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公开(公告)号：US20190194233A1
公开(公告)日：2019-06-27
申请号：US16243686
申请日：2019-01-09
申请人： Versalis S.p.A.
CPC分类号： C07F9/5045 , C07F9/46 , C08F4/20 , C08F4/68 , C08F4/68086 , C08F4/76 , C08F10/00 , C08F10/06 , C08F10/08 , C08F136/06
摘要： Vanadium phosphinic complex having general formula (I) or (II): V(X)3[P(R1)n(R2)3-n]2 (I) V(X)3[(R3)2P(R4)P(R3)2] (II) wherein: X represents an anion selected from halogens such as, for example, chlorine, bromine, iodine, preferably chlorine; or is selected from the following groups: thiocyanate, isocyanate, sulfate, acid sulfate, phosphate, acid phosphate, carboxylate, dicarboxylate; R1, identical or different among them, represent a hydrogen atom, or an allyl group (CH2═CH—CH2—); or are selected from alkyl groups C1-C20, preferably C1-C15, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups; n is an integer ranging from 0 to 3; R2, identical or different among them, are selected from optionally substituted aryl groups; R3, identical or different among them, represent a hydrogen atom, or an allyl group (CH2═CH—CH2—); or are selected from alkyl groups C1-C20, preferably C1-C15, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups, optionally substituted aryl groups; R4 represents a group —NR5 wherein R5 represents a hydrogen atom, or is selected from C1-C20 alkyl groups, preferably C1-C15, linear or branched; or R4 represents an alkylene group —(CH2) p- wherein p represents an integer ranging from 1 to 5; provided that in the general formula (I), in case n is equal to 1 and R1 is methyl, R2 is different from phenyl. Said phosphinic vanadium complex having general formula (I) or (II) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.
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公开(公告)号：US20170275312A1
公开(公告)日：2017-09-28
申请号：US15518556
申请日：2015-11-24
申请人： Versalis S.p.A.
CPC分类号： C07F9/5045 , C07F9/46 , C08F4/20 , C08F4/68 , C08F4/68086 , C08F4/76 , C08F10/00 , C08F10/06 , C08F10/08 , C08F136/06
摘要： Vanadium phosphinic complex having general formula (I) or (II): V(X)M3P̂WFys-nMO V(X)3[(R3)2P(R4)P(R3)2] (ID wherein: X represents an anion selected from halogens such as, for example, chlorine, bromine, iodine, preferably chlorine; or is selected from the following groups: thiocyanate, isocyanate, sulfate, acid sulfate, phosphate, acid phosphate, carboxylate, dicarboxylate; Ri, identical or different among them, represent a hydrogen atom, or an allyl group (CH2=CH—CH2-); or are selected from alkyl groups CrC2o, preferably CrĈ, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups; —n is an integer ranging from 0 to 3; R2, identical or different among them, are selected from optionally substituted aryl groups; R3, identical or different among them, represent a hydrogen atom, or an allyl group (CH2=CH—CH2-); or are selected from alkyl groups C1-C2o, preferably CrĈ, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups, optionally substituted aryl groups; R4 represents a group —NR5 wherein R5 represents a hydrogen atom, or is selected from C1-C20 alkyl groups, preferably CrC15, linear or branched; or R4 represents an alkylene group —(CH2) p- wherein p represents an integer ranging from 1 to 5; provided that in the general formula (I), in case n is equal to 1 and Ri is methyl, R2 is different from phenyl. Said phosphinic vanadium complex having general formula (I) or (II) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.
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公开(公告)号：US20100087608A1
公开(公告)日：2010-04-08
申请号：US12555247
申请日：2009-09-08
IPC分类号： C08F4/42
摘要： A method that is capable of producing a vinyl chloride-based polymer having excellent thermal stability without sacrificing productivity is provided. The method includes polymerizing a vinyl chloride-based monomer in the presence of a vanadium compound (A) represented by formula: Vi(═O)jZk (wherein i is an integer of 2 to 5, j represents 0 or 1, Z represents a ligand such as is an organic ligand that can bond to the vanadium atom via a hetero atom, and a plurality of ligands Z may be bonded together to form a ring that also includes the vanadium atom as a member of the ring, and k is an integer from 1 to 5), and in the presence of at least one aluminum compound (B).
摘要翻译： 提供能够生产具有优异的热稳定性而不牺牲生产率的氯乙烯类聚合物的方法。 该方法包括在由式（Ⅵ））ZZ表示的钒化合物（A）存在下聚合氯乙烯基单体：其中i为2至5的整数，j表示0或1，Z表示 配体，例如可以通过杂原子键合到钒原子上的有机配体，并且多个配位体Z可以键合在一起形成还包括钒原子作为环的成员的环，k是 1至5的整数）和至少一种铝化合物（B）的存在下进行。
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公开(公告)号：US07501479B2
公开(公告)日：2009-03-10
申请号：US11800736
申请日：2007-05-07
申请人： Mihail Ionescu , Zoran S. Petrovic
发明人： Mihail Ionescu , Zoran S. Petrovic
CPC分类号： C11C3/00 , C08F4/06 , C08F4/12 , C08F4/20 , C08F220/64
摘要： A method for the cationic polymerization of unsaturated biological oils (e.g., vegetable oils and animal oils) based on the cationic reaction of double bonds initiated by superacids is provided. The process occurs under very mild reaction conditions (about 70-110° C. and atmospheric pressure) and with short reaction times. The polymerized oils have a viscosity about 10 to 200 times higher than the initial oil and relatively high unsaturation (only about 10-30% lower than that of initial oils).
