公开(公告)号：US5177280A

公开(公告)日：1993-01-05

申请号：US534229

申请日：1990-06-07

Applicant: Bernard Juguin ,  Pierre Dufresne ,  Francis Raatz ,  Germain Martino

Inventor： Bernard Juguin ,  Pierre Dufresne ,  Francis Raatz ,  Germain Martino

IPC: B01J29/08 ,  B01J29/18 ,  C07B61/00 ,  C07C2/66 ,  C07C2/70 ,  C07C6/12 ,  C07C15/02 ,  C07C15/073 ,  C07C15/085

CPC classification number: C07C15/085 ,  C07C15/02 ,  C07C15/073 ,  C07C2/66 ,  C07C6/126 ,  C07C2529/08 ,  C07C2529/18 ,  Y02P20/52

Abstract: The invention relates to a process for producing an alkylbenzene from benzene and an aliphatic mono-olefin in the presence of a catalyst based on a dealuminized Y zeolite with a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 ranging from 8 to 70, the product of this reaction being afterwards fractionated into a first fraction containing non converted benzene and a mono-alkylbenzene and a second fraction containing a poly-alkylbenzene, said second fraction reacting then with benzene in the presence of a catalyst based on a dealuminized mordenite with a total atomic ratio Si/Al ranging from 30 to 80. The invention especially applies to the production of ethylbenzene and cumene respectively from ethylene and propene.

Abstract translation: 本发明涉及一种在基于SiO 2 / Al 2 O 3的摩尔比为8至70的脱铝Y沸石的催化剂存在下由苯和脂族单烯烃生产烷基苯的方法，该反应产物之后 分馏成含有未转化的苯和单烷基苯的第一馏分和含有聚烷基苯的第二馏分，所述第二馏分在基于脱铝丝光沸石的催化剂存在下与苯反应，总原子比Si / Al 范围从30到80.本发明特别适用于从乙烯和丙烯生产乙苯和枯烯。

公开(公告)号：US4780436A

公开(公告)日：1988-10-25

申请号：US904081

申请日：1986-09-04

Applicant: Francis Raatz ,  Christian Marcilly ,  Pierre Dufresne

Inventor： Francis Raatz ,  Christian Marcilly ,  Pierre Dufresne

IPC: C10G35/095 ,  B01J29/00 ,  B01J29/06 ,  B01J29/70 ,  B01J29/74 ,  B01J29/78 ,  C01B39/00 ,  C01B39/04 ,  C01B39/06 ,  C01B39/34 ,  C10G47/02 ,  C10G47/16 ,  C10G49/08 ,  B01J29/30

CPC classification number: B01J29/7423 ,  B01J29/7011 ,  B01J29/7823 ,  C10G47/16 ,  B01J2229/16 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42

Abstract: The invention concerns a new stabilized and dealuminated zeolite of OMEGA structure, characterized by:a total SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least 10,a sodium content lower than 0.5% by weight,a and c parameters of elementary mesh respectively lower than 1.814 nm and 0.759 nm,a nitrogen adsorption capacity at 77 K higher than about 5% by weight for a partial pressure P/P.sub.o of 0.19,a lattice of mesopores whose radii range preferably from 1.5 to 14 nm.This zeolite can be used in admixture with a convenient matrix in reactions of hydrocarbon conversion.

Abstract translation: 本发明涉及一种OMEGA结构的新的稳定和脱铝沸石，其特征在于：SiO 2 / Al 2 O 3的总摩尔比至少为10，钠含量低于0.5重量％，基本网格的a和c参数分别低于1.814nm 和0.759nm，对于分压P / Po为0.19，77K时的氮吸附容量高于约5重量％，半径范围优选为1.5至14nm的中孔的晶格。 该沸石可以与烃转化反应中的方便的基质混合使用。

