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公开(公告)号：US07750172B2
公开(公告)日：2010-07-06
申请号：US11929358
申请日：2007-10-30
CPC分类号： C08F4/80 , B01J31/18 , B01J31/2265 , B01J31/24 , B01J31/2404 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07F15/002 , C07F15/0046 , C08F32/00 , C08G61/08
摘要： Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula where M is Os or Ru; R1 is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X1 are independently selected from any anionic ligand; and L and L1 are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors. The ruthenium and osmium carbene compounds of the present invention may be used to catalyze olefin metathesis reactions including, but not limited to, ROMP, RCM, depolymerization of unsaturated polymers, synthesis of telechelic polymers, and olefin synthesis.
摘要翻译： 公开了在各种官能团存在下稳定并且可用于催化非限制性环状和无环烯烃上的烯烃复分解反应的钌和锇卡宾化合物。 还公开了制备卡宾化合物的方法。 卡宾化合物具有下式：其中M是Os或Ru; R1是氢; R选自氢，取代或未取代的烷基和取代或未取代的芳基; X和X 1独立地选自任何阴离子配体; L和L 1独立地选自任何中性给电子体。 本发明的钌和锇卡宾化合物可以使用重氮化合物，通过中性电子给体配体交换，通过交叉复分解，使用乙炔，使用累积的烯烃，以及使用重氮化合物和中性电子给体的一锅法合成。 本发明的钌和锇卡宾化合物可用于催化烯烃复分解反应，包括但不限于ROMP，RCM，不饱和聚合物的解聚，遥爪聚合物的合成和烯烃合成。
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公开(公告)号：US20090012248A1
公开(公告)日：2009-01-08
申请号：US11929358
申请日：2007-10-30
CPC分类号： C08F4/80 , B01J31/18 , B01J31/2265 , B01J31/24 , B01J31/2404 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07F15/002 , C07F15/0046 , C08F32/00 , C08G61/08
摘要： Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula where M is Os or Ru; R1 is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X1 are independently selected from any anionic ligand; and L and L1 are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors. The ruthenium and osmium carbene compounds of the present invention may be used to catalyze olefin metathesis reactions including, but not limited to, ROMP, RCM, depolymerization of unsaturated polymers, synthesis of telechelic polymers, and olefin synthesis.
摘要翻译： 公开了在各种官能团存在下稳定并且可用于催化非限制性环状和无环烯烃上的烯烃复分解反应的钌和锇卡宾化合物。 还公开了制备卡宾化合物的方法。 卡宾化合物具有下式：其中M是Os或Ru; R1是氢; R选自氢，取代或未取代的烷基和取代或未取代的芳基; X和X 1独立地选自任何阴离子配体; L和L 1独立地选自任何中性给电子体。 本发明的钌和锇卡宾化合物可以使用重氮化合物，通过中性电子给体配体交换，通过交叉复分解，使用乙炔，使用累积的烯烃，以及使用重氮化合物和中性电子给体的一锅法合成。 本发明的钌和锇卡宾化合物可用于催化烯烃复分解反应，包括但不限于ROMP，RCM，不饱和聚合物的解聚，遥爪聚合物的合成和烯烃合成。
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43.发明申请Single component cationic palladium proinitiators for the latent polymerization of cycloolefins 审中-公开单组分阳离子钯催化剂用于环烯烃的潜在聚合公开(公告)号：US20050187398A1
公开(公告)日：2005-08-25
申请号：US10976350
申请日：2004-10-28
IPC分类号： B01J31/04 , B01J31/14 , B01J31/18 , B01J31/22 , B01J31/24 , C07F15/00 , C08F10/00 , C08F32/00 , C08F32/08
CPC分类号： C07F15/0066 , B01J31/143 , B01J31/146 , B01J31/1805 , B01J31/1895 , B01J31/223 , B01J31/2239 , B01J31/226 , B01J31/24 , B01J31/2404 , B01J31/2438 , B01J31/2447 , B01J31/248 , B01J2531/0216 , B01J2531/824 , C08F10/00 , C08F32/00 , C08F4/7027 , C08F4/7019
摘要： Palladium compound compositions are provided in accordance with Formulae [((R)3E)aPd(Q)(LB)b]p [WCA]r, where ((R)3E) is a Group 15 electron donor ligand, Q is an anionic ligand, LB is a Lewis base, WCA is a weakly coordinating anion, a is 1, 2 or 3, b is 0, 1 or 2, the sum of a and b is 1, 2 or 3 and each of p and r is an integer such that the molecular charge is zero, or [(E(R)3)(E(R)2R*)Pd(LB)]p[WCA]r where E(R)2R* represents a Group 15 neutral electron donor ligand and where R* is an anionic hydrocarbyl containing moiety, bonded to the Pd and having a β hydrogen with respect to the Pd center. Such compound composition exhibits latent polymerization activity in the presence of polycyclic olefins.
