公开(公告)号：US5264203A

公开(公告)日：1993-11-23

申请号：US735224

申请日：1991-07-24

Applicant: Jeffrey S. Beck ,  Charles T. Kresge ,  Michael E. Leonowicz ,  Wieslaw J. Roth ,  James C. Vartuli

Inventor： Jeffrey S. Beck ,  Charles T. Kresge ,  Michael E. Leonowicz ,  Wieslaw J. Roth ,  James C. Vartuli

IPC: B01D53/86 ,  B01J20/02 ,  B01J29/03 ,  B01J29/04 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/05 ,  C10G47/16 ,  C01B33/34

CPC classification number: B01J29/04 ,  B01D53/8628 ,  B01J20/041 ,  B01J20/06 ,  B01J20/08 ,  B01J20/103 ,  B01J20/12 ,  B01J20/18 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/05 ,  C10G47/16 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42

Abstract: This invention relates to a new synthetic composition of ultra-large pore crystalline material, e.g., [metallo]silicoaluminophosphate, having a composition, expressed on an anhydrous basis as follows:M.sub.n/q (W.sub.a X.sub.b Y.sub.c Z.sub.d O.sub.h)wherein M is one or more ions; n is the charge of the composition excluding M expressed as oxides; q is the weighted molar average valence of M; n/q is the number of moles or mole fraction of M; W is one or more divalent elements; X is one or more trivalent elements; Y is one or more tetravalent elements; Z is one or more pentavalent elements; a, b, c, and d are mole fractions of W, X, Y, and Z, respectively; (a+b+c+d)=1; a .gtoreq. 0; b, c, and d are each>0; and h is a number of from 1 to 2.5. The crystalline material is prepared by i) crystallizing a reaction mixture comprising sources of W, X, Z and an organic directing agent; ii) contacting the product of i) with a reaction mixture comprising sources of Y and organic directing agent; and iii) maintaining the mixture of ii) under conditions sufficient to form said composition of matter. The composition is suited to use for catalytic conversion of organic compounds.

Abstract translation: 本发明涉及具有如下无水基础的组成的[金属]硅铝磷酸盐的超大孔结晶材料的新合成组合物：Mn / q（WaXbYcZdOh）其中M是一个或多个离子; n是不含M表示为氧化物的组成的电荷; q是M的加权摩尔平均化合价; n / q是M的摩尔数或摩尔分数; W是一个或多个二价元素; X是一个或多个三价元素; Y是一种或多种四价元素; Z是一种或多种五价元素; a，b，c和d分别为W，X，Y和Z的摩尔分数; （a + b + c + d）= 1; a> / = 0; b，c和d各自> 0; h为1〜2.5的数。 晶体材料通过i）使含有W，X，Z和有机导向剂的反应混合物结晶来制备; ii）使i）的产物与包含Y和有机导向剂的反应混合物接触; 和iii）保持ii）的混合物在足以形成所述组合物的条件下。 该组合物适用于有机化合物的催化转化。

公开(公告)号：US5246689A

公开(公告)日：1993-09-21

申请号：US735240

申请日：1991-07-24

Applicant: Jeffrey S. Beck ,  William S. Borghard ,  Charles T. Kresge ,  Michael E. Leonowicz ,  Wieslaw J. Roth ,  James C. Vartuli

Inventor： Jeffrey S. Beck ,  William S. Borghard ,  Charles T. Kresge ,  Michael E. Leonowicz ,  Wieslaw J. Roth ,  James C. Vartuli

IPC: B01D53/86 ,  B01J20/02 ,  B01J29/03 ,  B01J29/04 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/05 ,  C10G47/16

CPC classification number: C10G11/05 ,  B01D53/8628 ,  B01J20/041 ,  B01J20/06 ,  B01J20/08 ,  B01J20/103 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G47/16 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42

