公开(公告)号：US5591406A

公开(公告)日：1997-01-07

申请号：US527434

申请日：1995-09-13

申请人： Kenji Hirai ,  Akira Aono ,  Shinya Tsuneda ,  Hirokazu Matsumoto ,  Yuji Yamashita ,  Hisayoshi Tanaka ,  Takanori Shiina ,  Haruko Kaburagi

发明人： Kenji Hirai ,  Akira Aono ,  Shinya Tsuneda ,  Hirokazu Matsumoto ,  Yuji Yamashita ,  Hisayoshi Tanaka ,  Takanori Shiina ,  Haruko Kaburagi

IPC分类号： G01N30/04 ,  G01N30/02 ,  G01N30/38 ,  G01N30/46 ,  G01N30/62 ,  G01N30/88 ,  G01N33/00 ,  G01N31/12 ,  G05D9/00

CPC分类号： G01N30/467 ,  G01N33/0031 ,  G01N2030/025 ,  G01N2030/626 ,  G01N2030/8804 ,  G01N2030/8886 ,  G01N30/38

摘要： An automatic exhaust gas analyzer for analyzing an exhaust gas of an internal combustion engine. The analyzer includes: a) plural analyzing units; b) two independent gas lines provided in each of the plural analyzing units; c) a gas-chromatographic column provided in each of the gas lines; d) a gas-chromatographic detector connected with the column in each of the gas lines; and e) a signal communication network interconnecting the gas-chromatographic detectors. Exhaust gas and the background gas are sampled at each stage of a predetermined run cycle, and are provided immediately to the two independent gas lines of the plurality of analyzing units respectively. Then the exhaust gas and background gas are analyzed in parallel in each of the plurality of analyzing units, which facilitates equalizing the measurement conditions of the two gases and the background correction of the measurement results of the exhaust gas can be made at high precision.

摘要翻译： 一种用于分析内燃机的废气的自动废气分析装置。 分析仪包括：a）多个分析单元; b）设置在多个分析单元中的每一个中的两个独立的气体管线; c）设置在每条气体管线中的气相色谱柱; d）气相色谱检测器，每个气体管线与色谱柱连接; 和e）互连气相色谱检测器的信号通信网络。 废气和背景气体在预定的运行循环的每个阶段被采样，并且立即分别提供给多个分析单元的两个独立气体管线。 然后在多个分析单元中的每个分析单元中并行分析废气和背景气体，这有助于均衡两种气体的测量条件，并且可以高精度地进行废气的测量结果的背景校正。

公开(公告)号：US5464811A

公开(公告)日：1995-11-07

申请号：US409453

申请日：1995-03-24

申请人： Kenji Hirai ,  Mitsuo Yamashita ,  Tomoko Tateno ,  Emiko Ejiri ,  Kikuko Harasawa ,  Yuichi Onji ,  Sadayuki Ugai ,  Shoin Nagato

发明人： Kenji Hirai ,  Mitsuo Yamashita ,  Tomoko Tateno ,  Emiko Ejiri ,  Kikuko Harasawa ,  Yuichi Onji ,  Sadayuki Ugai ,  Shoin Nagato

IPC分类号： A01N37/32 ,  A01N43/56 ,  C07C69/96 ,  C07C205/34 ,  C07C217/76 ,  C07C219/34 ,  C07C271/28 ,  C07D209/48 ,  C07D231/56

CPC分类号： C07D209/48 ,  A01N37/32 ,  A01N43/56 ,  C07C205/43 ,  C07C217/88 ,  C07C219/34 ,  C07C271/28 ,  C07C69/96 ,  C07D231/56 ,  C07C2101/08 ,  C07C2101/14

摘要： A benzene derivative substituted with a heterocyclic ring represented by the general formula: ##STR1## wherein R represents a cycloalkyl group having 3 to 8 carbon atoms, X represents a halogen atom, and Z represents ##STR2## in which said cycloalkyl group may be substituted with an alkyl group having 1 to 6 carbon atoms, a process for preparing the same, and a herbicidal agent comprising the above compound as an active ingredient are disclosed. The compound has an excellent effect in that the compound exhibits a markedly high herbicidal effect on weeds in the field and the paddy field at a low dose and yet exhibits markedly low noxious effects on main crops.

