摘要:
The present invention is directed at a bulkpolymerisation process for the preparation of a polymer (P) comprising the steps of: (i) providing at least one diene monomer (DM) and optionally at least one comonomer (COM); (ii) contacting the at least one diene monomer (DM) and optionally the at least one comonomer (COM) with a catalyst system (CS) forming a reaction mixture (RM); (iii) polymerizing the reaction mixture (RM) comprising the at least one diene monomer (DM) and optionally the at least one comonomer (COM) in at least one reactor vessel (RV); (iv) isolating the polymer (P) obtained from the at least one reactor vessel (RV); wherein the reaction mixture (RM) comprises solvent, diluent and/or dispersant in an amount of ≤10 wt.-%, based on the weight of the reaction mixture (RM); and wherein the conversion rate of the diene monomer (DM) and optionally the comonomer (COM) is ≥80%.
摘要:
The present invention provides a cationically curable resin composition for assembling hard disk devices which comprises a resin having a cationically polymerizable functional group (a component A) and a cationic polymerization initiator (a component B), the component B being at least one selected from the group consisting of X+(SbF6)−(B1), X+(B(C6F5)4)−(B2) and X+((Rf)nPF6-n)−(B3) (in the formulae, X+ is iodonium or sulfonium, Rf is a fluorinated alkyl having 1 to 6 carbon atoms, and n is an integer of 1 to 6). The invention also provides a hard disk device manufacturing method using the composition, and a hard disk device assembled with the composition.
摘要:
The present invention relates to halogenated, low-gel, high molecular weight isoolefin multiolefin copolymers, in particular to halogenated, low-gel, high molecular weight butyl rubbers, and halogenated, low-gel, high molecular weight isoolefin multiolefin copolymers synthesized from isobutene, isoprene and optionally further monomers, with a multiolefin content of greater than 2.5 mol %, a molecular weight Mw of greater than 240 kg/mol and a gel content of less than 1.2 wt. % and a process for their preparation.
摘要:
Disclosed is a process for the azeotropic copolymerization of isobutylene and beta-pinene including the steps of charging a reaction vessel, substantially free from moisture, with an X mole percent amount of isobutylene and a Y mole percent of beta-pinene with a suitable solvent. The numerical values of X and Y may be any number from about 0.5 to about 99.5 and the sum of X and Y will equal 100 percent. The contents of the reaction vessel are then cooled to about -130*C. and a catalytic amount of precooled catalyst is added thereto. The temperature within the reaction vessel is maintained within a range from about 0.1 hours to about 5 hours so as to form a random copolymer consisting essentially of X mole percent of isobutylene and Y mole percent of betapinene. Homopolymers of beta-pinene can also be prepared, in the absence of a catalyst, by heating the monomer in a reaction vessel at a temperature of about 180*C. for a period of time ranging from about 160 hours to about 240 hours. Both processes may be conducted in a continuous manner.