公开(公告)号：US09567475B1

公开(公告)日：2017-02-14

申请号：US15298637

申请日：2016-10-20

申请人： SIRRUS, INC.

发明人： Aniruddha S. Palsule ,  Jeffrey M. Sullivan ,  Katherine E. Vanderpool ,  Alexander R. Holzer ,  Anushree Deshpande ,  John Klier

IPC分类号： C08L33/14 ,  C08L67/06 ,  B32B27/00 ,  B05D3/02 ,  C09D133/06 ,  C08L33/00

CPC分类号： C09D167/06 ,  C08G63/00 ,  C08G63/553 ,  C08G63/676 ,  C08G63/78 ,  C08L67/06 ,  C09D133/06 ,  C09D167/02 ,  C12P7/625 ,  C08L83/04 ,  C08L79/02

摘要： Compositions comprising a) one or more polyester macromers containing one or more chains of the residue of one or more diols and one or more diesters wherein the residue of the one or more diols and the one or more diesters alternate along the chain and a portion of the diesters are 1,1-diester-1-alkenes and at least one terminal end comprises the residue of one of the 1,1-diester-1 alkenes and wherein one or more terminal ends may comprise the residue of one or more diols; and b) one or more polymers having pendant Michael Addition donor groups. Disclosed are coating prepared from these compositions.

摘要翻译： 组合物，其包含a）一种或多种聚酯大分子单体，其含有一个或多个一个或多个二醇残基的链和一个或多个二酯，其中一个或多个二醇的残基和一个或多个二酯沿着链交替， 二酯是1,1-二酯-1-烯烃，并且至少一个末端包含1,1-二酯-1-烯烃之一的残基，并且其中一个或多个末端可以包含一个或多个二醇的残基; 和b）一种或多种具有侧链迈克尔加成供体基团的聚合物。 公开了由这些组合物制备的涂层。

公开(公告)号：US20160369359A1

公开(公告)日：2016-12-22

申请号：US15183930

申请日：2016-06-16

申请人： Rohm and Haas Company

发明人： Joy A. Gallagher ,  Philip R. Harsh ,  Pu Luo ,  Edwin Nungesser

IPC分类号： C14C11/00 ,  C09D5/00 ,  C09D133/12

CPC分类号： C14C11/003 ,  C09D4/06 ,  C09D5/00 ,  C09D133/06 ,  C09D133/12 ,  C08F230/02

摘要： The present invention relates to a composition comprising an aqueous dispersion of submicron-sized polymer particles and micron-sized polymer beads, wherein the polymer particles or beads or both are functionalized with phosphorus acid groups. The composition of the present invention is useful for providing a matte finish on substrates, such as leather, textiles, wallboard, decorative coatings, concrete, and wood, with improved stain resistance. The present invention also relates to a leather substrate coated with a clear matte finish comprising an acrylic or styrene-acrylic polymer film and micron-sized polymer beads, wherein the film or the beads or both are functionalized with a phosphorus acid monomer.

摘要翻译： 本发明涉及一种组合物，其包含亚微米级聚合物颗粒和微米级聚合物颗粒的水性分散体，其中聚合物颗粒或珠或两者均用磷酸基团官能化。 本发明的组合物可用于在诸如皮革，纺织品，墙板，装饰性涂料，混凝土和木材的基材上提供无光饰面，并具有改善的耐污性。 本发明还涉及一种涂有透明无光饰面的皮革基材，其包含丙烯酸或苯乙烯 - 丙烯酸聚合物膜和微米级聚合物珠，其中该膜或珠或两者均用磷酸单体官能化。

公开(公告)号：US20160311754A1

公开(公告)日：2016-10-27

申请号：US15135144

申请日：2016-04-21

申请人： NDSU RESEARCH FOUNDATION

发明人： Dean C. WEBSTER ,  Arvin YU

IPC分类号： C07C69/602 ,  C09D133/10 ,  C07C67/04

CPC分类号： C09D133/10 ,  C07C69/67 ,  C09D133/06 ,  C09D133/08 ,  C08L67/00

摘要： The invention relates to a polyfunctional bio-based oligomer which is the reaction product of a) at least one epoxidized sucrose fatty acid ester resin; b) at least one ethylenically unsaturated acid selected from methacrylic acid, acrylic acid, crotonic acid, and mixtures thereof; c) at least one acid anhydride selected from acetic acid anhydride, acrylic acid anhydride, methacrylic acid anhydride, crotonic acid anhydride, and mixtures thereof; d) optionally, at least one catalyst; and e) optionally, at least one inhibitor. In a polyfunctional bio-based oligomer of the invention, the ratio of ethylenically unsaturated acid to acid anhydride ranges from 90:1 to 1:90; at least one epoxide group of the at least one epoxidized sucrose fatty acid ester resin is esterified by at least one ethylenically unsaturated acid; and at least one epoxide group of the at least one epoxidized sucrose fatty acid ester resin is esterified by at least one acid anhydride. Other embodiments of the invention relate to methods of making the polyfunctional bio-based oligomers of the invention and to curable coating compositions containing them.

