- 专利标题: BULKPOLYMERISATION PROCESS FOR THE PREPARATION OF POLYDIENES
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申请号: US16311812申请日: 2017-06-29
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公开(公告)号: US20190202944A1公开(公告)日: 2019-07-04
- 发明人: Marcus Vater , Ulrich Wendler , Michael Bartke
- 申请人: FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V.
- 优先权: EP16177220.7 20160630
- 国际申请: PCT/EP2017/066196 WO 20170629
- 主分类号: C08F2/02
- IPC分类号: C08F2/02 ; C08F236/06 ; C08F236/04 ; C08F236/10 ; C08F220/18 ; C08F2/01 ; C08F236/12 ; C08K5/56 ; C08F4/16 ; C08F4/20 ; C08F2/38
摘要:
The present invention is directed at a bulkpolymerisation process for the preparation of a polymer (P) comprising the steps of: (i) providing at least one diene monomer (DM) and optionally at least one comonomer (COM); (ii) contacting the at least one diene monomer (DM) and optionally the at least one comonomer (COM) with a catalyst system (CS) forming a reaction mixture (RM); (iii) polymerizing the reaction mixture (RM) comprising the at least one diene monomer (DM) and optionally the at least one comonomer (COM) in at least one reactor vessel (RV); (iv) isolating the polymer (P) obtained from the at least one reactor vessel (RV); wherein the reaction mixture (RM) comprises solvent, diluent and/or dispersant in an amount of ≤10 wt.-%, based on the weight of the reaction mixture (RM); and wherein the conversion rate of the diene monomer (DM) and optionally the comonomer (COM) is ≥80%.
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