Abstract: This invention relates to a composition of matter, e.g., silicoaluminate or metalloaluminosilicate, comprising an inorganic, porous crystalline phase material exhibiting, after calcination, an X-ray diffraction pattern with at least one peak at a d-spacing greater than 1.8 nm and having a benzene adsorption capacity of greater than 15 grams benzene per 100 grams of said material at 6.7 kPa (50 torr) and 25.degree. C. wherein said crystalline phase has a composition expressed as follows:M.sub.n/q (W.sub.a X.sub.b Y.sub.c O.sub.h)wherein M is one or more ions; n is the charge of the composition excluding M expressed as oxides; q is the weighted molar average valence of M; n/q is the number of moles or mole fraction of M; W is one or more divalent elements; X is one or more trivalent elements; Y is one or more tetravalent elements; a, b, and c are mole fractions of W, X, and Y, respectively; h is a number of from 1 to 2.5; (a+b+c)=1; and a, b, and c, are each >0.

Abstract translation: 本发明涉及一种物质的组合物，例如硅铝酸盐或金属铝硅酸盐，其包含无机多孔结晶相材料，其在煅烧后表现出具有至少一个d值大于1.8nm的峰的X射线衍射图，并且具有 在6.7kPa（50托）和25℃下每100克所述材料苯吸附量大于15克苯。其中所述结晶相的组成如下表示：Mn / q（WaXbYcOh）其中M是一个或 更多离子 n是不含M表示为氧化物的组成的电荷; q是M的加权摩尔平均化合价; n / q是M的摩尔数或摩尔分数; W是一个或多个二价元素; X是一个或多个三价元素; Y是一种或多种四价元素; a，b和c分别是W，X和Y的摩尔分数; h是从1到2.5的数字; （a + b + c）= 1; 和a，b和c分别为> 0。

公开(公告)号：US5198203A

公开(公告)日：1993-03-30

申请号：US734825

申请日：1991-07-24

Applicant: Charles T. Kresge ,  Michael E. Leonowicz ,  Wieslaw J. Roth ,  Kirk D. Schmitt ,  James C. Vartuli

Inventor： Charles T. Kresge ,  Michael E. Leonowicz ,  Wieslaw J. Roth ,  Kirk D. Schmitt ,  James C. Vartuli

IPC: C01B39/04 ,  B01D53/86 ,  B01J20/02 ,  B01J20/06 ,  B01J29/03 ,  B01J29/035 ,  B01J29/04 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/02 ,  C10G11/05 ,  C10G11/06 ,  C10G47/16

CPC classification number: B01D53/8628 ,  B01J20/06 ,  B01J29/0308 ,  B01J29/035 ,  B01J29/04 ,  B01J29/041 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/05 ,  C10G47/16 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42 ,  Y10S423/30

Abstract: This invention relates to a new synthetic composition of porous crystalline material and use thereof as sorbent and in catalytic conversion of organic and inorganic compounds. The new crystalline material exhibits a large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 10 grams benzene/100 grams at 50 torr and 25.degree. C. and a particular, unique X-ray diffraction pattern.

Abstract translation: 本发明涉及多孔结晶材料的新型合成组合物及其作为吸附剂的用途以及有机和无机化合物的催化转化。 新的结晶材料表现出很大的吸附能力，其吸附能力在50托和25℃下大于约10克苯/ 100克，具有独特的X射线衍射图。

公开(公告)号：US5196633A

公开(公告)日：1993-03-23

申请号：US853458

申请日：1992-03-18

Applicant: Charles T. Kresge ,  Michael E. Leonowicz ,  Wieslaw J. Roth ,  James C. Vartuli

Inventor： Charles T. Kresge ,  Michael E. Leonowicz ,  Wieslaw J. Roth ,  James C. Vartuli

IPC: B01D53/86 ,  B01J20/02 ,  B01J29/03 ,  B01J29/04 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/05 ,  C10G47/16

CPC classification number: B01J29/045 ,  B01D53/8628 ,  B01J20/041 ,  B01J20/06 ,  B01J20/08 ,  B01J20/103 ,  B01J20/12 ,  B01J20/3078 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/05 ,  C10G47/16 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42

Abstract: A process is provided for effecting catalytic conversion of an organic compound-containing feedstock to conversion product which comprises contacting said feedstock under catalytic conversion conditions with a catalyst comprising an active form of an inorganic, porous crystalline phase exhibiting, after calcination, a hexagonal arrangement of uniformly-sized pores having diameters of at least about 13, e.g., at least about 15, Angstrom Units and exhibiting a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units.

