公开(公告)号：US09688782B2

公开(公告)日：2017-06-27

申请号：US14781973

申请日：2014-03-24

申请人： Fraunhofer-Gesellschaft Zur Förderung Der Angewandten Forschung E.V.

发明人： Ulrich Wendler ,  Marcus Vater ,  Carsten Gehrhardt ,  Frank Herzig

IPC分类号： C08F120/18 ,  C08F36/00 ,  C08F236/00 ,  B01D24/00 ,  C08F6/12 ,  C08C2/06 ,  C08F6/00 ,  C08F6/10 ,  C08F6/14 ,  B01D1/20 ,  B01D19/00 ,  B01D45/14

CPC分类号： C08F6/12 ,  B01D1/20 ,  B01D19/0042 ,  B01D45/14 ,  C08C2/06 ,  C08F6/003 ,  C08F6/10 ,  C08F6/14

摘要： The present invention relates to a method for separation of a polymer from a polymer solution or dispersion, wherein (i) a solution or dispersion of a polymer in an organic solvent is atomized by being brought into contact with water vapor in an atomizer container; (ii) the mixture obtained in the atomizer container is routed into a polymer degasification container and flows through same, wherein the organic solvent present in the polymer particles is driven at least partially out of the polymer particles due to the thermal contact between the polymer particles and the water vapor and transitions into the gas phase (iii) the mixture exiting from the polymer degasification container is routed into a phase separator (1) and the organic solvent present in the gas phase is separated from the polymer particles and the condensed water vapor; and (iv) the polymer particles and the condensed water vapor are routed into a phase separator (2) in order to separate the polymer particles from the condensed water vapor.

公开(公告)号：US20190202944A1

公开(公告)日：2019-07-04

申请号：US16311812

申请日：2017-06-29

申请人： FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V.

发明人： Marcus Vater ,  Ulrich Wendler ,  Michael Bartke

IPC分类号： C08F2/02 ,  C08F236/06 ,  C08F236/04 ,  C08F236/10 ,  C08F220/18 ,  C08F2/01 ,  C08F236/12 ,  C08K5/56 ,  C08F4/16 ,  C08F4/20 ,  C08F2/38

CPC分类号： C08F2/02 ,  C08F2/01 ,  C08F2/38 ,  C08F4/16 ,  C08F4/20 ,  C08F36/04 ,  C08F36/06 ,  C08F220/18 ,  C08F236/045 ,  C08F236/06 ,  C08F236/10 ,  C08F236/12 ,  C08F2220/1808 ,  C08F2400/02 ,  C08K5/56 ,  C08L9/00

摘要： The present invention is directed at a bulkpolymerisation process for the preparation of a polymer (P) comprising the steps of: (i) providing at least one diene monomer (DM) and optionally at least one comonomer (COM); (ii) contacting the at least one diene monomer (DM) and optionally the at least one comonomer (COM) with a catalyst system (CS) forming a reaction mixture (RM); (iii) polymerizing the reaction mixture (RM) comprising the at least one diene monomer (DM) and optionally the at least one comonomer (COM) in at least one reactor vessel (RV); (iv) isolating the polymer (P) obtained from the at least one reactor vessel (RV); wherein the reaction mixture (RM) comprises solvent, diluent and/or dispersant in an amount of ≤10 wt.-%, based on the weight of the reaction mixture (RM); and wherein the conversion rate of the diene monomer (DM) and optionally the comonomer (COM) is ≥80%.

公开(公告)号：US20160137757A1

公开(公告)日：2016-05-19

申请号：US14781973

申请日：2014-03-24

申请人： FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V.

发明人： Ulrich Wendler ,  Marcus Vater ,  Carsten Gehrhardt ,  Frank Herzig

IPC分类号： C08F6/12 ,  B01D19/00 ,  B01D45/14 ,  B01D1/20

CPC分类号： C08F6/12 ,  B01D1/20 ,  B01D19/0042 ,  B01D45/14 ,  C08C2/06 ,  C08F6/003 ,  C08F6/10 ,  C08F6/14

摘要： The present invention relates to a method for separation of a polymer from a polymer solution or dispersion, wherein (i) a solution or dispersion of a polymer in an organic solvent is atomized by being brought into contact with water vapour in an atomizer container; (ii) the mixture obtained in the atomizer container is routed into a polymer degasification container and flows through same, wherein the organic solvent present in the polymer particles is driven at least partially out of the polymer particles due to the thermal contact between the polymer particles and the water vapour and transitions into the gas phase (iii) the mixture exiting from the polymer degasification container is routed into a phase separator (1) and the organic solvent present in the gas phase is separated from the polymer particles and the condensed water vapour; and (iv) the polymer particles and the condensed water vapour are routed into a phase separator (2) in order to separate the polymer particles from the condensed water vapour.

摘要翻译： 本发明涉及从聚合物溶液或分散体中分离聚合物的方法，其中（i）聚合物在有机溶剂中的溶液或分散体通过与雾化容器中的水蒸气接触而雾化; （ii）将在雾化器容器中获得的混合物送入聚合物脱气容器并流过其中，其中存在于聚合物颗粒中的有机溶剂由于聚合物颗粒之间的热接触至少部分地从聚合物颗粒中驱出 和水蒸气转变成气相（iii）从聚合物脱气容器排出的混合物被引入相分离器（1）中，并且存在于气相中的有机溶剂与聚合物颗粒和冷凝水蒸气分离 ; 和（iv）将聚合物颗粒和冷凝水蒸气引入相分离器（2）中，以便将聚合物颗粒与冷凝的水蒸气分离。