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61.发明授权Latex-base paint containing 2-methoxy-2-phenyl propane or 8-methoxy-p-menthane 失效含有2-甲氧基-2-苯基丙烷或8-甲氧基对薄荷酸的乳胶基漆
公开(公告)号：US4292219A
公开(公告)日：1981-09-29
申请号：US101656
申请日：1979-12-10
申请人： James E. Lyons , Peter Hosler
发明人： James E. Lyons , Peter Hosler
IPC分类号： C07C43/04 , C07C43/115 , C09D5/02 , C09D123/00 , C09D129/00 , C08K5/06
CPC分类号： C10L1/1852 , C07C43/04 , C07C43/115 , C09D5/024
摘要： In the acid-catalyzed etherification of olefins with alcohols, substantially complete recovery of alcohol and catalyst is obtained when small amounts of water (1-10%) are added to the reaction. The addition of water provides a two-phase reaction medium in which olefin and ether are in the upper phase and alcohol and catalyst are in the lower phase. These phases are maintained during the course of the reaction, which continues as a two-phase system. Certain novel ethers produced by this process are likewise disclosed herein.
摘要翻译： 在烯烃与醇的酸催化醚化中，当将少量的水（1-10％）加入到反应中时，获得醇和催化剂的基本上完全的回收。 水的添加提供了两相反应介质，其中烯烃和醚在上段，醇和催化剂处于较低的相。 在反应过程中维持这些相，作为两相体系继续进行。 通过该方法生产的某些新型醚同样在此公开。
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62.发明授权Catalytic process for the conversion of toluene to equimolar amounts of phenol acetate and methylene diacetate 失效将甲苯转化为等摩尔量的乙酸苯酯和二乙酸亚甲酯的催化方法
公开(公告)号：US4260808A
公开(公告)日：1981-04-07
申请号：US957273
申请日：1978-11-03
申请人： James E. Lyons , George Suld , Robert W. Shinn
发明人： James E. Lyons , George Suld , Robert W. Shinn
IPC分类号： C07C67/05
CPC分类号： C07C67/05 , C07C67/035
摘要： Equimolar amounts of phenol and formaldehyde may be prepared from oxygen and toluene. The catalytic oxidation of toluene, when carried out in the presence of acetic anhydride, forms phenyl acetate and methylene diacetate. Pyrolysis of these two intermediates yields phenol and formaldehyde.Significant improvements in this process are achieved when the first stage of the reaction is carried out in the presence of MoO.sub.3.In a further embodiment of this invention it has been found that Group VIII dithiosemibenzil compounds, particularly nickel dithiosemibenzil, serves as a superior promoter for the toluene oxidation reaction.In still a further embodiment of this invention it has been found that persulfate promoters such as potassium persulfate, persulfuric acid, or Caro's dry acid are particularly effective promoters for the toluene oxidation reaction.In a like manner, hydroquinone or resorcinol may be obtained from cresyl acetates.
摘要翻译： 可以从氧和甲苯制备等摩尔量的苯酚和甲醛。 甲苯的催化氧化在乙酐存在下进行时，形成乙酸苯酯和二乙酸亚甲酯。 这两种中间体的热解产生苯酚和甲醛。 当反应的第一阶段在MoO 3存在下进行时，可以实现该方法的显着改进。 在本发明的另一个实施方案中，已经发现，第VIII族二硫代二苯胺化合物，特别是二硫代二苯胺二镍，用作甲苯氧化反应的优良助剂。 在本发明的又一个实施方案中，已经发现过硫酸盐促进剂如过硫酸钾，过硫酸或Caro's干酸是用于甲苯氧化反应的特别有效的促进剂。 以类似的方式，可以从乙酸甲苯酯获得氢醌或间苯二酚。
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公开(公告)号：US4191839A
公开(公告)日：1980-03-04
申请号：US890175
申请日：1978-03-27
申请人： James E. Lyons , Robert W. Shinn , George Suld
发明人： James E. Lyons , Robert W. Shinn , George Suld
CPC分类号： C07C45/36 , C07C67/035
摘要： A highly selective, one-step conversion of toluene to benzylidene diacetate is provided by the reaction of toluene with O.sub.2 and acetic anhydride in the presence of an acid catalyst. No metal catalysts are required.
摘要翻译： 通过甲酸与O 2和乙酸酐在酸催化剂存在下的反应，可以提供甲苯对亚乙基二乙酸酯的高选择性，一步转化。 不需要金属催化剂。
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公开(公告)号：US4169864A
公开(公告)日：1979-10-02
申请号：US888906
申请日：1978-03-22
CPC分类号： C07C13/68 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Novel codimers (I) of norbornadiene and phenylacetylenes and their hydrogenated derivatives (II), having the following structures ##STR1## wherein R is a hydrogen, a phenyl, or a phenyl having alkyl substitutents and R.sub.1 is a phenyl or a phenyl having alkyl substituents and processes for preparing both are disclosed. Codimer (II) can be used as a high energy fuel or a diluent for such a fuel. Process for making codimer (I) involves reacting norbornadiene and phenylacetylene or diphenylacetylene with a catalyst system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride.
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65.发明授权Process for making codimers of norbornadiene and alkynes using a cobalt catalyst 失效使用钴催化剂制备降冰片二烯和炔烃的共聚物的方法
公开(公告)号：US4110409A
公开(公告)日：1978-08-29
申请号：US842812
申请日：1977-10-17
CPC分类号： C07C13/68 , C07C2/42 , C07C5/03 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Norbornadiene and an alkyne are catalytically codimerized in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride. Also, novel codimers of norbornadiene and an alkyne containing at least three carbons are disclosed. After hydrogenation, resulting codimers can be used as high energy fuels or diluents for such fuels.