摘要翻译： 本发明涉及多官能生物基低聚物，其是a）至少一种环氧化蔗糖脂肪酸酯树脂的反应产物; b）至少一种选自甲基丙烯酸，丙烯酸，巴豆酸及其混合物的烯属不饱和酸; c）至少一种选自乙酸酐，丙烯酸酐，甲基丙烯酸酐，巴豆酸酐及其混合物的酸酐; d）任选的至少一种催化剂; 和e）任选的至少一种抑制剂。 在本发明的多官能生物基低聚物中，烯键式不饱和酸与酸酐的比例为90:1至1:90; 所述至少一种环氧化蔗糖脂肪酸酯树脂的至少一个环氧基被至少一种烯属不饱和酸酯化; 并且所述至少一种环氧化蔗糖脂肪酸酯树脂的至少一个环氧基团被至少一种酸酐酯化。 本发明的其它实施方案涉及制备本发明的多官能生物基低聚物和含有它们的可固化涂料组合物的方法。

公开(公告)号：US20160311725A1

公开(公告)日：2016-10-27

申请号：US14692205

申请日：2015-04-21

申请人： Behr Process Corporation

发明人： Hector Antonio PEREZ

IPC分类号： C04B41/63 ,  C04B41/45 ,  C04B41/48

CPC分类号： C04B41/63 ,  C04B41/4596 ,  C04B41/483 ,  C08K3/34 ,  C08K7/00 ,  C08K7/04 ,  C08K2201/005 ,  C09D5/02 ,  C09D5/027 ,  C09D5/028 ,  C09D7/70 ,  C09D133/00 ,  C09D133/06 ,  C09D133/08

摘要： A coating composition includes water, a plurality of flakes having a maximum dimension less than 0.05 inches, a plurality of inorganic fibers, a thixotropic suspending agent that is insoluble in water, and a resin. Decorative coating on a concrete substrate is also provided.

摘要翻译： 涂料组合物包括水，最大尺寸小于0.05英寸的多个薄片，多个无机纤维，不溶于水的触变悬浮剂和树脂。 还提供了在混凝土基板上的装饰涂层。

公开(公告)号：US09475953B2

公开(公告)日：2016-10-25

申请号：US14613521

申请日：2015-02-04

申请人： Arkema Inc.

发明人： Wenjun Wu ,  Jeffrey A. Schneider ,  Albert R. Miner, II

IPC分类号： C09D131/04 ,  C08L31/04 ,  C09D133/06

CPC分类号： C09D131/04 ,  B05D3/007 ,  C08L31/04 ,  C08L2201/52 ,  C08L2203/16 ,  C09D133/06 ,  C08L2666/04

摘要： Embodiments include coating compositions, methods of coating a substrate, and substrates having at least one surface coated according to the methods of the present disclosure. The aqueous, substantially volatile organic compound (VOC)-free coating compositions includes an acrylic latex and a vinyl acetate-ethylene latex including from about 10 to about 90 weight percent of a vinyl acetate-ethylene polymer, based on total weight of acrylic polymer and vinyl acetate-ethylene polymer, having a Tg from about −20 to about 20 degrees Celsius; and from about 10 to about 90 weight percent of an acrylic polymer, based on the total weight of acrylic polymer and vinyl acetate-ethylene polymer, the acrylic polymer comprising, in polymerized form, at least one ethylenically unsaturated (meth)acrylic monomer and from about 0.01 to about 10 weight percent, based on total weight of the acrylic polymer, of an acetoacetate moiety containing monomer, where the acrylic polymer has a Tg of from about −20 to about 20 degrees Celsius.

摘要翻译： 实施方案包括涂料组合物，涂布基材的方法和具有根据本公开的方法涂覆的至少一个表面的基材。 含水的，基本上挥发性的挥发性有机化合物（VOC）的涂料组合物包括丙烯酸胶乳和乙酸乙烯酯 - 乙烯胶乳，其包含约10至约90重量％的乙酸乙烯酯 - 乙烯聚合物，基于丙烯酸聚合物的总重量和 乙酸乙烯酯 - 乙烯聚合物，具有约-20至约20摄氏度的Tg; 和约10至约90重量％的丙烯酸类聚合物，基于丙烯酸聚合物和乙酸乙烯酯 - 乙烯聚合物的总重量，丙烯酸类聚合物包含聚合形式的至少一种烯属不饱和（甲基）丙烯酸单体和 约0.01至约10重量％，基于丙烯酸类聚合物的总重量，含乙酰乙酸酯部分的单体，其中丙烯酸类聚合物的Tg为约-20至约20摄氏度。