公开(公告)号：US4738940A

公开(公告)日：1988-04-19

申请号：US39832

申请日：1987-04-16

Applicant: Pierre Dufresne ,  Christian Marcilly

Inventor： Pierre Dufresne ,  Christian Marcilly

IPC: C10G11/02 ,  B01J29/08 ,  B01J29/10 ,  C10G11/00 ,  C10G45/12 ,  C10G47/16

CPC classification number: B01J29/106 ,  C10G47/16

Abstract: The invention relates to a novel hydrocarbon hydroconversion catalyst. This catalyst is a mixture of a matrix and a zeolite, the zeolite having a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 comprised between about 8 and 70, a sodium content below 0.15% by weight, a parameter a of the elementary mesh comprised between 24.55.times.10.sup.-10 m and 24.24.times.10.sup.-10 m, a sodium ion take-up capacity C.sub.Na expressed in grams of sodium per 100 grams of the modified zeolite, higher than 0.85%, a specific surface higher than 400 m.sup.2.g.sup.-1, a water vapor adsorption capacity at 25.degree. C. (at a P/Po ratio equal to 0.10) higher than 6%, a pore distribution comprised between 1 to 20% of the pore volume, contained in pores of diameter situated between 20 and 80.times.10.sup.-10 m, the remainder of the volume being essentially contained in pores of diameter less than 20.times.10.sup.-10 m. The pore volume V (desorption isotherm of nitrogen) and the micropore distribution DV/dD are demonstrated particularly in FIG. 1.

Abstract translation: 本发明涉及新型烃加氢转化催化剂。 该催化剂是基质和沸石的混合物，沸石的SiO 2 / Al 2 O 3的摩尔比在约8至70之间，钠含量低于0.15重量％，基本网格的参数a在24.55×10 -10 m和24.24x10-10 m，钠离子吸收容量CNa以每克100g改性沸石表示的钠克数，高于0.85％，比表面积高于400 m2.g-1，水蒸气吸附 在25℃（P / Po比等于0.10）高于6％的容量，孔径分布为包含在20至80×10 -10 m之间的直径的孔中的孔体积的1至20％ 体积的其余部分基本上包含在直径小于20×10 -10 m的孔中。 孔体积V（氮的解吸等温线）和微孔分布DV / dD在图1中特别示出。 1。

公开(公告)号：US4645752A

公开(公告)日：1987-02-24

申请号：US748809

申请日：1985-06-25

Applicant: Pierre Dufresne ,  Christian Marcilly ,  Dinh Chan Trinh

Inventor： Pierre Dufresne ,  Christian Marcilly ,  Dinh Chan Trinh

IPC: C10G11/05 ,  B01J23/22 ,  B01J29/076 ,  B01J29/72 ,  B01J31/28 ,  C10G11/00 ,  C10G45/12 ,  C10G47/16 ,  C10G47/20 ,  B01J29/12 ,  B01J29/22

CPC classification number: B01J29/076 ,  C10G47/20

Abstract: The invention concerns a new catalyst containing (a) a zeolite carrier, (b) a metal from group VIII and (c) an additional metal selected from tin, germanium and lead, forming an alloy with the metal of group VIII, said additional metal being introduced as organic compound.The catalyst can be used, in particular, in hydrocarbon hydrocracking reactions.The figure of the accompanying drawing illustrates the conversion of n-heptane in the presence of a catalyst containing palladium and tin. Curve (A) illustrates this conversion at different temperatures, curves (B) and (C) giving the results after ageing of the catalyst.

Abstract translation: 本发明涉及一种新的催化剂，其包含（a）沸石载体，（b）来自VIII族的金属和（c）另一种选自锡，锗和铅的金属，与第VIII族金属形成合金，所述附加金属 作为有机化合物引入。 催化剂特别可用于烃类加氢裂化反应中。 附图示出了在含有钯和锡的催化剂存在下正庚烷的转化率。 曲线（A）示出了在不同温度下的转化，曲线（B）和（C）给出催化剂老化后的结果。

公开(公告)号：US08772191B2

公开(公告)日：2014-07-08

申请号：US13344887

申请日：2012-01-06

Applicant: Philippe Kerleau ,  Pierre Dufresne

Inventor： Philippe Kerleau ,  Pierre Dufresne

IPC: B01J38/48 ,  B01J38/56 ,  B01J38/04 ,  B01J38/44 ,  B01J38/12 ,  B01J38/02 ,  B01J38/10 ,  B01J38/68 ,  B01J29/90 ,  B01J23/96 ,  B01J23/75 ,  B01J23/882 ,  B01J23/883 ,  B01J23/90 ,  B01J23/94 ,  B01J38/00