摘要翻译： 钯化合物组合物按照式[（（R）3））提供：Pd（Q）（LB）b 其中（（R）3E）是第15族电子给体配体，Q是阴离子配位体，LB是一种（Ⅴ） 路易斯碱，WCA是弱配位阴离子，a为1,2或3，b为0,1或2，a和b之和为1,2或3，p和r各自为整数，使得 分子电荷为零，或[（E（R）3 N）（E（R）2 R *）Pd（LB）] p < 其中E（R）2 R *代表第15族中性电子给体配体，其中R *是含有部分阴离子烃基的部分，键合到Pd和 相对于Pd中心具有β氢。 这种化合物组合物在多环烯烃的存在下表现出潜在的聚合活性。
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44.发明授权Polymerized cycloolefins using transition metal catalyst and end products thereof 有权使用过渡金属催化剂及其最终产物的聚合环烯烃公开(公告)号：US06903171B2
公开(公告)日：2005-06-07
申请号：US10271393
申请日：2002-10-15
申请人： Larry Funderburk Rhodes , Andrew Bell , Ramakrishna Ravikiran , John C. Fondran , Saikumar Jayaraman , Brian Leslie Goodall , Richard A. Mimna , John-Henry Lipian
发明人： Larry Funderburk Rhodes , Andrew Bell , Ramakrishna Ravikiran , John C. Fondran , Saikumar Jayaraman , Brian Leslie Goodall , Richard A. Mimna , John-Henry Lipian
摘要： Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R′)zM(L′)x(L″)y]b[WCA]d wherein [(R′)zM(L′)x(L″)y] is a cation complex where M represents a Group 10 transition metal; R′ represents an anionic hydrocarbyl containing ligand; L′ represents a Group 15 neutral electron donor ligand; L″ represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.
摘要翻译： 使用阳离子第10族金属络合物和下式的弱配位阴离子加成聚合环烯的方法：<？in-line-formula description =“In-line formula”end =“lead”？> [（R' M（L'）x（L“）Y'B <？in-line-formula description =“In-line Formulas”end =“tail”？>其中[（R'）Z M（L'）x < （L“）Y是阳离子络合物，其中M表示第10族过渡金属; R'表示含阴离子烃基的配体; L'表示15族中性电子给体配体; L“表示不稳定的中性电子给体配体; x为1或2; y为0,1,2或3; 且z为0或1，其中x，y和z之和为4; 和[WCA]代表弱协调的对抗综合体; b和d是表示阳离子络合物和弱配位抗衡阴离子络合物在总体催化剂络合物上平衡电荷的次数的数字。
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公开(公告)号：US06825307B2
公开(公告)日：2004-11-30
申请号：US10196525
申请日：2002-07-16
申请人： Brian L. Goodall
发明人： Brian L. Goodall
IPC分类号： C08F3208
CPC分类号： C08F32/08 , C08F32/00 , Y02P20/582
摘要： Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R′)zM(L′)x(L″)y]b[WCA]d wherein [(R′)zM(L′)x(L″)y] is a cation complex where M represents a Group 10 transition metal; R′ represents an anionic hydrocarbyl containing ligand; L′ represents a Group 15 neutral electron donor ligand; L″ represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.
