Process for the preparation of isobutylene/beta-pinene copolymers
    20.
    发明授权
    Process for the preparation of isobutylene/beta-pinene copolymers 失效
    制备异丁烯/β-蒎烯共聚物的方法

    公开(公告)号:US3923759A

    公开(公告)日:1975-12-02

    申请号:US41433773

    申请日:1973-11-09

    申请人: UNIV AKRON

    IPC分类号: C08F210/10 C08F210/00

    摘要: Disclosed is a process for the azeotropic copolymerization of isobutylene and beta-pinene including the steps of charging a reaction vessel, substantially free from moisture, with an X mole percent amount of isobutylene and a Y mole percent of beta-pinene with a suitable solvent. The numerical values of X and Y may be any number from about 0.5 to about 99.5 and the sum of X and Y will equal 100 percent. The contents of the reaction vessel are then cooled to about -130*C. and a catalytic amount of precooled catalyst is added thereto. The temperature within the reaction vessel is maintained within a range from about 0.1 hours to about 5 hours so as to form a random copolymer consisting essentially of X mole percent of isobutylene and Y mole percent of betapinene. Homopolymers of beta-pinene can also be prepared, in the absence of a catalyst, by heating the monomer in a reaction vessel at a temperature of about 180*C. for a period of time ranging from about 160 hours to about 240 hours. Both processes may be conducted in a continuous manner.

    摘要翻译: 公开了一种用于异丁烯和β-蒎烯的共沸共聚的方法,包括以合适的溶剂将基本不含水分的反应容器与X摩尔百分数的异丁烯和Y摩尔%的β-蒎烯一起加入的步骤。 X和Y的数值可以是约0.5至约99.5的任何数,X和Y的总和将等于100%。 然后将反应容器的内容物冷却至约-130℃,并向其中加入催化量的预冷催化剂。 反应容器内的温度保持在约0.1小时至约5小时的范围内,以形成基本上由X摩尔%的异丁烯和Y摩尔%的β-蒎烯组成的无规共聚物。 在不存在催化剂的情况下,也可以通过在约180℃的温度下将反应容器中的单体加热约160小时至约240小时的时间段来制备β-蒎烯的均聚物。 两种方法可以以连续的方式进行。