公开(公告)号：US09458345B2

公开(公告)日：2016-10-04

申请号：US13976830

申请日：2011-12-28

申请人： David James Telford ,  Kenneth James Gardner ,  Ryan Roberts, Sr. ,  Tiffany Weidendorf ,  Denise E. Yancey

发明人： David James Telford ,  Kenneth James Gardner ,  Ryan Roberts, Sr. ,  Tiffany Weidendorf ,  Denise E. Yancey

IPC分类号： C09D133/06 ,  C09D151/00 ,  C08F267/06

CPC分类号： C09D133/06 ,  C08F267/06 ,  C09D151/00 ,  Y10T428/1352 ,  C08F212/08 ,  C08F220/28 ,  C08F220/18 ,  C08F220/06

摘要： The present invention includes coating compositions and methods for coating substrates using the coating compositions. In some embodiments of the invention, a coating composition is prepared by a method including the steps of a) preparing a latex emulsion by a method including mixing an ethylenically unsaturated monomer component in a carrier to form a monomer emulsion, and reacting the monomer emulsion with an initiator to form the latex emulsion, b) preparing a hydroxyl functional oil graft copolymer by a method including reacting an epoxidized vegetable oil with a hydroxyl functional material in the presence of an acid catalyst to form a hydroxyl functional oil polyol, and reacting the hydroxyl functional oil polyol with an ethylenically unsaturated monomer component in the presence of an initiator to form the hydroxyl functional oil polyol graft copolymer, and c) blending the latex emulsion and a crosslinker then adding the hydroxyl functional oil graft copolymer to form the coating composition. The coating compositions may exhibit no or minimal blush, no or minimal color pick-up, and commercially acceptable adhesion. Substrates coated with the coating compositions of the invention are also disclosed.

摘要翻译： 本发明包括涂料组合物和使用该涂料组合物涂覆基材的方法。 在本发明的一些实施方案中，通过包括以下步骤的方法制备涂料组合物：a）通过包括在载体中混合烯属不饱和单体组分以形成单体乳液并使单体乳液与 引发剂以形成胶乳乳液，b）通过在酸催化剂存在下使环氧化植物油与羟基官能物质反应形成羟基官能油多羟基化合物的方法制备羟基官能油接枝共聚物，并使羟基 在引发剂存在下使用具有烯键式不饱和单体成分的官能油多元醇形成羟基官能油多元醇接枝共聚物，和c）将胶乳乳液和交联剂共混，然后加入羟基官能油接枝共聚物以形成涂料组合物。 涂料组合物可以表现出没有或最少的腮红，没有或最少的颜色吸收和商业上可接受的粘附。 还公开了涂覆有本发明的涂料组合物的基材。

公开(公告)号：US09404007B2

公开(公告)日：2016-08-02

申请号：US14144686

申请日：2013-12-31

申请人： HONEYWELL INTERNATIONAL INC.

发明人： George Leotsakos ,  Wayne M. Gravatt ,  Christopher P. Smith ,  Michael A. Kocur

IPC分类号： C08L91/06 ,  C09D11/12 ,  C09D133/06 ,  C08K9/10 ,  C09D133/08 ,  C08K5/06 ,  C08K5/42 ,  C08L23/06

CPC分类号： C09D133/06 ,  C08K5/06 ,  C08K5/42 ,  C08K9/10 ,  C08L23/06 ,  C08L91/06 ,  C09D11/12 ,  C09D133/08

摘要： Aqueous wax dispersions useful as surface modifiers for paints, inks and coatings. More particularly, aqueous particulate wax dispersions useful as surface modifiers to provide improved properties in primers, paints, inks and other coating formulations. The dispersions are stable, substantially homogenous, have a high solids concentration at low viscosities, and comply with the applicable FDA regulations for use in food packaging applications.

摘要翻译： 水性蜡分散体可用作油漆，油墨和涂料的表面改性剂。 更具体地，可用作表面改性剂的水性颗粒状蜡分散体，以在底漆，油漆，油墨和其它涂料配方中提供改进的性能。 分散体是稳定的，基本均匀的，在低粘度下具有高固体浓度，并且符合食品包装应用中适用的FDA规定。

公开(公告)号：US09360592B2

公开(公告)日：2016-06-07

申请号：US14618161

申请日：2015-02-10

申请人： 3M INNOVATIVE PROPERTIES COMPANY

发明人： Bryan V. Hunt ,  Judith M. Invie ,  Anthony M. Renstrom ,  David B. Olson

IPC分类号： G02B1/04 ,  C08L33/14 ,  F21V8/00 ,  C08F290/06 ,  C09D4/06

CPC分类号： G02B5/0231 ,  C08F290/06 ,  C08L33/14 ,  C09D4/06 ,  C09D133/06 ,  C09D133/16 ,  G02B1/04 ,  G02B6/0053 ,  Y10T428/24355 ,  Y10T428/264 ,  Y10T428/265

摘要： Presently described are optical films, such as a brightness enhancing film, having a polymerized microstructured surface disposed on a preformed polymeric film wherein the film has a thickness of no greater than 3 mils and the polymerized microstructured surface consists of the reaction product of a substantially non-brominated polymerizable resin composition.