Abstract translation: 提供了一种用于将含有机化合物的原料催化转化成转化产物的方法，其包括在催化转化条件下使所述原料与包含活性形式的无机多孔结晶相的催化剂接触，所述催化剂在煅烧后显示六边形排列 具有至少约13个（例如至少约15）埃单位的直径的均匀尺寸的孔，并且显示出可以用大于约18埃单位的d100值进行索引的六方电子衍射图。

公开(公告)号：US5145816A

公开(公告)日：1992-09-08

申请号：US718056

申请日：1991-06-20

Applicant: Jeffrey S. Beck ,  David C. Calabro ,  Sharon B. McCullen ,  Bruce P. Pelrine ,  Kirk D. Schmitt ,  James C. Vartuli

Inventor： Jeffrey S. Beck ,  David C. Calabro ,  Sharon B. McCullen ,  Bruce P. Pelrine ,  Kirk D. Schmitt ,  James C. Vartuli

IPC: B01J20/10 ,  B01D53/86 ,  B01J20/02 ,  B01J29/03 ,  B01J29/04 ,  B01J29/06 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C01B39/04 ,  C01B39/06 ,  C01B39/48 ,  C10G11/05 ,  C10G47/16

CPC classification number: B01D53/8628 ,  B01J20/041 ,  B01J20/06 ,  B01J20/08 ,  B01J20/103 ,  B01J20/12 ,  B01J20/18 ,  B01J20/3078 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/045 ,  B01J29/40 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/05 ,  C10G47/16 ,  B01J2229/12 ,  B01J2229/14 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/40 ,  B01J2229/42

Abstract: A method is described for modifying an ultra-large pore crystalline material by contacting with a treatment composition M'X'Y'.sub.n wherein M' is an element of Groups IIA, IVA, VA, VIA, VIIA, IB, IIB, IVB, VB or VIB; X' is halide, hydride, alkoxide of C.sub.1-6', or acetate; Y' is X or phosphine, sulfide, carbonyl or cyano; and N=1-5. The contacted crystalline material becomes functionalized. The functionalized material is also described and can be used as a sorbent or catalyst component.

Abstract translation: 描述了通过与处理组合物M'X'Y'n接触来改性超大孔结晶材料的方法，其中M'是IIA，IVA，VA，VIA，VIIA，IB，IIB，IVB，IVB族的元素， VB或VIB; X'是卤化物，氢化物，C1-6'的醇盐或乙酸盐; Y'是X或膦，硫化物，羰基或氰基; N = 1-5。 接触的结晶材料变得官能化。 还描述了官能化材料并且可以用作吸附剂或催化剂组分。

公开(公告)号：US5126298A

公开(公告)日：1992-06-30

申请号：US667856

申请日：1991-03-12

Applicant: Robert P. L. Absil ,  Jocelyn A. Kowalski

Inventor： Robert P. L. Absil ,  Jocelyn A. Kowalski

IPC: B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J37/00 ,  C10G11/05

CPC classification number: C10G11/05 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J37/0045 ,  B01J2229/26 ,  B01J2229/42

Abstract: The present invention is directed to a novel catalyst useful in the cracking of hydrocarbons. The catalyst of the present invention is formed with at least one zeolite, a first clay having a first average particle size and a second clay having a smaller average particle size than the first clay, wherein at least one of the clays or the zeolite is first treated with a source of phosphorus, such as phosphoric acid. These components are mixed in a slurry and spray dried at a low pH. Thus the present invention is also directed to a process for preparing a zeolite catalyst. The catalysts of the present invention advantageously do not require calcination in order to obtain low attritability.