摘要翻译： 使用阳离子10族金属络合物和下式的弱配位阴离子进行环烯加成聚合的方法：其中[（R'）z M（L'）x（L“）y]是阳离子络合物，其中M表示 第10组过渡金属; R'表示含阴离子烃基的配体; L'表示15族中性电子给体配体; L“表示不稳定的中性电子给体配体; x为1或2; y为0,1,2或3; 且z为0或1，其中x，y和z之和为4; 和[WCA]代表弱协调的对抗综合体; b和d是表示阳离子络合物和弱配位抗衡阴离子络合物在总体催化剂络合物上平衡电荷的次数的数字。
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公开(公告)号：US06750272B2
公开(公告)日：2004-06-15
申请号：US09892221
申请日：2001-06-25
IPC分类号： C08K910
摘要： A method for making a fiber-reinforced composite comprises dispensing a reactive liquid into a mold. The mold comprises fibers and a single-component activator on the fibers. The reactive liquid comprises a cyclic olefin, and the mold comprises fibers and a single-component ROMP activator on the fibers. Composites formed by the method may have high fiber densities.
摘要翻译： 制造纤维增强复合材料的方法包括将反应性液体分配到模具中。 模具包括纤维和纤维上的单组分活化剂。 反应性液体包含环状烯烃，模具包含纤维和纤维上的单组分ROMP活化剂。 通过该方法形成的复合材料可具有高的纤维密度。
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公开(公告)号：US20030181609A1
公开(公告)日：2003-09-25
申请号：US10325998
申请日：2002-12-19
IPC分类号： C07F015/00 , C08F004/80
CPC分类号： C08F4/80 , B01J31/18 , B01J31/2265 , B01J31/24 , B01J31/2404 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07F15/002 , C07F15/0046 , C08F32/00 , C08G61/08
摘要： Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula 1 where M is Os or Ru; R1 is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X1 are independently selected from any anionic ligand; and L and L1 are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors. The ruthenium and osmium carbene compounds of the present invention may be used to catalyze olefin metathesis reactions including, but not limited to, ROMP, RCM, depolymerization of unsaturated polymers, synthesis of telechelic polymers, and olefin synthesis.
摘要翻译： 公开了在各种官能团存在下稳定并且可用于催化非限制性环状和无环烯烃上的烯烃复分解反应的钌和锇卡宾化合物。 还公开了制备卡宾化合物的方法。 卡宾化合物具有下式：其中M是Os或Ru; R 1是氢; R选自氢，取代或未取代的烷基和取代或未取代的芳基; X和X 1独立地选自任何阴离子配体; L和L 1独立地选自任何中性电子给体。 本发明的钌和锇卡宾化合物可以使用重氮化合物，通过中性电子给体配体交换，通过交叉复分解，使用乙炔，使用累积的烯烃，以及使用重氮化合物和中性电子给体的一锅法合成。 本发明的钌和锇卡宾化合物可用于催化烯烃复分解反应，包括但不限于ROMP，RCM，不饱和聚合物的解聚，遥爪聚合物的合成和烯烃合成。
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48.发明授权公开(公告)号：US06576726B1
公开(公告)日：2003-06-10
申请号：US09673281
申请日：2000-10-19
申请人： Bernhard Rieger
发明人： Bernhard Rieger
IPC分类号： C08F464
CPC分类号： C08F110/06 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F32/00 , Y10S526/943 , C08F4/65927 , C08F2500/15 , C08F2500/03
摘要： The invention concerns a metallocene catalyst composition for preparing linear isotactic polymers, wherein said catalyst composition contains a metal complex and an activator. The invention also concerns a process for preparing linear, isotactic polymers which have a structure of which the tacticity varies within the range of between 25 and 60% of [mmmm] pentad concentration, in which process a C2 to C20 olefin is polymerized in the presence of catalyst composition.