公开(公告)号：US09334400B2

公开(公告)日：2016-05-10

申请号：US14005633

申请日：2012-03-16

申请人： Motonobu Matsuyama ,  Masayuki Haraguchi ,  Masaaki Ozawa

发明人： Motonobu Matsuyama ,  Masayuki Haraguchi ,  Masaaki Ozawa

IPC分类号： C08F2/46 ,  C08F2/50 ,  C08G61/04 ,  C08L33/10 ,  C08F4/04 ,  C08F220/18 ,  C08F22/10 ,  C09D133/06 ,  C08F222/10 ,  C08F230/08

CPC分类号： C08L33/10 ,  C08F2/50 ,  C08F4/04 ,  C08F22/10 ,  C08F220/18 ,  C08F222/1006 ,  C08F230/08 ,  C08F257/00 ,  C08F265/06 ,  C08F267/06 ,  C08F2220/1833 ,  C09D133/06

摘要： There is provided a highly branched lipophilic polymer that is excellent in blending and dispersing properties in a matrix resin, and is possible to provide surface modification properties such as excellent lipophilicity (anti-fingerprint property) and the like to a coating that is obtained from the resin composition while the intrinsic transparency of the resin is not impaired; and a photopolymeizable composition comprising the highly branched lipophilic polymer. A highly branched lipophilic polymer obtained by polymerizing a monomer A containing two or more radically polymerizable double bonds per molecule and a monomer B containing a C6-30 alkyl group or a C3-30 alicyclic group and at least one radically polymerizable double bond per molecule in the presence of 5 to 200 mol % of a polymerization initiator C relative to the number of moles of the monomer A. A photopolymeizable composition comprising the highly branched lipophilic polymer.

摘要翻译： 提供了一种在基质树脂中具有优异的共混和分散性能的高度支化的亲脂性聚合物，并且可以提供表面改性性质，例如从亲水性聚合物获得的涂料具有优异的亲油性（抗指纹性）等 树脂组合物，而树脂的固有透明度不受损害; 和包含高支化亲脂性聚合物的光聚合组合物。 通过聚合每分子含有两个或更多个可自由基聚合的双键的单体A和每分子含有C 6-30烷基或C 3-30脂环族基团和至少一个可自由基聚合的双键的单体B而获得的高度支化的亲脂性聚合物 相对于单体A的摩尔数，存在5〜200摩尔％的聚合引发剂C.含有高支化亲脂性聚合物的光聚合性组合物。

公开(公告)号：US09259598B2

公开(公告)日：2016-02-16

申请号：US11637655

申请日：2006-12-12

申请人： Ray F. Stewart ,  Natarajan Balachander ,  Steven P. Bitler ,  Loc Phan ,  Valentine Y. Yoon

发明人： Ray F. Stewart ,  Natarajan Balachander ,  Steven P. Bitler ,  Loc Phan ,  Valentine Y. Yoon

IPC分类号： A61K9/00 ,  A61K9/50 ,  A61Q5/06 ,  A01C1/06 ,  A61K8/02 ,  A61K8/81 ,  A61Q5/00 ,  B05D7/00 ,  C09D133/14 ,  D06M15/263

CPC分类号： A61Q5/06 ,  A01C1/06 ,  A61K8/0237 ,  A61K8/8152 ,  A61K8/8158 ,  A61K2800/54 ,  A61Q5/00 ,  B05D7/00 ,  C08F2/20 ,  C08F220/18 ,  C09D4/00 ,  C09D5/022 ,  C09D133/06 ,  C09D133/14 ,  D06M15/263 ,  D06M2200/20 ,  C08F2220/1891 ,  C08F2220/1841 ,  C08F220/06 ,  C08F2222/1013

摘要： Aqueous dispersions of crystalline polymers based on hydrophobic monomers, preferably on a mixture of hydrophobic and hydrophilic monomers which contains a crosslinking monomer, particularly side chain crystalline (SCC) polymers. The dispersions are useful for providing coatings on substrates, particularly on seeds (whose dormancy is thus extended) and on fibrous substrates, particularly human hair (which thus becomes heat-settable).