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公开(公告)号：US20170190080A1
公开(公告)日：2017-07-06
申请号：US15314854
申请日：2015-05-29
申请人： BASF SE
发明人： Gerd Rischko , Jörg Pöltl , Julio Albuerne
IPC分类号： B29C44/12 , C08G18/76 , C08G18/79 , B60R13/02 , B32B5/20 , B32B27/06 , B32B27/30 , C08G18/08 , C08G18/48
CPC分类号： B29C44/12 , B29K2075/00 , B29K2105/04 , B29K2627/06 , B29L2031/3008 , B32B5/20 , B32B27/065 , B32B27/304 , B32B2250/02 , B32B2250/24 , B32B2266/0278 , B32B2307/72 , B32B2605/003 , B60R13/02 , C08G18/12 , C08G18/14 , C08G18/1808 , C08G18/1825 , C08G18/1833 , C08G18/3206 , C08G18/324 , C08G18/3281 , C08G18/4018 , C08G18/4216 , C08G18/4816 , C08G18/482 , C08G18/4837 , C08G18/5021 , C08G18/6674 , C08G18/6681 , C08G18/721 , C08G18/7657 , C08G18/7664 , C08G18/7671 , C08G18/797 , C08G2101/0016 , C08G2101/0058 , C08G2101/0066 , C08G2101/0083 , C08G18/6688 , C08G18/6622
摘要： In a process for producing a composite element having at least a covering layer and polyurethane foam, the covering layer is inserted into a mold and a polyurethane reaction mixture is introduced onto the covering layer. The polyurethane reaction mixture is reacted to form a polyurethane foam, wherein the polyurethane reaction mixture is obtained by mixing a) polyisocyanate with b) compounds having isocyanate-reactive OH groups, c) blowing agents including water, d) thickeners and e) catalysts. Bis(N,N-dimethylaminoethoxyethyl) carbamate, N,N,N-trimethyl-N-hydroxyethylbis(aminopropyl ether), N,N,N-trimethyl-N-hydroxyethyl(aminoethyl ether) or mixtures thereof and/or tetramethyldiaminoethyl ether are employed as catalysts and the polyurethane foam has a density of not more than 200 g/dm3.
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62.发明申请公开(公告)号：US20160362540A1
公开(公告)日：2016-12-15
申请号：US15245810
申请日：2016-08-24
申请人： Covestro LLC
CPC分类号： C08K7/14 , B29C47/0014 , B29C70/52 , B29C70/521 , B29C70/527 , B29K2075/00 , B29K2309/08 , C08G18/2063 , C08G18/24 , C08G18/3206 , C08G18/3281 , C08G18/3284 , C08G18/4804 , C08G18/4816 , C08G18/482 , C08G18/4829 , C08G18/751 , C08G18/758 , C08G18/7664 , C08G18/7831 , C08G18/792 , C08G18/8016 , C08J5/04 , C08J2375/04 , C08J2375/08 , C08K3/40
摘要： Clear polyurethane fiber reinforced composites are produced by a pultrusion process with a polyurethane-forming system that includes: (a) a clear, aliphatic polyisocyanate having a viscosity at 25° C. of no more than 1000 centipoise, (b) a colorless polyol component comprising an amine-initiated polyol having a molecular weight of from about 150 to about 400 and an OH functionality greater than or equal to 3, and (c) a catalyst. These fiber-reinforced composites are characterized by both excellent weathering characteristics and excellent physical properties.
摘要翻译： 透明聚氨酯纤维增强复合材料是通过具有聚氨酯形成体系的拉挤成型方法生产的，其包括：（a）在25℃下粘度不超过1000厘泊的透明脂族多异氰酸酯，（b）无色多元醇组分 包括分子量为约150至约400且OH官能度大于或等于3的胺引发的多元醇，和（c）催化剂。 这些纤维增强复合材料的特征在于优异的耐候性和优异的物理性能。
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公开(公告)号：US20160304687A1
公开(公告)日：2016-10-20
申请号：US15101183
申请日：2014-11-24
申请人： BASF SE
发明人： Iran OTERO MARTINEZ
CPC分类号： C08J9/0033 , C08G18/14 , C08G18/288 , C08G18/3281 , C08G18/482 , C08G18/4845 , C08G18/5024 , C08G18/6688 , C08G18/725 , C08G18/7664 , C08G18/797 , C08G2101/0066 , C08G2101/0083 , C08J2207/06 , C08J2375/08 , C08K5/42 , C08L75/08
摘要： The present invention relates to a process for the production of polyurethanes where (a) polyisocyanate, (b) polymeric compounds having groups reactive toward isocyanates, (c) catalysts, (d) sulfur-carbon compounds selected from the group consisting of sulfinic acid derivatives of the general formula (I) and/or sulfonic acid derivatives according to the general formula (II) where R1 and R2 can be identical or different and are respectively any desired substituted or unsubstituted hydrocarbon moiety, with the proviso that the carbon atom bonded to the sulfur atom is an aliphatic carbon atom, and optionally (e) blowing agent, (f) chain extender and/or crosslinking agent, and (g) auxiliaries and/or additives are mixed to give a reaction mixture, and the reaction mixture is allowed to complete a reaction to give the polyurethane. The present invention further relates to polyurethanes produced by this process and to the use of these polyurethanes in the interior of means of transport.