摘要翻译： 提供了基于由超强酸引发的双键的阳离子反应的不饱和生物油（例如植物油和动物油）的阳离子聚合的方法。 该过程发生在非常温和的反应条件（约70-110℃和大气压）下，反应时间短。 聚合油的粘度比初始油高约10至200倍，并且具有相对高的不饱和度（比初始油低约10-30％）。
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5.发明授权Process for producing polyisobutene using a catalytic system comprising transition metal-benzene derivative compound-methylaluminoxane 有权使用包含过渡金属 - 苯衍生物化合物 - 甲基铝氧烷的催化体系制备聚异丁烯的方法公开(公告)号：US06252021B1
公开(公告)日：2001-06-26
申请号：US09447866
申请日：1999-11-23
申请人： Kwanyoung Lee , Pil Sung Kim , IL Sang Maeng , Jong Mok Kim
发明人： Kwanyoung Lee , Pil Sung Kim , IL Sang Maeng , Jong Mok Kim
IPC分类号： C08F4649
CPC分类号： C08F110/10 , C08F10/00 , C08F4/6428 , C08F4/6494 , C08F4/20 , C08F4/6495 , C08F4/16 , C08F4/651 , C08F4/00 , C08F2500/03 , C08F2500/04
摘要： This invention relates to a process for polymerizing isobutene using a catalytic system comprising a transition metal compound, a benzene derivative compound, and methylaluminoxane, and the catalytic system applied to the polymerization of isobutene, (1) the added benzene derivative compound and methyl aluminoxane to the transition metal species provides higher stability of cation active site so that polyisobutene with a high molecular weight can be produced even at a higher reaction temperature than the conventional cationic polymerization temperature; (2) nonhalogen solvent such as toluene can be employed as a polymerization solvent instead of halogenated solvents such as methyl chloride; and (3) under the stable catalytic system, a final product with a high yield can be ensured for its long-term use.
摘要翻译： 本发明涉及使用包含过渡金属化合物，苯衍生物化合物和甲基铝氧烷的催化体系以及应用于异丁烯聚合的催化体系来聚合异丁烯的方法，（1）所添加的苯衍生物化合物和甲基铝氧烷， 过渡金属物质提供更高的阳离子活性位点的稳定性，使得即使在比常规阳离子聚合温度更高的反应温度下也可以产生高分子量的聚异丁烯; （2）非卤素溶剂如甲苯可用作聚合溶剂而不是卤代溶剂如氯甲烷; 和（3）在稳定的催化体系下，长期使用可以保证高产率的最终产品。
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公开(公告)号：US3678120A
公开(公告)日：1972-07-18
申请号：US3678120D
申请日：1970-01-29
发明人： BLOCH HERMAN S
IPC分类号： B01J27/00 , B01J27/06 , B01J27/12 , C07C2/22 , C07C2/60 , C07C2/62 , C07C2/68 , C07C2/70 , C07C5/22 , C07C5/27 , C08F10/00 , C10G45/60 , C07C15/02
CPC分类号： C10G45/60 , B01J27/00 , B01J27/06 , B01J27/12 , C07C2/22 , C07C2/60 , C07C2/62 , C07C2/68 , C07C2/70 , C07C5/2253 , C07C5/2266 , C07C5/2721 , C07C2521/18 , C07C2527/03 , C07C2527/1206 , C07C2527/133 , C08F10/00 , Y02P20/582 , C07C15/02 , C07C15/00 , C07C9/00 , C08F4/20
摘要： A hydrocarbon conversion catalyst comprising an inert support combined with an active catalytic complex comprising either SbF5HF or SbF5-HSO3F. The catalyst is particularly suitable for isomerization, alkylation and polymerization processes.
摘要翻译： 一种烃转化催化剂，包括与包含SbF 5 -FH或SbF 5 -HSO 3 F的活性催化络合物结合的惰性载体。 催化剂特别适用于异构化，烷基化和聚合过程。
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公开(公告)号：US08013088B2
公开(公告)日：2011-09-06
申请号：US12400635
申请日：2009-03-09
申请人： Mihail Ionescu , Zoran S. Petrovic
发明人： Mihail Ionescu , Zoran S. Petrovic
CPC分类号： C11C3/00 , C08F4/06 , C08F4/12 , C08F4/20 , C08F220/64
摘要： A polymerization reaction mixture for the cationic polymerization of unsaturated biological oils (e.g. vegetable oils and animals oils) based on the cationic reaction of double bonds initiated by superacids is provided. The polymerized oils have a viscosity about 10 to 200 times higher than the initial oil and relatively high unsaturation (only about 10-30% lower than that of initial oils).
