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公开(公告)号：US20220177500A1
公开(公告)日：2022-06-09
申请号：US17556199
申请日：2021-12-20
申请人： Versalis S.p.A.
IPC分类号： C07F9/50 , C07F9/46 , C08F136/06 , C08F4/68 , C08F4/76 , C08F10/06 , C08F10/08 , C08F4/20 , C08F10/00
摘要： Vanadium phosphinic complex having general formula (I) or (II): V(X)3[P(R1)n(R2)3-n]2 (I) V(X)3[(R3)2P(R4)P(R3)2] (II) wherein: X represents an anion selected from halogens; or is selected from the following groups: thiocyanate, isocyanate, sulfate, acid sulfate, phosphate, acid phosphate, carboxylate, dicarboxylate; R1, identical or different among them, represent a hydrogen atom, or an allyl group (CH2═CH—CH2—); or are selected from alkyl groups C1-C20, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups; n is an integer ranging from 0 to 3; R2, identical or different among them, are selected from optionally substituted aryl groups; R3, identical or different among them, represent a hydrogen atom, or an allyl group (CH2═CH—CH2—); or are selected from alkyl groups C1-C20, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups, optionally substituted aryl groups; R4 represents a group —NR5 wherein R5 represents a hydrogen atom, or is selected from C1-C20 alkyl groups, linear or branched; or R4 represents an alkylene group —(CH2)p- wherein p represents an integer ranging from 1 to 5; provided that in the general formula (I), in case n is equal to 1 and R1 is methyl, R2 is different from phenyl. Said phosphinic vanadium complex having general formula (I) or (II) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.
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公开(公告)号：US20190194233A1
公开(公告)日：2019-06-27
申请号：US16243686
申请日：2019-01-09
申请人： Versalis S.p.A.
CPC分类号： C07F9/5045 , C07F9/46 , C08F4/20 , C08F4/68 , C08F4/68086 , C08F4/76 , C08F10/00 , C08F10/06 , C08F10/08 , C08F136/06
摘要： Vanadium phosphinic complex having general formula (I) or (II): V(X)3[P(R1)n(R2)3-n]2 (I) V(X)3[(R3)2P(R4)P(R3)2] (II) wherein: X represents an anion selected from halogens such as, for example, chlorine, bromine, iodine, preferably chlorine; or is selected from the following groups: thiocyanate, isocyanate, sulfate, acid sulfate, phosphate, acid phosphate, carboxylate, dicarboxylate; R1, identical or different among them, represent a hydrogen atom, or an allyl group (CH2═CH—CH2—); or are selected from alkyl groups C1-C20, preferably C1-C15, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups; n is an integer ranging from 0 to 3; R2, identical or different among them, are selected from optionally substituted aryl groups; R3, identical or different among them, represent a hydrogen atom, or an allyl group (CH2═CH—CH2—); or are selected from alkyl groups C1-C20, preferably C1-C15, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups, optionally substituted aryl groups; R4 represents a group —NR5 wherein R5 represents a hydrogen atom, or is selected from C1-C20 alkyl groups, preferably C1-C15, linear or branched; or R4 represents an alkylene group —(CH2) p- wherein p represents an integer ranging from 1 to 5; provided that in the general formula (I), in case n is equal to 1 and R1 is methyl, R2 is different from phenyl. Said phosphinic vanadium complex having general formula (I) or (II) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.
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公开(公告)号：US20170275312A1
公开(公告)日：2017-09-28
申请号：US15518556
申请日：2015-11-24
申请人： Versalis S.p.A.
CPC分类号： C07F9/5045 , C07F9/46 , C08F4/20 , C08F4/68 , C08F4/68086 , C08F4/76 , C08F10/00 , C08F10/06 , C08F10/08 , C08F136/06
摘要： Vanadium phosphinic complex having general formula (I) or (II): V(X)M3P̂WFys-nMO V(X)3[(R3)2P(R4)P(R3)2] (ID wherein: X represents an anion selected from halogens such as, for example, chlorine, bromine, iodine, preferably chlorine; or is selected from the following groups: thiocyanate, isocyanate, sulfate, acid sulfate, phosphate, acid phosphate, carboxylate, dicarboxylate; Ri, identical or different among them, represent a hydrogen atom, or an allyl group (CH2=CH—CH2-); or are selected from alkyl groups CrC2o, preferably CrĈ, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups; —n is an integer ranging from 0 to 3; R2, identical or different among them, are selected from optionally substituted aryl groups; R3, identical or different among them, represent a hydrogen atom, or an allyl group (CH2=CH—CH2-); or are selected from alkyl groups C1-C2o, preferably CrĈ, linear or branched, optionally halogenated, optionally substituted cycloalkyl groups, optionally substituted aryl groups; R4 represents a group —NR5 wherein R5 represents a hydrogen atom, or is selected from C1-C20 alkyl groups, preferably CrC15, linear or branched; or R4 represents an alkylene group —(CH2) p- wherein p represents an integer ranging from 1 to 5; provided that in the general formula (I), in case n is equal to 1 and Ri is methyl, R2 is different from phenyl. Said phosphinic vanadium complex having general formula (I) or (II) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.
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