摘要翻译： 其中R 1和R 2可以相同或不同，并且分别是任何所需的取代或未取代的烃部分，条件是与硫原子键合的碳原子是脂族碳原子，和任选地（e）发泡剂，（f）链 增量剂和/或交联剂，和（g）助剂和/或添加剂混合以产生反应混合物，并使反应混合物完成反应，得到聚氨酯。 本发明还涉及通过该方法生产的聚氨酯和在运输工具内部使用这些聚氨酯。
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公开(公告)号：US09399696B2
公开(公告)日：2016-07-26
申请号：US14378189
申请日：2013-03-14
CPC分类号： C08G18/7621 , C08G18/222 , C08G18/242 , C08G18/3281 , C08G18/409 , C08G18/4829
摘要： Embodiments include polymer polyol dispersions which include a polyol liquid phase and solid particle phase. Embodiments include methods of making the polymer polyol dispersions. The polymer polyol dispersions are essentially free of tin, have a solid content of between about 20 and 50 wt % based on the total weight of the polymer polyol dispersion, and have a viscosity at 20 C. of less than 9000 mPas. The solid particle phase has more than 90% by weight of particles in the solid particle phase having a particle diameter of less than 5 μm.
摘要翻译： 实施方案包括聚合物多元醇分散体，其包括多元醇液相和固体颗粒相。 实施方案包括制备聚合物多元醇分散体的方法。 聚合物多元醇分散体基本上不含锡，固体含量基于聚合物多元醇分散体的总重量为约20至50重量％，并且在20℃下的粘度小于9000mPas。 固体颗粒相具有超过90重量％的固体颗粒相中的粒径小于5μm的颗粒。
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公开(公告)号：US20160194433A1
公开(公告)日：2016-07-07
申请号：US14911648
申请日：2014-07-31
申请人： ENERLAB 2000 INC.
发明人： Armand LANGLOIS , Michel DROUIN
CPC分类号： C08G18/6492 , C08G18/0838 , C08G18/14 , C08G18/165 , C08G18/168 , C08G18/1808 , C08G18/246 , C08G18/3218 , C08G18/3281 , C08G18/3806 , C08G18/4211 , C08G18/6655 , C08G18/7664 , C08G18/797 , C08G2101/0008 , C08G2101/0025 , C08G2101/005 , C08G2120/00 , C08G2150/00 , C08G2170/00 , C08H6/00 , C08K3/016 , C08L75/04 , C08L97/005
摘要： A process for the production of a lignin based polyurethane products is provided. The process comprises mixing at least one dried lignin and at least one isocyanate to form a lignin-isocyanate mixture, and submitting the lignin-isocyanate mixture to a polymerization reaction. The polymerization reaction may include heating the lignin-isocyanate mixture, adding at least one catalyst to the lignin-isocyanate mixture, or mixing the lignin-isocyanate mixture with a resin comprising at least one polyol, in the presence of at least one catalyst. The lignin based polyurethane products obtained by the process may be rigid foams, flexible foams, rigid boards, rigid blocks, coatings, packagings, adhesives, binders, sealants, elastomers, Thermoplastic Polyurethanes or Reaction Injection Moldings. There is also provided a mixture comprising at least one dried lignin and at least one isocyanate for use in the production of a lignin based polyurethane products.
