公开(公告)号：US09458345B2

公开(公告)日：2016-10-04

申请号：US13976830

申请日：2011-12-28

申请人： David James Telford ,  Kenneth James Gardner ,  Ryan Roberts, Sr. ,  Tiffany Weidendorf ,  Denise E. Yancey

发明人： David James Telford ,  Kenneth James Gardner ,  Ryan Roberts, Sr. ,  Tiffany Weidendorf ,  Denise E. Yancey

IPC分类号： C09D133/06 ,  C09D151/00 ,  C08F267/06

CPC分类号： C09D133/06 ,  C08F267/06 ,  C09D151/00 ,  Y10T428/1352 ,  C08F212/08 ,  C08F220/28 ,  C08F220/18 ,  C08F220/06

摘要： The present invention includes coating compositions and methods for coating substrates using the coating compositions. In some embodiments of the invention, a coating composition is prepared by a method including the steps of a) preparing a latex emulsion by a method including mixing an ethylenically unsaturated monomer component in a carrier to form a monomer emulsion, and reacting the monomer emulsion with an initiator to form the latex emulsion, b) preparing a hydroxyl functional oil graft copolymer by a method including reacting an epoxidized vegetable oil with a hydroxyl functional material in the presence of an acid catalyst to form a hydroxyl functional oil polyol, and reacting the hydroxyl functional oil polyol with an ethylenically unsaturated monomer component in the presence of an initiator to form the hydroxyl functional oil polyol graft copolymer, and c) blending the latex emulsion and a crosslinker then adding the hydroxyl functional oil graft copolymer to form the coating composition. The coating compositions may exhibit no or minimal blush, no or minimal color pick-up, and commercially acceptable adhesion. Substrates coated with the coating compositions of the invention are also disclosed.

摘要翻译： 本发明包括涂料组合物和使用该涂料组合物涂覆基材的方法。 在本发明的一些实施方案中，通过包括以下步骤的方法制备涂料组合物：a）通过包括在载体中混合烯属不饱和单体组分以形成单体乳液并使单体乳液与 引发剂以形成胶乳乳液，b）通过在酸催化剂存在下使环氧化植物油与羟基官能物质反应形成羟基官能油多羟基化合物的方法制备羟基官能油接枝共聚物，并使羟基 在引发剂存在下使用具有烯键式不饱和单体成分的官能油多元醇形成羟基官能油多元醇接枝共聚物，和c）将胶乳乳液和交联剂共混，然后加入羟基官能油接枝共聚物以形成涂料组合物。 涂料组合物可以表现出没有或最少的腮红，没有或最少的颜色吸收和商业上可接受的粘附。 还公开了涂覆有本发明的涂料组合物的基材。

公开(公告)号：US20130280454A1

公开(公告)日：2013-10-24

申请号：US13976830

申请日：2011-12-28

申请人： David James Telford ,  Kenneth James Gardner ,  Ryan Roberts, SR. ,  Tiffany Weidendorf ,  Denise E. Yancey

发明人： David James Telford ,  Kenneth James Gardner ,  Ryan Roberts, SR. ,  Tiffany Weidendorf ,  Denise E. Yancey

IPC分类号： C09D133/06

CPC分类号： C09D133/06 ,  C08F267/06 ,  C09D151/00 ,  Y10T428/1352 ,  C08F212/08 ,  C08F220/28 ,  C08F220/18 ,  C08F220/06

摘要： The present invention includes coating compositions and methods for coating substrates using the coating compositions. In some embodiments of the invention, a coating composition is prepared by a method including the steps of a) preparing a latex emulsion by a method including mixing an ethylenically unsaturated monomer component in a carrier to form a monomer emulsion, and reacting the monomer emulsion with an initiator to form the latex emulsion, b) preparing a hydroxyl functional oil graft copolymer by a method including reacting an epoxidized vegetable oil with a hydroxyl functional material in the presence of an acid catalyst to form a hydroxyl functional oil polyol, and reacting the hydroxyl functional oil polyol with an ethylenically unsaturated monomer component in the presence of an initiator to form the hydroxyl functional oil polyol graft copolymer, and c) blending the latex emulsion and a crosslinker then adding the hydroxyl functional oil graft copolymer to form the coating composition. The coating compositions may exhibit no or minimal blush, no or minimal color pick-up, and commercially acceptable adhesion. Substrates coated with the coating compositions of the invention are also disclosed.