摘要翻译： 由以下通式表示的杂环取代的苯衍生物：其中R表示碳原子数为3〜8的环烷基，X表示卤素原子，Z表示可以被取代的环烷基的Z表示的化合物 具有1-6个碳原子的烷基，其制备方法和包含上述化合物作为活性成分的除草剂。 该化合物具有优异的效果，该化合物对田间杂草和低剂量的稻田显示出显着高的除草效果，对主要作物显示出显着低的有害作用。

公开(公告)号：US5424277A

公开(公告)日：1995-06-13

申请号：US855694

申请日：1992-05-06

申请人： Kenji Hirai ,  Mitsuo Yamashita ,  Tomoko Tateno ,  Emiko Ejiri ,  Kikuko Harasawa ,  Yuichi Onji ,  Sadayuki Ugai ,  Shoin Nagato

发明人： Kenji Hirai ,  Mitsuo Yamashita ,  Tomoko Tateno ,  Emiko Ejiri ,  Kikuko Harasawa ,  Yuichi Onji ,  Sadayuki Ugai ,  Shoin Nagato

IPC分类号： A01N37/32 ,  A01N43/56 ,  C07C69/96 ,  C07C205/34 ,  C07C217/76 ,  C07C219/34 ,  C07C271/28 ,  C07D209/48 ,  C07D231/56 ,  A01N43/38

CPC分类号： C07D209/48 ,  A01N37/32 ,  A01N43/56 ,  C07C205/43 ,  C07C217/88 ,  C07C219/34 ,  C07C271/28 ,  C07C69/96 ,  C07D231/56 ,  C07C2101/08 ,  C07C2101/14

摘要： A benzene derivative substituted with a heterocyclic ring represented by the general formula: ##STR1## wherein R represents a cycloalkyl group having 3 to 8 carbon atoms, X represents a halogen atom, and Z represents ##STR2## in which said cycloalkyl group may be substituted with an alkyl group having 1 to 6 carbon atoms, a process for preparing the same, and a herbicidal agent comprising the above compound as an active ingredient are disclosed. The compound has an excellent effect in that the compound exhibits a markedly high herbicidal effect on weeds in the field and the paddy field at a low dose and yet exhibits markedly low noxious effects on main crops.

摘要翻译： PCT No.PCT / JP91 / 00950 Sec。 371日期：1992年5月6日 102（e）日期1992年5月6日PCT提交1991年7月16日PCT公布。 出版物WO92 / 01671 日本1992年2月6日。一种由通式表示的杂环取代的苯衍生物：其中R表示碳原子数3〜8的环烷基，X表示卤素原子，Z表示“ 其中所述环烷基可以被碳原子数1〜6的烷基取代，其制备方法以及含有上述化合物作为有效成分的除草剂。 该化合物具有优异的效果，该化合物对田间杂草和低剂量的稻田显示出显着高的除草效果，对主要作物显示出显着低的有害作用。

公开(公告)号：US5024692A

公开(公告)日：1991-06-18

申请号：US376570

申请日：1989-07-07

申请人： Shoin Nagato ,  Ryusuke Taguchi ,  Kenji Hirai ,  Hiroaki Hirose ,  Masahiro Yokota

发明人： Shoin Nagato ,  Ryusuke Taguchi ,  Kenji Hirai ,  Hiroaki Hirose ,  Masahiro Yokota

IPC分类号： A01N43/76 ,  A01N57/20

CPC分类号： A01N43/76

摘要： A herbicidal composition comprising at least one oxazolidinedione derivative expressed by the following formula: ##STR1## (wherein R.sup.1, R.sup.2 and R.sup.3 independently denote hydrogen atoms, halogen atoms, nitro groups, alkyl groups, alkoxy groups, alkenyloxy groups, alkynyloxy groups or cycloalkyloxy groups; R.sup.4 and R.sup.5 independently denote hydrogen atoms, alkyl groups or aryl groups or may be combined with each other to form a polymethylene chain; and said alkyl groups, alkoxy groups, alkenyloxy groups, alkynyloxy groups, cycloalkyloxy groups and aryl groups may be substituted); and at least one organic phosphorus herbicide, as active ingredients.