摘要翻译： 提供了一种生产木质素聚氨酯产品的方法。 该方法包括将至少一种干燥的木质素和至少一种异氰酸酯混合以形成木质素 - 异氰酸酯混合物，并将木质素 - 异氰酸酯混合物交给聚合反应。 聚合反应可以包括加热木质素 - 异氰酸酯混合物，在木质素 - 异氰酸酯混合物中加入至少一种催化剂，或在至少一种催化剂的存在下将木质素 - 异氰酸酯混合物与包含至少一种多元醇的树脂混合。 通过该方法获得的基于木质素的聚氨酯产品可以是刚性泡沫，柔性泡沫，刚性板，刚性块，涂层，包装，粘合剂，粘合剂，密封剂，弹性体，热塑性聚氨酯或反应注射成型品。 还提供了包含至少一种干燥的木质素和至少一种用于生产木质素基聚氨酯产品的异氰酸酯的混合物。
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公开(公告)号：US09051411B2
公开(公告)日：2015-06-09
申请号：US12905949
申请日：2010-10-15
IPC分类号： C08K3/00 , C08G18/32 , B82Y30/00 , C08G18/73 , C08J9/00 , C08G18/08 , C08G18/38 , C08L75/14 , C08L75/04 , C08L75/12 , A61B17/34 , A61B17/00 , A61B17/29
CPC分类号： C08G18/3203 , A61B17/3498 , A61B2017/00867 , A61B2017/00871 , A61B2017/2932 , B82Y30/00 , C08G18/08 , C08G18/3221 , C08G18/3271 , C08G18/3281 , C08G18/3284 , C08G18/3287 , C08G18/3851 , C08G18/73 , C08G2280/00 , C08J9/0085 , C08L75/04 , C08L75/12 , C08L75/14
摘要： New shape memory polymer compositions, methods for synthesizing new shape memory polymers, and apparatus comprising an actuator and a shape memory polymer wherein the shape memory polymer comprises at least a portion of the actuator. A shape memory polymer comprising a polymer composition which physically forms a network structure wherein the polymer composition has shape-memory behavior and can be formed into a permanent primary shape, re-formed into a stable secondary shape, and controllably actuated to recover the permanent primary shape. Polymers have optimal aliphatic network structures due to minimization of dangling chains by using monomers that are symmetrical and that have matching amine and hydroxyl groups providing polymers and polymer foams with clarity, tight (narrow temperature range) single transitions, and high shape recovery and recovery force that are especially useful for implanting in the human body.
摘要翻译： 新形状记忆聚合物组合物，用于合成新形状记忆聚合物的方法，以及包括致动器和形状记忆聚合物的装置，其中形状记忆聚合物包括致动器的至少一部分。 一种形状记忆聚合物，其包含物理形成网状结构的聚合物组合物，其中所述聚合物组合物具有形状记忆行为并且可以形成为永久性初级形状，重新形成稳定的二次形状，并且可控地致动以恢复永久性初级 形状。 聚合物具有最佳的脂肪族网络结构，因为通过使用对称的单体使悬挂链最小化，并且具有匹配的胺和羟基，提供具有透明度，紧密（窄温度范围）单一过渡的聚合物和聚合物泡沫以及高形状恢复和恢复力 这对植入人体尤其有用。
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公开(公告)号：US20130253086A1
公开(公告)日：2013-09-26
申请号：US13893033
申请日：2013-05-13
CPC分类号： C08G18/3203 , A61B17/3498 , A61B2017/00867 , A61B2017/00871 , A61B2017/2932 , B82Y30/00 , C08G18/08 , C08G18/3221 , C08G18/3271 , C08G18/3281 , C08G18/3284 , C08G18/3287 , C08G18/3851 , C08G18/73 , C08G2280/00 , C08J9/0085 , C08L75/04 , C08L75/12 , C08L75/14
摘要： New shape memory polymer compositions, methods for synthesizing new shape memory polymers, and apparatus comprising an actuator and a shape memory polymer wherein the shape memory polymer comprises at least a portion of the actuator. A shape memory polymer comprising a polymer composition which physically forms a network structure wherein the polymer composition has shape-memory behavior and can be formed into a permanent primary shape, re-formed into a stable secondary shape, and controllably actuated to recover the permanent primary shape. Polymers have optimal aliphatic network structures due to minimization of dangling chains by using monomers that are symmetrical and that have matching amine and hydroxl groups providing polymers and polymer foams with clarity, tight (narrow temperature range) single transitions, and high shape recovery and recovery force that are especially useful for implanting in the human body.
摘要翻译： 新形状记忆聚合物组合物，用于合成新形状记忆聚合物的方法，以及包括致动器和形状记忆聚合物的装置，其中形状记忆聚合物包括致动器的至少一部分。 一种形状记忆聚合物，其包含物理形成网状结构的聚合物组合物，其中所述聚合物组合物具有形状记忆行为并且可以形成为永久性初级形状，重新形成稳定的二次形状，并且可控地致动以恢复永久性初级 形状。 聚合物具有最佳的脂肪族网络结构，因为通过使用对称的单体使悬挂链最小化，并且具有匹配的胺和羟基，提供具有透明度，紧密（窄温度范围）单一跃迁的聚合物和聚合物泡沫体以及高形状恢复和恢复力 这对植入人体尤其有用。
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公开(公告)号：US20100069518A1
公开(公告)日：2010-03-18
申请号：US12532471
申请日：2008-03-20
申请人： Henri Mispreuve , Reinold Naescher , Kurt Schoenenberger , Johan Frei , Erik Vogel , Zacharias Grote
发明人： Henri Mispreuve , Reinold Naescher , Kurt Schoenenberger , Johan Frei , Erik Vogel , Zacharias Grote
CPC分类号： C08G18/244 , C08G18/0876 , C08G18/12 , C08G18/165 , C08G18/3281 , C08G18/409 , C08G18/485 , C08G18/6688 , C08G2101/005 , C08G2101/0083 , C08L83/00 , C08G18/7621
摘要： Polymer-modified polyol, for use as a starting material for polyurethane foam, is made by reacting an olamine, such as triethanolamine, with an isocyanate in the presence of a metal organic catalyst. The catalyst is a metal salt of an organic acid and the viscosity of the polymer-modified polyol is at least 2250 mPa·s. In one embodiment the catalyst is of the formulat M(O.CO.R.CH3)2 where M is a metal and R is a carbon chain of 6 to 20 carbons. A metal salt of a monohydroxy fatty acid, particularly ricinoleic acid may be used.