摘要翻译： 本发明涉及用于制备线性全同立构聚合物的茂金属催化剂组合物，其中所述催化剂组合物含有金属络合物和活化剂。 本发明还涉及一种制备线性全同立构聚合物的方法，其具有其立构规整度在[mmmm]五单元组浓度的25至60％的范围内变化的结构，其中C2至C20烯烃在存在下聚合 的催化剂组成。
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49.发明授权Process for the polymerization of olefins using a catalyst containing a novel catalyst component 失效使用含有新催化剂组分的催化剂进行烯烃聚合的方法公开(公告)号：US06350831B1
公开(公告)日：2002-02-26
申请号：US09220589
申请日：1998-12-28
IPC分类号： C08F464
CPC分类号： C08F32/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F10/02 , C08F12/00 , C08F12/04 , C08F110/02 , C08F210/02 , C08F210/16 , C08F2420/04 , Y10S526/943 , C08F236/20 , C08F2500/25 , C08F210/14 , C08F4/65925
摘要： A metallocene compound may be used as a catalyst component for the polymerization of olefins. The compound is stable to air and moisture so that it generates no hydrogen halide by hydrolysis and is easily handled, and it has high storage stability and high catalyst activity. Specifically, the catalyst component for the polymerization of olefins comprises a transition metal composition represented by the general formula [1] and [2]: (Ra Cp)m(R′b Cp)M(—X—Ar—Yc)4−(m+n) [1] R″(Rd Cp)(R′e Cp)M(—X—Ar—Yc)2 [2] wherein M is Ti, Zr or Hf; each of (Ra Cp), (R′b Cp), (Rd Cp) and (R″e Cp) is a radical having the cyclopentadienyl skeleton; R″ is a radical that links (Rd Cp) and (R′e Cp); (—X—Ar—Yc) is a grouping in which the aromatic ring Ar substituted by a specified radical Y bonds to M through an oxygen or sulphur atom X.
摘要翻译： 茂金属化合物可用作烯烃聚合的催化剂组分。 该化合物对空气和水分是稳定的，因此通过水解不产生卤化氢，易于处理，具有高储存稳定性和高催化剂活性。 具体地，用于烯烃聚合的催化剂组分包括由通式[1]和[2]表示的过渡金属组合物：其中M是Ti，Zr或Hf; （Ra Cp），（R'b Cp），（Rd Cp）和（R''e Cp）中的每一个是具有环戊二烯基骨架的基团; R“是连接（Rd Cp）和（R'e Cp）的基团; （-X-Ar-Yc）是其中被特定基团Y取代的芳环Ar经由氧或硫原子X与M键合的基团。
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公开(公告)号：US20010039360A1
公开(公告)日：2001-11-08
申请号：US09746146
申请日：2000-12-21
IPC分类号： C07F015/00
CPC分类号： C08F4/80 , B01J31/18 , B01J31/2265 , B01J31/24 , B01J31/2404 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07F15/002 , C07F15/0046 , C08F32/00 , C08G61/08
摘要： Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula 1 where M is Os or Ru; R1 is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X1 are independently selected from any anionic ligand; and L and L1 are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors. The ruthenium and osmium carbene compounds of the present invention may be used to catalyze olefin metathesis reactions including, but not limited to, ROMP, RCM, depolymerization of unsaturated polymers, synthesis of telechelic polymers, and olefin synthesis.
摘要翻译： 公开了在各种官能团存在下稳定并且可用于催化非限制性环状和无环烯烃上的烯烃复分解反应的钌和锇卡宾化合物。 还公开了制备卡宾化合物的方法。 卡宾化合物具有下式：其中M是Os或Ru; R1是氢; R选自氢，取代或未取代的烷基和取代或未取代的芳基; X和X 1独立地选自任何阴离子配体; L和L 1独立地选自任何中性给电子体。 本发明的钌和锇卡宾化合物可以使用重氮化合物，通过中性电子给体配体交换，通过交叉复分解，使用乙炔，使用累积的烯烃，以及使用重氮化合物和中性电子给体的一锅法合成。 本发明的钌和锇卡宾化合物可用于催化烯烃复分解反应，包括但不限于ROMP，RCM，不饱和聚合物的解聚，遥爪聚合物的合成和烯烃合成。
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