公开(公告)号：US4621150A

公开(公告)日：1986-11-04

申请号：US703617

申请日：1985-02-21

申请人： Kenji Hirai ,  Takamasa Fuchikami ,  Hiroaki Hirose ,  Iwao Ojima

发明人： Kenji Hirai ,  Takamasa Fuchikami ,  Hiroaki Hirose ,  Iwao Ojima

IPC分类号： B01J31/16 ,  B01J31/22 ,  C07C67/30 ,  C07C69/732 ,  C07C69/738 ,  C07C69/76

CPC分类号： B01J31/2291 ,  B01J31/16 ,  B01J31/2295 ,  C07C41/56 ,  C07C45/58 ,  C07C67/333 ,  B01J2231/52 ,  B01J2531/822 ,  B01J2531/824 ,  C07C2101/10 ,  C07C2101/14 ,  C07C2101/16

摘要： A catalyst for isomerization consisting essentially of a salt or complex salt represented by the formula:[ML.sub.m ].sup.n+ [Y].sub.n.sup.- (I)where M is a metal of Group IB, IIA, IIB or VIII of the periodic table, L is a ligand, Y is a conjugated base of a Bronsted acid, m is 0, 1, 2, 3 or 4 and n is 1, 2 or 3.

摘要翻译： 用于异构化的催化剂基本上由下式表示的盐或络合盐：[MLm] n + [Y] n-（I）其中M是元素周期表中IB，IIA，IIB或VIII族的金属，L是 配体Y是布朗斯台德酸的共轭碱，m是0,1,2,3或4，n是1,2或3。

公开(公告)号：US20110105319A1

公开(公告)日：2011-05-05

申请号：US12599617

申请日：2008-05-01

申请人： Kenji Hirai ,  Akihito Ogino

发明人： Kenji Hirai ,  Akihito Ogino

IPC分类号： B41M5/323 ,  B41M5/337

CPC分类号： B41M5/3372 ,  B41M5/327 ,  B41M5/3275 ,  B41M5/3335 ,  B41M5/3336 ,  B41M5/3375

摘要： The present invention presents a thermosensitive recording medium having an excellent color developing property, water resistance and preservation properties (such as anti-self-color-development) and is harmless to the environment.The present invention is a thermosensitive recording medium having a thermosensitive recording layer comprising a colorless or pale colored basic leuco dye and an electron accepting developing agent on a substrate, wherein the thermosensitive recording layer further comprises a resin containing a carboxyl group, an epichlorohydrin resin and a modified polyamine/amide resin. This thermosensitive recording medium is suitable for recording with a low applied energy.

摘要翻译： 本发明提供了具有优异的显色性，耐水性和保存性（例如抗自色显影）并且对环境无害的热敏记录介质。 本发明是一种热敏记录介质，其具有包含无色或浅色的碱性无色染料和在基底上的电子接受显影剂的热敏记录层，其中热敏记录层还包含含有羧基的树脂，表氯醇树脂和 改性聚胺/酰胺树脂。 该热敏记录介质适用于以低施加能量进行记录。

公开(公告)号：US20100152443A1

公开(公告)日：2010-06-17

申请号：US12713421

申请日：2010-02-26

申请人： Kenji Hirai ,  Atsushi Uchida ,  Atsuko Watanabe ,  Taeko Abe ,  Takuya Ueda ,  Hiroshi Sakurai

发明人： Kenji Hirai ,  Atsushi Uchida ,  Atsuko Watanabe ,  Taeko Abe ,  Takuya Ueda ,  Hiroshi Sakurai

IPC分类号： C07D413/12 ,  C07D231/18 ,  C07D401/12 ,  C07D405/12

CPC分类号： A01N47/38 ,  C07D231/20

摘要： The present invention provides a pyrazole derivative of the general formula (1), which has an excellent efficacy as an active component for a herbicide, an intermediate for the production thereof, processes for the production thereof, and a herbicide containing the derivative as an active ingredient.