摘要翻译： 降冰片二烯和炔烃在钴或钴乙酰丙酮化合物，1,2-双二苯基膦基乙烷和烷基氯化铝的均相催化体系存在下进行催化同步化。 此外，公开了降冰片二烯和含有至少三个碳的炔烃的新型共聚物。 氢化后，得到的共混物可用作这种燃料的高能燃料或稀释剂。
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公开(公告)号：US5386074A
公开(公告)日：1995-01-31
申请号：US100595
申请日：1993-07-30
摘要： Barium peroxide in which has been incorporated a transition metal compound is used as a catalyst for the oxidative dehydrogenation of organic compounds in the presence of terminal oxidants.
摘要翻译： 其中已经加入过渡金属化合物的过氧化钡被用作有机化合物在末端氧化剂存在下氧化脱氢的催化剂。
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公开(公告)号：US5345010A
公开(公告)日：1994-09-06
申请号：US76990
申请日：1993-06-15
摘要： A process for the direct catalytic oxidation of methane to methanol comprises separately contacting chromium chemically bound to the oxygen of a metal oxide support surface with (1) methane and (2) oxidant. The support may comprise silica, alumina, magnesia, titania, or zirconia.
摘要翻译： 将甲烷直接催化氧化成甲醇的方法包括分别将与金属氧化物载体表面的氧化学键合的铬与（1）甲烷和（2）氧化剂接触。 载体可以包括二氧化硅，氧化铝，氧化镁，二氧化钛或氧化锆。
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公开(公告)号：US5132472A
公开(公告)日：1992-07-21
申请号：US599185
申请日：1990-10-17
CPC分类号： B01J8/0285 , B01J8/0214 , B01J8/0453 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/36 , B01J2208/00415 , B01J2219/00135
摘要： Process is provided for oxidation of organic compounds in which a reaction zone is provided, containing an open space and a bed of solid granular catalyst, an organic feedstock and oxygen are passed in gas phase through the open space and then into contact with the catalyst bed, and reaction products are removed from the open space after relatively less contact with the catalyst, and from at least one other location after relatively greater contact with the catalyst. Greater yield of desired product may be obtained in such operation than in operation where all of the reaction products are removed after the greater contact with the catalyst.
摘要翻译： 提供了含有开放空间和固体颗粒状催化剂床的有机化合物氧化的方法，有机原料和氧气通过开放空间通过，然后与催化剂床接触 并且在与催化剂接触较少的情况下从开放空间除去反应产物，以及在与催化剂相对较大的接触之后的至少一个其它位置。 在所述操作中可以获得所需产物的产率比在所有反应产物在与催化剂更大接触之后除去的操作中获得。
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公开(公告)号：US5073664A
公开(公告)日：1991-12-17
申请号：US667733
申请日：1991-03-11
申请人： Vincent A. Durante , James E. Lyons
发明人： Vincent A. Durante , James E. Lyons
CPC分类号： C07C2/82
摘要： Propane is dimerized to 2,3-dimethylbutane with barium peroxide oxidizer.
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70.发明授权Phosphonite-and phosphonite-promoted ruthenium - cobalt catalysts for the dealkoxyhydroxymethylation of acetals to form glycol ethers 失效亚膦酸酯和亚膦酸盐促进的钌 - 钴催化剂用于缩醛的脱烷基羟甲基化形成二醇醚
公开(公告)号：US4895987A
公开(公告)日：1990-01-23
申请号：US871351
申请日：1986-06-06
CPC分类号： C07C41/30 , B01J31/0261 , B01J31/0262 , B01J31/20 , B01J2231/34 , B01J2231/641 , B01J2531/0211 , B01J2531/821 , B01J2531/845
摘要： Ruthenium-cobalt- or cobalt-containing catalysts which have been promoted with phosphonites or phosphinites effectively catalyze the dealkoxyhydroxymethylation of aldehyde acetals to form glycol monoethers. Methylal, for example, may be reacted with syngas, i.e., CO and H.sub.2, in the presence of these phosphonite- or phosphinite-promoted cobalt or ruthenium- cobalt catalysts to form the monomethyl ether of ethylene glycol. In a like manner acetaldehyde may be converted to the corresponding propylene glycol monoether. The process may advantageously be carried out with high yields and selectivities in the presence of a polar or non-polar organic solvent in combination with the catalyst system of this invention.The invention is also directed to the phosphonite- or phosphonite-promoted cobalt and ruthenium-cobalt catalyst system per se.
摘要翻译： 已经用亚膦酸盐或次膦酸盐促进的含钌钴或钴的催化剂有效地催化醛缩醛的脱烷基羟甲基化形成二醇单醚。 甲缩醛例如可以在合成气（即CO和H 2）的存在下，在这些亚膦酸盐或次膦酸盐促进的钴或钌 - 钴催化剂的存在下反应以形成乙二醇的单甲基醚。 以类似方式，乙醛可以转化成相应的丙二醇单醚。 在极性或非极性有机溶剂与本发明的催化剂体系的组合下，该方法可以有利地以高产率和选择性进行。 本发明还涉及亚膦酸盐或亚膦酸盐促进的钴和钌 - 钴催化剂体系本身。
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