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    Brominated Styrenic Polymers and Their Preparation
    1.
    发明申请
    Brominated Styrenic Polymers and Their Preparation 有权
    溴化苯乙烯聚合物及其制备

    公开(公告)号：US20100081762A1

    公开(公告)日：2010-04-01

    申请号：US12631333

    申请日：2009-12-04

    申请人： Charles H. Kolich ,  Jeffrey Todd Aplin ,  John F. Balhoff

    发明人： Charles H. Kolich ,  Jeffrey Todd Aplin ,  John F. Balhoff

    IPC分类号： C08L25/06 ,  C08F112/08

    CPC分类号： C08F8/20 ,  C08F8/22 ,  C08F12/08 ,  C08F12/16 ,  C08F12/00 ,  C08F4/48

    摘要： Preparing brominated styrenic polymer by maintaining a mixture formed from (i) brominating agent, (ii) a solvent solution of styrenic polymer, and (iii) aluminum halide catalyst, at −20 to +20° C., and terminating bromination in 20 minutes or less. New brominated anionic styrenic polymers have better melt flow and/or lower initial ΔE values than the best previously-known brominated anionic styrenic polymers. Other features of such new polymers include high thermal stabilities at 320° C. and/or very low initial color values. Brominated styrenic polymers, especially brominated anionic styrenic polymers, are useful as flame retardants for thermoplastic polymers.

    摘要翻译： 通过保持由（i）溴化剂，（ii）苯乙烯聚合物的溶剂溶液和（iii）卤化铝催化剂）在-20至+ 20℃形成的混合物，并在20分钟内终止溴化，制备溴化苯乙烯聚合物 或更少。 新的溴化阴离子苯乙烯聚合物具有比最先前已知的溴代阴离子苯乙烯聚合物更好的熔体流动和/或较低的初始＆Dgr; E值。 这种新聚合物的其它特征包括在320℃下的高热稳定性和/或非常低的初始颜色值。 溴化苯乙烯聚合物，特别是溴化阴离子苯乙烯聚合物，可用作热塑性聚合物的阻燃剂。

    Terminating Bromination of Styrenic Polymer in a Bromination Reaction Mixture
    2.
    发明申请
    Terminating Bromination of Styrenic Polymer in a Bromination Reaction Mixture 审中-公开
    在溴化反应混合物中终止苯乙烯聚合物的溴化

    公开(公告)号：US20090264599A1

    公开(公告)日：2009-10-22

    申请号：US12375549

    申请日：2007-08-22

    申请人： John F. Balhoff ,  Charles H. Kolich

    发明人： John F. Balhoff ,  Charles H. Kolich

    IPC分类号： C08F8/20

    CPC分类号： C08F8/20 ,  C08F12/00

    摘要： A brominated styrenic polymer reaction mixture containing at least (i) brominated styrenic polymer, (ii) bromination reaction solvent, (iii) hydrogen bromide, and (iv) Lewis acid bromination catalyst, and an aqueous medium in an amount sufficient to deactivate the Lewis acid catalyst but insufficient to form a separate continuous liquid phase in the resultant mixture are mixed together to terminate bromination. The advantages of using such small amounts of aqueous medium, as well as various follow on procedures are described.

    摘要翻译： 含有至少（i）溴化苯乙烯类聚合物，（ⅱ）溴化反应溶剂，（ⅲ）溴化氢和（ⅳ）路易斯酸溴化催化剂的溴化苯乙烯类聚合物反应混合物和含量足以使路易斯酸失活的水性介质 酸催化剂但不足以在所得混合物中形成单独的连续液相混合在一起以终止溴化。 描述了使用这种少量水性介质的优点以及各种方法。

    Preparation of brominated styrenic polymers or resins
    3.
    发明授权
    Preparation of brominated styrenic polymers or resins 有权
    制备溴化苯乙烯聚合物或树脂

    公开(公告)号：US07446153B2

    公开(公告)日：2008-11-04

    申请号：US11612705

    申请日：2006-12-19

    申请人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    发明人： Charles H. Kolich ,  John F. Balhoff ,  Martin B. Berdon ,  Ronny W. Lin

    IPC分类号： C08F8/18

    CPC分类号： C08F8/20 ,  C08F12/16 ,  C08F12/00

    摘要： Bromination of styrenic polymer is carried out in a closed reaction system to retain HX coproduct (where HX is HBr or HCl, or both) in the bromination reaction mixture at superatmospheric pressure. Preferably, the reaction mixture which includes the brominated styrenic polymer and substantially all of the HX coproduct formed is discharged into an aqueous quenching medium. By operating in this manner, the reaction is terminated and the brominated styrenic polymer of desired bromine content and substantially all HX coproduct are captured in the same operation, process equipment costs are reduced, and processing of the reaction mixture is facilitated.