摘要翻译： 本发明包括涂料组合物和使用该涂料组合物涂覆基材的方法。 在本发明的一些实施方案中，通过包括以下步骤的方法制备涂料组合物：a）通过包括在载体中混合烯属不饱和单体组分以形成单体乳液并使单体乳液与 引发剂以形成胶乳乳液，b）通过在酸催化剂存在下使环氧化植物油与羟基官能物质反应形成羟基官能油多羟基化合物的方法制备羟基官能油接枝共聚物，并使羟基 在引发剂存在下使用具有烯键式不饱和单体成分的官能油多元醇形成羟基官能油多元醇接枝共聚物，和c）将胶乳乳液和交联剂共混，然后加入羟基官能油接枝共聚物以形成涂料组合物。 涂料组合物可以表现出没有或最少的腮红，没有或最少的颜色吸收和商业上可接受的粘附。 还公开了涂覆有本发明的涂料组合物的基材。

公开(公告)号：US20130281574A1

公开(公告)日：2013-10-24

申请号：US13996600

申请日：2011-12-28

申请人： Cathy Li ,  Tiffany Weidendorf ,  Timothy I. Memmer ,  Daniel Bode

发明人： Cathy Li ,  Tiffany Weidendorf ,  Timothy I. Memmer ,  Daniel Bode

IPC分类号： C09D133/04

CPC分类号： C09D133/04 ,  B65D25/14 ,  C08F2/001 ,  C08F2/22 ,  C08F265/06 ,  C09D5/20 ,  C09D133/062 ,  C09D133/068 ,  C09D151/003 ,  C08F220/18 ,  C08F220/32 ,  C08F220/28

摘要： Latex emulsions are disclosed which can be used in the formation of coating compositions that are not water sensitive have good blush resistance and retortability. In some embodiments, the coating compositions are used to coat substrates such as cans and packaging materials for the storage of food and beverages. Coating compositions of the invention may be prepared by polymerizing at least one ethylenically unsaturated monomer component, a stabilizer comprising a strong acid and an initiator in a carrier to form an emulsion, polymerizing the emulsion with at least one different ethylenically unsaturated monomer component to prepare the composite latex emulsion, and reacting the composite latex emulsion with a neutralizer to form the coating composition. Methods of coating substrates with the coating compositions, and substrates coated with the coating compositions are also disclosed.

摘要翻译： 公开了可用于形成不具有水敏性的涂料组合物的乳胶乳液，其具有良好的抗沾红和耐蒸煮性能。 在一些实施方案中，涂料组合物用于涂覆底物例如罐和包装材料以储存食品和饮料。 本发明的涂料组合物可以通过在载体中聚合至少一种烯键式不饱和单体组分，包含强酸和引发剂的稳定剂以形成乳液，使乳液与至少一种不同的烯属不饱和单体组分聚合以制备 复合胶乳乳液，并使复合胶乳乳液与中和剂反应形成涂料组合物。 还公开了用涂料组合物涂布基材的方法和涂覆有涂料组合物的基材。

公开(公告)号：US09181448B2

公开(公告)日：2015-11-10

申请号：US13996600

申请日：2011-12-28

申请人： Cathy Li ,  Tiffany Weidendorf ,  Timothy I. Memmer ,  Daniel Bode

发明人： Cathy Li ,  Tiffany Weidendorf ,  Timothy I. Memmer ,  Daniel Bode

IPC分类号： C09D151/00 ,  C08F6/14 ,  C08F2/00 ,  C08F2/22 ,  C09D133/06 ,  B65D25/14 ,  C09D133/04 ,  C09D5/20 ,  C08F265/06

CPC分类号： C09D133/04 ,  B65D25/14 ,  C08F2/001 ,  C08F2/22 ,  C08F265/06 ,  C09D5/20 ,  C09D133/062 ,  C09D133/068 ,  C09D151/003 ,  C08F220/18 ,  C08F220/32 ,  C08F220/28

摘要： Latex emulsions are disclosed which can be used in the formation of coating compositions that are not water sensitive, have good blush resistance and retortability. In some embodiments, the coating compositions are used to coat substrates such as cans and packaging materials for the storage of food and beverages. Coating compositions of the invention may be prepared by polymerizing at least one ethylenically unsaturated monomer component, a stabilizer comprising a strong acid and an initiator in a carrier to form an emulsion, polymerizing the emulsion with at least one different ethylenically unsaturated monomer component to prepare the composite latex emulsion, and reacting the composite latex emulsion with a neutralizer to form the coating composition. Methods of coating substrates with the coating compositions, and substrates coated with the coating compositions are also disclosed.

摘要翻译： 公开了乳胶乳液，其可用于形成不具有水敏感性，具有良好抗腮红性和耐蒸煮性的涂料组合物。 在一些实施方案中，涂料组合物用于涂覆底物例如罐和包装材料以储存食品和饮料。 本发明的涂料组合物可以通过在载体中聚合至少一种烯键式不饱和单体组分，包含强酸和引发剂的稳定剂以形成乳液，使乳液与至少一种不同的烯属不饱和单体组分聚合以制备 复合胶乳乳液，并使复合胶乳乳液与中和剂反应形成涂料组合物。 还公开了用涂料组合物涂布基材的方法和涂覆有涂料组合物的基材。