摘要翻译： 提供了基于由超强酸引发的双键的阳离子反应的不饱和生物油（例如植物油和动物油）的阳离子聚合的聚合反应混合物。 聚合油的粘度比初始油高约10至200倍，并且具有相对高的不饱和度（比初始油低约10-30％）。
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公开(公告)号：US20080281071A1
公开(公告)日：2008-11-13
申请号：US11800736
申请日：2007-05-07
申请人： Mihail Ionescu , Zoran S. Petrovic
发明人： Mihail Ionescu , Zoran S. Petrovic
CPC分类号： C11C3/00 , C08F4/06 , C08F4/12 , C08F4/20 , C08F220/64
摘要： A method for the cationic polymerization of unsaturated biological oils (e.g., vegetable oils and animal oils) based on the cationic reaction of double bonds initiated by superacids is provided. The process occurs under very mild reaction conditions (about 70-110° C. and atmospheric pressure) and with short reaction times. The polymerized oils have a viscosity about 10 to 200 times higher than the initial oil and relatively high unsaturation (only about 10-30% lower than that of initial oils).
摘要翻译： 提供了基于由超强酸引发的双键的阳离子反应的不饱和生物油（例如植物油和动物油）的阳离子聚合的方法。 该过程发生在非常温和的反应条件（约70-110℃和大气压）下，反应时间短。 聚合油的粘度比初始油高约10至200倍，并且具有相对高的不饱和度（比初始油低约10-30％）。
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公开(公告)号：US06441110B1
公开(公告)日：2002-08-27
申请号：US09367194
申请日：1999-08-06
申请人： Christoph Sigwart , Thomas Narbeshuber , Karsten Eller , Manfred Barl , Rolf Fischer , Eugen Gehrer
发明人： Christoph Sigwart , Thomas Narbeshuber , Karsten Eller , Manfred Barl , Rolf Fischer , Eugen Gehrer
IPC分类号： C08F424
CPC分类号： C08F110/10 , C08F10/10 , C08F4/24 , C08F4/20 , C08F4/025
摘要： A process for preparing halogen-free, reactive polyisobutene having a terminal double bond content of more than 50 mol % and an average molecular weight Mn of 280-10000 dalton by the cationic polymerization in the liquid phase of isobutene or hydrocarbon mixtures comprising isobutene comprises polymerizing at from −30° C. to +40° C. in the presence of a heterogeneous polymerisation catalyst comprising one or more oxides of the elements of transition groups V and VI of the Periodic Table of the Elements or in the presence of a heterogeneous polymerization catalyst comprising one or more oxidic compounds of one or more elements of transition groups V and VI of the Periodic Table of the Elements supported on a non-zeolitic oxidic support material which is not an oxygen-containing zirconium compound, the catalyst not containing a technically effective amount of halogen.
摘要翻译： 通过在异丁烯或包含异丁烯的烃混合物的液相中的阳离子聚合制备末端双键含量大于50mol％，平均分子量Mn为280-10000dalton的无卤活性聚异丁烯的方法包括聚合 在-30℃至+ 40℃下，在包含元素周期表的过渡基团V和VI的元素的一种或多种氧化物的非均相聚合催化剂的存在下，或在非均相聚合 催化剂包含负载在不是含氧锆化合物的非沸石氧化载体材料上的元素周期表的一个或多个过渡基团V和VI元素的一种或多种氧化化合物，该催化剂不含技术上 有效量的卤素。
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10.发明申请High molecular weight, gel-free isobutene copolymers with elevated double bond contents 审中-公开具有升高的双键含量的高分子量，无凝胶的异丁烯共聚物公开(公告)号：US20010014726A1
公开(公告)日：2001-08-16
申请号：US09764670
申请日：2001-01-18
IPC分类号： C08F002/00
CPC分类号： C08F210/12 , C08F4/20 , C08F236/08 , C08F2500/17
摘要： The present invention provides a novel process for the production of low-gel, high molecular weight isoolefin copolymers in the presence of vanadium compounds and organic nitro compounds, in particular for the production of butyl rubbers, and isoolefin copolymers synthesized from isobutene, isoprene and optionally further monomers with a comonomer content of greater than 2.5 mol %, a molecular weight Mw of greater than 240 kg/mol and a gel content of less than 1.2 wt. %.
摘要翻译： 本发明提供了一种用于在钒化合物和有机硝基化合物存在下生产低凝胶，高分子量异烯烃共聚物的新方法，特别是用于生产丁基橡胶以及由异丁烯，异戊二烯和任选地合成的异烯烃共聚物 共聚单体含量大于2.5摩尔％，分子量Mw大于240千克/摩尔，凝胶含量小于1.2重量％的其它单体。 ％。
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