摘要:
A supported catalyst comprising a support having supported thereon at least one member selected from the group consisting of heteropolyacids and heteropolyacid salts, in which the heteropolyacid and/or heteropolyacid salt is substantially present in a surface layer region of the support to a depth of 30% from the support surface. The catalyst has a high performance when used for the production of compounds by various reactions.
摘要:
[Objective] To develop a method of fabricating carbon nanotube bundles clad in a quartz sheath with high temperature and chemical resistance.[Method of Fabrication] The microcrystalline carbon nanotube sample in powder form is vacuum-sealed within a quartz tube sheath and heated to the softening temperature of quartz, then quickly quenched to room temperature while simultaneously extending or “drawing” the quartz tube along its major axis.
摘要:
A method for producing crystallized silicon according to the EFG process by using a shaping part, between which part and a silicon melt, crystallized silicon grows in a growth zone. Inert gas and at least water vapor are fed into the silicon melt and/or growth zone, by means of which the oxygen content of the crystallized silicon is increased. From 50 to 250 ppm of vapor water is added to the inert gas, and the inert gas has an oxygen, CO and/or CO2 content of less than 20 ppm total.
摘要:
A silicon nanosheet comprising a silicon atom layer formed by bonding two-dimensionally and periodically arranged silicon atoms to each other through an Si—Si bond. A nanosheet solution prepared by dispersing or suspending the silicon nanosheets in a solvent. A nanosheet-containing composite having the silicon nanosheets on the surface and/or in the interior of a substrate. A nanosheet aggregate formed by aggregating the silicon nanosheets. A process for producing a nanosheet solution comprising: an acid treatment step of bringing a layered silicon compound into contact with an aqueous acid solution to derive a siloxene compound; and an exfoliation step of adding the siloxene compound into a solvent containing a surfactant, shaking the mixture, and peeling off the siloxene compound.
摘要:
This invention presents a process to produce bulk quantities of nanowires of a variety of semiconductor materials. Large liquid gallium drops are used as sinks for the gas phase solute, generated in-situ facilitated by microwave plasma. To grow silicon nanowires for example, a silicon substrate covered with gallium droplets is exposed to a microwave plasma containing atomic hydrogen. A range of process parameters such as microwave power, pressure, inlet gas phase composition, were used to synthesize silicon nanowires as small as 4 nm (nanometers) in diameter and several micrometers long. As opposed to the present technology, the instant technique does not require creation of quantum sized liquid metal droplets to synthesize nanowires. In addition, it offers advantages such as lower growth temperature, better control over size and size distribution, better control over the composition and purity of the nanowires.
摘要:
The invention concerns a peroxosilicated, optionally phosphatized, disinfecting compound with scale preventive effect obtained by reacting an alkaline or alkaline-earth metasilicate with an active oxygen-releasing compound, for example potassium monopersulphate and/or oxygen peroxide, in inert medium. The compound can be stabilised with sodium hexametaphosphate. Copper and aluminium in salt form can be encapsulated or complexed with the metasilicate so that the resulting peroxosilicated compound can be used for its disinfecting, scale preventive, anticorrosive, flocculating and algicidal properties for more than three weeks.
摘要:
A for producing metal oxide and/or organo-metal oxide compositions from metal oxide and organo-metal oxide precursors utilizing a rate modifying drying agent. The process allows metal oxide and/or organo-metal oxide compositions to be produced from a wide variety of metal oxide and organo-metal oxide precursors including metal halides and organometallic halides.
摘要:
Compounds of the formulae I and II ##STR1## are prepared by an addition reaction of a compound of the formula IIIR.sup.1 OH IIIwith an acetylene or allene of the formula IV or V ##STR2## where R.sup.1 and R are as defined, in the gas phase at elevated temperatures in the presence of a heterogeneous, silicate-containing catalyst, by a process in which the catalyst used is one which contains or consists of, as the active component, a zinc silicate obtained by precipitation in aqueous solution from a soluble silicon compound and zinc compound, zinc silicate beinga) an essentially X-ray amorphous zinc silicate of the formula VIZn.sub.a Si.sub.c O.sub.a+2c-0.5e (OH).sub.e.fH.sub.2 O VI, where e is from 0 to 2a+4c and the ratio a:c is from 1 to 3.5, and the ratio f:a is from 0 to 200, and/orb) a crystalline zinc silicate having the structure of hemimorphite of the formula Zn.sub.4 Si.sub.2 O.sub.7 (OH).sub.2.H.sub.2 O.