Abstract translation: 本发明涉及一种可用于烃裂解的新型催化剂。 本发明的催化剂由至少一种沸石，具有第一平均粒度的第一粘土和平均粒径小于第一粘土的第二粘土形成，其中至少一种粘土或沸石是第一 用磷源如磷酸处理。 将这些组分在浆料中混合并在低pH下喷雾干燥。 因此，本发明还涉及一种制备沸石催化剂的方法。 本发明的催化剂有利地不需要煅烧以获得低的可磨性。

公开(公告)号：US5069794A

公开(公告)日：1991-12-03

申请号：US674635

申请日：1991-03-25

Applicant: Werner O. Haag ,  John G. Tsikoyiannis

Inventor： Werner O. Haag ,  John G. Tsikoyiannis

IPC: B01D71/02 ,  B01J19/18 ,  B01J29/40 ,  B01J29/82 ,  B01J29/84 ,  B01J29/85 ,  B01J35/06 ,  C01B3/50 ,  C01B13/02

CPC classification number: B01D67/0083 ,  B01D69/141 ,  B01D71/028 ,  B01J19/1893 ,  B01J29/40 ,  B01J29/82 ,  B01J29/84 ,  B01J29/85 ,  B01J35/065 ,  C01B13/0255 ,  C01B3/503 ,  B01D2323/08 ,  B01D2323/12 ,  B01J2219/00159 ,  B01J2229/60 ,  B01J2229/64 ,  B01J2229/66 ,  C01B2203/041 ,  C01B2203/047 ,  C01B2203/048 ,  C01B2210/0046

Abstract: A process is provided for separation of components of a gaseous or liquid mixture which comprises contacting the mixture with a synthetic, non-composited microporous membrane comprising a continuous array of crystalline molecular sieve material.

Abstract translation: 提供了用于分离气体或液体混合物的组分的方法，其包括使混合物与包含连续阵列的结晶分子筛材料的合成的非复合微孔膜接触。

公开(公告)号：US4975180A

公开(公告)日：1990-12-04

申请号：US361617

申请日：1989-06-05

Applicant: Paul E. Eberly

Inventor： Paul E. Eberly

IPC: B01J27/14 ,  B01J29/04 ,  B01J29/06 ,  B01J29/08 ,  B01J29/82 ,  B01J37/04 ,  C10G11/05 ,  C10G47/04 ,  C10G47/16

CPC classification number: B01J37/04 ,  B01J29/04 ,  B01J29/06 ,  B01J29/084 ,  C10G11/05 ,  B01J29/82

Abstract: A catalytic cracking process is provided wherein a phosphorous containing alumina or an alkaline earth phosphorous containing alumina is added to a catalytic cracking zone for admixture with a zeolite containing cracking catalyst.

公开(公告)号：USRE33009E

公开(公告)日：1989-08-01

申请号：US215469

申请日：1988-07-05

Applicant: E. G. Derouane ,  R. M. Dessau ,  I. J. Heilweil ,  G. T. Kerr

Inventor： E. G. Derouane ,  R. M. Dessau ,  I. J. Heilweil ,  G. T. Kerr

IPC: B01J29/82 ,  C01B25/45 ,  C07F9/09 ,  C07F9/6506

CPC classification number: C07F9/65061 ,  B01J29/82 ,  C01B25/45 ,  C07F9/091 ,  B01J2229/40

Abstract: A new crystalline zirconium phosphate composition and method for its synthesis are provided. The composition has ion exchange properties and is readily convertible to catalytically active material by thermal treatment.

公开(公告)号：US4695642A

公开(公告)日：1987-09-22

申请号：US902121

申请日：1986-09-02

Applicant: E. G. Derouane ,  R. M. Dessau ,  I. J. Heilweil ,  G. T. Kerr

Inventor： E. G. Derouane ,  R. M. Dessau ,  I. J. Heilweil ,  G. T. Kerr

IPC: B01J29/82 ,  B01J39/12 ,  C01B25/45 ,  C07F9/09 ,  C07F9/6506 ,  C07F7/00

CPC classification number: C07F9/65061 ,  B01J29/82 ,  B01J39/12 ,  C01B25/45 ,  C07F9/091 ,  B01J2229/40

Abstract: A new crystalline zirconium phosphate composition and method for its synthesis are provided. The composition has ion exchange properties and is readily convertible to catalytically active material by thermal treatment.

Abstract translation: 提供了一种新的结晶磷酸锆组合物及其合成方法。 该组合物具有离子交换性能，并且通过热处理容易地转化为催化活性材料。