CPC classification number: B01J23/75 ,  B01J21/04 ,  B01J23/882 ,  B01J23/883 ,  B01J23/90 ,  B01J23/92 ,  B01J23/94 ,  B01J23/96 ,  B01J29/064 ,  B01J29/90 ,  B01J35/1019 ,  B01J38/02 ,  B01J38/10 ,  B01J38/12 ,  B01J38/56 ,  B01J38/68 ,  B01J2038/005

Abstract: The invention provides a process for the off site regeneration of a solid catalyst, comprising two consecutive steps: a first step of washing the catalyst using one or more fluid(s) in the supercritical state, so as to extract from the catalyst at least a portion of the hydrocarbons present at the surface of the latter, followed by a second step of combustion of at least a portion of the coke present at the surface of the said catalyst by a heat treatment of the latter in the presence of oxygen and at a temperature ranging from 300° C. to 600° C.

Abstract translation: 本发明提供了一种用于固体催化剂的非现场再生的方法，包括两个连续步骤：第一步骤，使用超临界状态的一种或多种流体洗涤催化剂，以便从催化剂中提取至少一种 存在于后者的表面的部分烃，随后是通过在氧的存在下热处理在所述催化剂的表面处的至少一部分焦炭燃烧第二步骤 温度范围从300°C到600°C

公开(公告)号：US08307985B2

公开(公告)日：2012-11-13

申请号：US12146640

申请日：2008-06-26

Applicant: Pierre Dufresne ,  Maxime Meens ,  Mickaël Bremaud

Inventor： Pierre Dufresne ,  Maxime Meens ,  Mickaël Bremaud

IPC: B07C5/342

CPC classification number: B07C5/3427

Abstract: Process for separating at least one type of catalyst or adsorbent particles having similar colors characterized in that such particles undergo an oxidative heating treatment for generating particle of different colors, and then particles are separated using a color sorting process for separating at least one type of particles.

Abstract translation: 用于分离至少一种具有相似颜色的催化剂或吸附剂颗粒的方法，其特征在于，这种颗粒进行氧化加热处理以产生不同颜色的颗粒，然后使用颜色分选方法分离颗粒，以分离至少一种类型的颗粒 。

公开(公告)号：US07582587B2

公开(公告)日：2009-09-01

申请号：US10526499

申请日：2004-02-06

Applicant: Pierre Dufresne ,  Franck Labruyere

Inventor： Pierre Dufresne ,  Franck Labruyere

IPC: B01J20/34 ,  B01J38/30 ,  B01J38/22 ,  B01J27/02

CPC classification number: B01J37/20 ,  B01J23/883 ,  B01J23/888 ,  B01J33/00 ,  B01J37/06 ,  B01J37/14 ,  C10G49/02 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1051 ,  C10G2300/1059 ,  C10G2300/1074 ,  C10G2300/301 ,  C10G2300/705 ,  Y02P30/20

Abstract: The present invention concerns a process for ex situ oxidizing passivation of hydrocarbon hydroconversion catalysts, in particular for hydrotreatment in their sulphurized states, in which the sulphurized catalyst undergoes two treatments: contact with an oxidizing gas stream, and contact with an organic liquid (for example hydrocarbon) which partially fills its pores.

Abstract translation: 本发明涉及一种用于烃加氢转化催化剂的非原位氧化钝化的方法，特别是用于其硫化状态下的加氢处理，其中硫化催化剂经受两种处理：与氧化气流接触并与有机液接触（例如 烃），其部分地填充其孔。

公开(公告)号：US07501376B2

公开(公告)日：2009-03-10

申请号：US10529378

申请日：2003-09-25

Applicant: Pierre Dufresne ,  Franck Labruyere

Inventor： Pierre Dufresne ,  Franck Labruyere

IPC: B01J27/02 ,  B01J27/047 ,  B01J27/051 ,  B01J27/049 ,  B01J27/043 ,  B01J27/045

CPC classification number: B01J37/20 ,  B01J23/882 ,  B01J33/00 ,  B01J37/14 ,  C10G49/02 ,  C10G2300/705

Abstract: This invention relates to a process of ex-situ oxidizing passivation of catalysts for hydroconversion of hydrocarbons and especially of hydrotreating, in their sulfide state, process in which the sulfurized catalyst is brought into contact with an oxidizing gas flow that can be dry or wet, during heat treatment at more than 50° C. This invention, for passivation of sulfide phases, can be equally well implemented for a process that takes place in a fixed bed or a fluidized bed, for example a moving bed.