摘要翻译:式I和II的化合物通过在存在下在升高的温度下在气相中通过式III R1OHIII的化合物与式IV或V的炔或其中R1和R如所定义的二烯的加成反应来制备, 的不均一硅酸盐催化剂,其中使用的催化剂是含有或由作为活性组分的组成的方法,所述方法是通过在可溶性硅化合物和锌化合物的水溶液中沉淀而获得的硅酸锌,硅酸锌 a)基本上是式VI ZnaSicOa + 2c-0.5e(OH)e.fH2OVI的X射线无定形硅酸锌,其中e为0至2a + 4c,a:c为1至3.5,以及 比例f:a为0至200,和/或b)具有式Zn 4 Si 2 O 7(OH)2·H 2 O的半偏氟结构的结晶硅酸锌。
摘要:
A solid silica derivative which is represented by the general formula H.sub.n SiO.sub.(4-n)/2 wherein n is a real number larger than 0 but smaller than 2 and which contains Si--H bond, said solid silica derivative being able to be easily produced in a high yield by subjecting to hydrolysis-condensation an alkoxysilane represented by the mean general formula H.sub.n --Si(OR.sup.0).sub.4-n in which R.sup.0 represents an alkyl group having 1 to 4 carbon atoms, plural R.sup.0 groups may be the same as or different from one another and n is a real number greater than 0 but smaller than 2, using water in an amount of (4-n)/2 moles or more per mole of the alkoxysilane at a pH of 10.5 or less.
摘要翻译:由通式H n SiO(4-n)/ 2表示的固体二氧化硅衍生物,其中n是大于0但小于2的实数,并且含有Si-H键,所述固体二氧化硅衍生物能够容易地生成 通过水解缩合由通式为Hn-Si(OR0)4-n表示的烷氧基硅烷(其中R 0表示具有1至4个碳原子的烷基)表示的高收率,多个R0基团可以与 使用相对于每摩尔烷氧基硅烷为(10-n)/ 2摩尔以上的水,pH为10.5以下的水,n为大于0但小于2的实数。
摘要:
Crystalline sodium silicates having a sheet structure and an ion exchange capacity of 83-130 mmol of Na.sup.+ /mol of SiO.sub.2 are prepared by a method in which an aqueous reaction mixture which contains sodium silicate, has a molar ratio SiO.sub.2 /Na.sub.2 O of 3.9:1 to 15:1 and a molar ratio H.sub.2 O/(Na.sub.2 O+SiO.sub.2) of 3:1 to 80:1 and contains 0.01 to 30% by weight, relative to the amount of SiO.sub.2 in the reaction mixture employed, of seed crystals of the desired crystalline sodium silicate is prepared, the mixture is heated to temperatures of 160.degree. to 250.degree. C., the reaction is carried out at least until, in the X-ray diffraction pattern of a sample filtered off under suction and dried at 120.degree. C., the ratio of the intensity of the reflection at the interplanar spacing d.sub.1 =(20.+-.2).multidot.10.sup.-8 cm to the intensity of any reflection present at the interplanar spacing d.sub.2 =(15.5.+-.1.5).multidot.10.sup.-8 cm is at least 3:1, and the reaction is terminated before the intensity of the reflection at the interplanar spacing d.sub.3 =(3.34.+-.0.04).multidot.10.sup.-8 cm reaches or exceeds the intensity of the reflection at the interplanar spacing d.sub.4 =(3.44.+-.0.04).multidot.10.sup.-8 cm. A crystalline silicic acid having a sheet structure and the overall composition H.sub.2 Si.sub.x O.sub.2x+1, wherein 15