    摘要翻译： 苯乙烯聚合物的溴化在闭合反应体系中进行，以在超大气压下在溴化反应混合物中保留HX副产物（其中HX为HBr或HCl或两者）。 优选地，将包含溴化苯乙烯聚合物和基本上所有形成的HX副产物的反应混合物排出到含水淬火介质中。 以这种方式操作，终止反应，并且在相同的操作中捕获所需溴含量和基本上所有HX副产物的溴化苯乙烯聚合物，降低了工艺设备成本，并且促进了反应混合物的加工。

    Urethane oligomers of heterotelechelic amine functional polyolefins
    8.
    发明申请
    Urethane oligomers of heterotelechelic amine functional polyolefins 审中-公开
    聚异戊烯胺官能聚烯烃的聚氨酯低聚物

    公开(公告)号：US20030069366A1

    公开(公告)日：2003-04-10

    申请号：US10245451

    申请日：2002-09-17

    发明人： Robert J. Letchford ,  Thorsten Brockmann ,  John F. Engel ,  James A. Schwindeman ,  John L. Greak

    IPC分类号： C08F036/00

    CPC分类号： C08L19/006 ,  C08F8/32 ,  C08F12/00

    摘要： The present invention provides urethane oligomers of null,functional heterotelechelic polymers, and in particular heterotelechelic polyolefins having at least one terminal hydroxyl functionality and one other terminal functional group which is different from the hydroxyl functionality, such as an amine functional group. The oligomers of the invention can exhibit toughness, chemical resistance and other desired properties. The oligomers can also exhibit improved flexibility and impact resistance, due to the incorporation of the polyolefinic backbone. Thus the oligomers can be used in a variety of applications, including without limitation coatings, sealants, adhesives, and composites (prepregs). The heterotelechelic polyolefin is advantageously prepared via anionic polymerization using lithium initiators, and in particular functionalized lithium initiators having a protected hydroxy functionality as known in the art. The resulting living chain end can be functionalized using an amine functionalized electrophile, in which typically the amine group is protected. Alternatively amine protected functionalized initiators can used and the resulting living polymer functionalized using a hydroxy functionalizing electrophile. Protecting groups, when present, are removed to liberate the desired functionalities.

    摘要翻译： 本发明提供了阿姆斯特丹的氨基甲酸酯低聚物，功能杂多炔类聚合物， 特别是具有至少一个末端羟基官能团和与羟基官能团不同的另一个末端官能团的杂多烯烃聚烯烃，例如胺官能团。 本发明的低聚物可表现出韧性，耐化学性和其它期望的性能。 由于聚烯烃主链的并入，低聚物也可以表现出改进的柔韧性和耐冲击性。 因此，低聚物可用于各种应用，包括但不限于涂料，密封剂，粘合剂和复合材料（预浸料）。 通过使用锂引发剂，特别是具有本领域已知的被保护的羟基官能团的官能化锂引发剂，有利地通过阴离子聚合来制备杂亚油酰基聚烯烃。 所得的活性链端可以使用胺官能化的亲电试剂进行官能化，其中通常胺基被保护。 或者可以使用胺保护的官能化引发剂，并且所得活性聚合物使用羟基官能化亲电试剂官能化。 保护组（当存在时）被去除以释放所需的功能。

    Hydrogenated polymers, resin composition, and process for producing substrate for information-recording medium
    10.
    发明授权
    Hydrogenated polymers, resin composition, and process for producing substrate for information-recording medium 有权
    氢化聚合物，树脂组合物和用于制备信息记录介质的底物的方法

    公开(公告)号：US06433102B1

    公开(公告)日：2002-08-13

    申请号：US09856156

    申请日：2001-09-04

    申请人： Teruhiko Suzuki ,  Tsutomu Nagamune ,  Teiji Kohara ,  Toshihide Murakami ,  Haruhiko Takahashi

    发明人： Teruhiko Suzuki ,  Tsutomu Nagamune ,  Teiji Kohara ,  Toshihide Murakami ,  Haruhiko Takahashi

    IPC分类号： C08F804

    CPC分类号： G11B7/2533 ,  C08F8/04 ,  G11B5/7315 ,  G11B5/8404 ,  G11B7/252 ,  G11B7/2534 ,  G11B7/2535 ,  G11B7/2536 ,  G11B7/254 ,  G11B7/256 ,  G11B7/2578 ,  G11B7/2585 ,  G11B7/2595 ,  G11B7/263 ,  G11B11/10582 ,  G11B2007/24304 ,  C08F12/00

    摘要： A hydrogenated product of an aromatic vinyl polymer, wherein the hydrogenation rate of the aromatic rings thereof is at least 97%, a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) is at most 2.0, the weight average molecular weight (Mw) is 100,000 to 300,000, and the content of a component having a molecular weight (M) of at most 10,000 is at most 2% by weight based on the total weight of the polymer; a hydrogenated product of an aromatic vinyl polymer, wherein the content of foreign matter having a particle diameter of at least 0.5 &mgr;m in the hydrogenated polymer is at most 3.0×104 particles/g; and a substrate for information recording media obtained by molding a resin material containing a hydrogenated product of an aromatic vinyl polymer, wherein the hydrogenation rate of the aromatic rings thereof is at least 97%, a :ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) is at most 2.0, and the weight average molecular weight (Mw) is 100,000 to 300,000, and production process thereof.

    摘要翻译： 芳香族乙烯基聚合物的氢化物，其芳香环的氢化率为97％以上，重均分子量（Mw）与数均分子量（Mn）的比（Mw / Mn）为 至多2.0，重均分子量（Mw）为100,000至300,000，并且基于聚合物的总重量，分子量（M）至多为10,000的组分的含量为至多2重量％; 芳香族乙烯基聚合物的氢化物，氢化聚合物中粒径为0.5μm以上的异物含量为3.0×10 4个/ g以下; 以及通过模塑含有芳香族乙烯基聚合物的氢化物的树脂材料而获得的信息记录介质的基板，其中芳香族环的氢化率为97％以上，a：重均分子量比（Mw / Mn） 分子量（Mw）与数均分子量（Mn）之比为2.0以下，重均分子量（Mw）为100,000〜300,000及其制造方法。