Abstract translation: 本发明涉及一种用于烃的加氢转化的催化剂的非原位氧化钝化方法，特别是在其硫化物状态下加氢处理，其中使硫化催化剂与可干燥或潮湿的氧化气流接触的方法， 在超过50℃的热处理期间。本发明用于钝化硫化物相，对于在固定床或流化床（例如移动床）中发生的方法同样可以很好地实施。

公开(公告)号：US20090000992A1

公开(公告)日：2009-01-01

申请号：US12146640

申请日：2008-06-26

Applicant: Pierre Dufresne ,  Maxime Meens ,  Mickael Bremaud

Inventor： Pierre Dufresne ,  Maxime Meens ,  Mickael Bremaud

IPC: B03B1/00

CPC classification number: B07C5/3427

Abstract: Process for separating at least one type of catalyst or adsorbent particles having similar colours characterized in that such particles undergo an oxidative heating treatment for generating particle of different colours, and then particles are separated using a colour sorting process for separating at least one type of particles.

Abstract translation: 用于分离至少一种具有相似颜色的催化剂或吸附剂颗粒的方法，其特征在于，这种颗粒进行氧化加热处理以产生不同颜色的颗粒，然后使用颜色分选方法分离颗粒，以分离至少一种类型的颗粒 。

公开(公告)号：US20080312076A1

公开(公告)日：2008-12-18

申请号：US12117805

申请日：2008-05-09

Applicant: Pierre DUFRESNE ,  Franck Labruyere ,  Maxime Meens ,  Loredana Romano

Inventor： Pierre DUFRESNE ,  Franck Labruyere ,  Maxime Meens ,  Loredana Romano

IPC: B01J27/051 ,  B01J27/02 ,  B01J27/043 ,  B05C3/00 ,  B01J20/00 ,  B01J27/047

CPC classification number: B01J8/16 ,  B01J8/1809 ,  B01J8/1818 ,  B01J8/1836 ,  B01J8/40 ,  B01J23/72 ,  B01J23/882 ,  B01J27/043 ,  B01J27/047 ,  B01J27/0515 ,  B01J37/20 ,  B01J2208/00017 ,  B01J2208/00061 ,  B01J2208/00212 ,  B01J2208/00371 ,  B01J2208/00407 ,  B01J2208/00415 ,  B01J2208/0053 ,  B01J2219/1944 ,  C10G45/04 ,  C10G2300/207 ,  Y10S502/514

Abstract: The invention relates to a process for incorporating sulfur in the porosity of the solid particles of a catalyst for the conversion of hydrocarbons or an adsorbent. This process is carried out off-site in the presence of hydrogen sulfide that is pure or diluted in hydrogen or nitrogen, a process in which said particles are made to rise or fall in a sulfur incorporation zone that comprises at least one vibratory helical coil that is essentially tubular in shape and that comprises at least two turns, whereby said particles are subjected to a temperature profile over the majority of their path in said coil and whereby said particles are brought into contact with at least one fluid on at least one portion of their path.

Abstract translation: 本发明涉及在用于转化烃或吸附剂的催化剂的固体颗粒的孔隙中掺入硫的方法。 这种方法是在氢气或氮气中纯化或稀释的硫化氢存在下进行的，所述硫化氢在硫掺入区中上升或下降，其中包含至少一个振动螺旋线圈， 基本上是管状的并且包括至少两匝，由此所述颗粒在所述线圈中的大部分路径上经受温度分布，并且由此使所述颗粒在至少一个部分上与至少一个流体接触 他们的路径