/1438 ,  C08G59/42 ,  C08G59/625 ,  C08G63/68 ,  C08G63/91 ,  C08G65/329 ,  C09D133/02 ,  C09D163/00 ,  C09D167/00 ,  C09D171/02 ,  G03F7/091 ,  Y10S430/106

    Abstract: New polymers and new anti-reflective compositions containing such polymers are provided. The compositions comprise a polymer (e.g., epoxy cresol novolac resins) bonded with a chromophore (4-hydroxybenzoic acid, trimellitic anhydride). The inventive compositions can be applied to substrates (e.g., silicon wafers) to form anti-reflective coating layers having high etch rates which minimize or prevent reflection during subsequent photoresist exposure and developing.

    Abstract translation: 提供了新的聚合物和含有这种聚合物的新的抗反射组合物。 组合物包含与发色团（4-羟基苯甲酸，偏苯三酸酐）结合的聚合物（例如环氧甲酚酚醛清漆树脂）。 本发明的组合物可以施加到基底（例如，硅晶片）以形成具有高蚀刻速率的抗反射涂层，其在随后的光致抗蚀剂曝光和显影期间最小化或防止反射。

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