摘要翻译： 本发明提供通式（1）的吡唑衍生物，其作为除草剂的活性成分，其制备中间体，其制备方法和含有该衍生物作为活性成分的除草剂具有优异的功效 成分。

公开(公告)号：US20090018345A1

公开(公告)日：2009-01-15

申请号：US11915016

申请日：2006-05-22

申请人： Atsushi Uchida ,  Wakako Yokota ,  Kenji Hirai ,  Tomoyuki Yano

发明人： Atsushi Uchida ,  Wakako Yokota ,  Kenji Hirai ,  Tomoyuki Yano

IPC分类号： C07D231/20

CPC分类号： C07D231/20

摘要： Disclosed are pyrazole-1-carboxylate derivatives of the general formula (1), (wherein symbols are as defined in the specification), a process for the production thereof and processes for producing herbicidally active 3-aryloxypyrazole-1-carboxamide derivatives from the above compound and an intermediate therefor. According to this invention, there can be industrially advantageously produced 3-aryloxypyrazole-1-carboxamide derivatives that does not cause chemical damage on crops but exhibits excellent herbicidal activity against weeds that impair the growth of such crops.

摘要翻译： 公开了通式（1）的吡唑-1-羧酸酯衍生物（其中符号如说明书中所定义），其制备方法和从上述产生除草活性3-芳氧基吡唑-1-甲酰胺衍生物的方法 化合物及其中间体。 根据本发明，可以在工业上有利地生产不对作物造成化学损害的3-芳氧基吡唑-1-甲酰胺衍生物，但是对于损害这些作物生长的杂草显示出优异的除草活性。

公开(公告)号：US07465694B2

公开(公告)日：2008-12-16

申请号：US11663229

申请日：2005-09-30

申请人： Takashi Date ,  Mizuho Shimoyama ,  Koichi Yanai ,  Kenji Hirai

发明人： Takashi Date ,  Mizuho Shimoyama ,  Koichi Yanai ,  Kenji Hirai

IPC分类号： B41M5/41

CPC分类号： B41M5/3377 ,  B41M5/426 ,  B41M2205/04 ,  B41M2205/12 ,  B41M2205/38 ,  B41M2205/40

摘要： A thermally sensitive recording medium has at least one layer on a substrate which is a thermally sensitive recording layer that contains a colorless or pale colored electron-donating leuco dye and an electron-accepting color-developing agent. At least one layer on the substrate contains a hydrated silicic acid compound which is treated by wet grinding treatment in a deposition process of the hydrated silicic acid compound. A thermally sensitive recording medium of high brightness, which is superior in color-developing sensitivity and coating layer strength and, further, has excellent head abrasion resistance, less debris adhering and sticking resistance is obtained.

摘要翻译： 热敏记录介质在衬底上具有至少一层，该层是含有无色或浅色电子给予的无色染料和受电子显色剂的热敏记录层。 底物上至少有一层含有水合硅酸化合物，其在水合硅酸化合物的沉积过程中通过湿法研磨处理。 高亮度的热敏记录介质，其显色灵敏度和涂层强度都优异，并且还具有优异的头部耐磨性，较少的碎片附着力和耐粘附性。

公开(公告)号：US20080154045A1

公开(公告)日：2008-06-26

申请号：US11884665

申请日：2006-02-23

申请人： Hidenori Aihara ,  Wakako Yokota ,  Tetsu Yamakawa ,  Kenji Hirai

发明人： Hidenori Aihara ,  Wakako Yokota ,  Tetsu Yamakawa ,  Kenji Hirai

IPC分类号： C07D231/14

CPC分类号： C07D231/14

摘要： In a process for producing 1-substituted-3-fluoroalkyl-pyrazole-4-carboxylate (3) by a reaction of 2-alkoxymethylenefluoroacylacetate (1) and hydrazine (2), the reaction is conducted in the presence of a base and water, to produce 1-substituted-3-fluoroalkylpyrazole-4-carboxylate (3) with high selectivity and yield. This novel process enables to produce 1-substituted-3-fluoroalkylpyrazole-4-carboxylate (3), which is useful as an intermediate for pharmaceuticals and agrochemicals, with high selectivity and yield by simple and safe operations.

摘要翻译： 在通过2-烷氧基甲基三氟酰基乙酸酯（1）和肼（2）的反应制备1-取代-3-氟烷基 - 吡唑-4-羧酸酯（3）的方法中，反应在碱和水的存在下进行， 以高选择性和产率制备1-取代-3-氟烷基吡唑-4-羧酸酯（3）。 该新方法能够通过简单和安全的操作产生具有高选择性和产率的1-取代-3-氟烷基吡唑-4-羧酸酯（3），其可用作药物和农用化学品的中间体。