摘要翻译： 用作聚氨酯泡沫的原料的聚合物改性的多元醇是通过在金属有机催化剂存在下使醇如三乙醇胺与异氰酸酯反应来制备的。 催化剂是有机酸的金属盐，聚合物改性多元醇的粘度至少为2250mPa·s。 在一个实施方案中，催化剂为制剂M（O.CO.R.CH 3）2，其中M是金属，R是碳原子数为6至20的碳链。 可以使用单羟基脂肪酸的金属盐，特别是蓖麻油酸。
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69.发明授权公开(公告)号：US07354458B2
公开(公告)日：2008-04-08
申请号：US10939337
申请日：2004-09-14
IPC分类号： D06M13/395
CPC分类号： C08G18/3281 , C08G18/36 , C08G18/71 , C08G18/792 , C08G18/8019 , C08G18/8029 , C09D175/04 , D06M13/02 , D06M13/395 , D06M15/227 , D06M15/256 , D06M15/564 , D21H17/72 , D21H19/14 , C08L91/06
摘要： A composition based on water and/or organic solvents and their use as a finish on flat materials, comprising (1)10-90%of a hydrophobic wax based component, (2)10-90%of a hydrophobic reaction product prepared by reacting a component (A) with a partially blocked or non-blocked di-, tri- or polyisocyanate and (3) 0-45%by weight of a blocked or non-blocked di-, tri- or polyisocyanate and (4) optionally, an emulsifier. When used as a finish on flat materials, the composition can endow the treated flat materials with durable hydrophobic properties.
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公开(公告)号：US20080064843A1
公开(公告)日：2008-03-13
申请号：US11983377
申请日：2007-11-08
申请人： Thomas Daly
发明人： Thomas Daly
CPC分类号： C08G18/10 , C08G18/2865 , C08G18/3281
摘要： A hydrophobic polymer made by incorporating alkyl chains pendant to the main backbone of the polymer. The present invention allows creating polymers with alkyl chains pendant to the polymer chain. Synthetic and naturally derived starting materials such as tallow diamine or ethoxylated tallow amine typically contain a mixture of chain lengths with varying degrees of branching and unsaturation. The unsaturated positions in the final polymer can be made to cross-link in the presence of a catalyst to increase the hardness and reduce the effect of heat and solvent borne exposures. The present invention can be a replacement to current monomers or additive to common polymers to replace or modify the current polymers to alter the properties of a polymer adding the known benefits of fatty compounds to common polymers such as hydrophobicity, or in altering the HLB (hydrophilic lipophilic balance) of polymeric surfactants. While the preferred embodiment of the present invention is directed primarily to urea and urethane polymers, the invention is also useful in the incorporation of pendant alkyl structures in other types of polymers that use an amine or alcohol groups to form the linkage. Other polymer types which can utilize this invention include, but are not limited to the following: polyamide, polyester, polycarbonate, polyether, polysiloxane, and epoxy.
摘要翻译： 通过将烷基链引入到聚合物的主骨架上制成的疏水性聚合物。 本发明允许产生具有悬挂于聚合物链上的烷基链的聚合物。 合成和天然衍生的起始物质如牛脂二胺或乙氧基化牛脂胺通常含有具有不同支化度和不饱和度的链长度的混合物。 最终聚合物中的不饱和位置可以在催化剂存在下进行交联以增加硬度并降低热和溶剂承受的影响。 本发明可以替代现有的单体或添加剂以代替或改性目前的聚合物以改变聚合物的性质，从而加入脂肪族化合物对普通聚合物如疏水性的已知益处，或改变HLB（亲水性 亲油平衡）的聚合物表面活性剂。 尽管本发明的优选实施方案主要涉及脲和聚氨酯聚合物，但是本发明也可用于将烷基结构侧链引入使用胺或醇基形成连接的其它类型的聚合物中。 可以利用本发明的其它聚合物类型包括但不限于：聚酰胺，聚酯，聚碳酸酯，聚醚，聚硅氧烷和环氧树脂。
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