METHOD OF PRODUCING POLYMERIZABLE COMPOUND, AND SOLUTION OF POLYMERIZABLE COMPOUND

    公开(公告)号:US20200283399A1

    公开(公告)日:2020-09-10

    申请号:US16497944

    申请日:2018-03-19

    申请人: ZEON CORPORATION

    IPC分类号: C07D277/82 C07C69/75

    摘要: Disclosed is a method of producing a polymerizable compound that enables production of, in high yield, a polymerizable compound used for producing an optical film or the like. The disclosed method of producing a polymerizable compound comprises reacting a compound represented by formula (I) with a compound represented by formula (II) in an organic solvent in which a base having a pKa from 6.1 to 9.5 is present, so as to obtain a reaction solution containing a polymerizable compound represented by formula (III).

    METHOD OF PRODUCING ACID HALIDE SOLUTION AND METHOD OF PRODUCING MONOESTER COMPOUND

    公开(公告)号:US20190016662A1

    公开(公告)日:2019-01-17

    申请号:US16069994

    申请日:2017-01-20

    申请人: ZEON CORPORATION

    IPC分类号: C07C51/64 C07C51/60 C07C67/14

    摘要: Provided is a method of producing an acid halide solution that is useful in production of a polymerizable liquid-crystal compound. The method of producing an acid halide solution includes: a first step of reacting a specific dicarboxylic acid compound with a halogenating agent in a water-immiscible organic solvent in the presence of at least 1.1 equivalents and not more than 3.0 equivalents of an activator relative to the dicarboxylic acid compound to obtain a reaction liquid including a solution that contains an acid halide compound and an oily liquid that is immiscible with the solution containing the acid halide compound; and a second step of removing the oily liquid from the reaction liquid obtained in the first step to obtain a purified liquid containing the acid halide compound.

    POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC SUBSTANCE

    公开(公告)号:US20170349539A1

    公开(公告)日:2017-12-07

    申请号:US15687151

    申请日:2017-08-25

    申请人: ZEON CORPORATION

    摘要: The present invention relates to: a polymerizable compound represented by a formula (I); a polymerizable composition comprising the polymerizable compound and an initiator; a polymer obtained by polymerizing the polymerizable compound or the polymerizable composition; and an optically anisotropic article comprising the polymer [in the formula, Y1 to Y8 are a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O—, or the like; G1 and G2 are a divalent aliphatic group having 1 to 20 carbon atoms, or the like; Z1 and Z2 are an alkenyl group having 2 to 10 carbon atoms, or the like; A1 is a tetravalent aromatic group, or the like; A2 and A3 are a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms, or the like; A4 and A5 are a divalent aromatic group having 4 to 30 carbon atoms, or the like; Ax1 and Ax2 are an organic group having 2 to 30 carbon atoms that includes an aromatic ring, or the like; Ay1 and Ay2 are a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like; Q1 and Q2 are a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like; and m and n are 0 or 1]. According to the present invention, a polymerizable compound, a polymerizable composition, and a polymer that have a practical low melting point, exhibit excellent solubility in a general-purpose solvent, can be produced at low cost, and can produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band, and also provide an optically anisotropic article.

    MIXTURE OF POLYMERIZABLE COMPOUND AND METHOD OF PRODUCING THE SAME

    公开(公告)号:US20200148622A1

    公开(公告)日:2020-05-14

    申请号:US16744489

    申请日:2020-01-16

    申请人: ZEON CORPORATION

    摘要: Disclosed is a mixture containing compound (I) and polymerizable compound (II) wherein compound (I) accounts for 50 mol % or more of the entire mixture and 1,4-cyclohexanedicarboxylic acid accounts for less than 5 mol % of the entire mixture; a method of producing the mixture which includes reacting in a water-immiscible organic solvent 1,4-cyclohexanedicarboxylic acid dichloride with compound (IV) in the presence of a base, and washing the obtained reaction solution with a weakly acidic buffer solution; etc. The disclosure provides mixtures useful for low-cost production of polymerizable compounds which have low melting points suitable for practical use, show superior solubility to general-purpose solvents, can be produced at low costs, and allow for provision of optical films capable of uniform polarized light conversion over a wide wavelength range, and methods of producing the mixtures. where A represents hydrogen, methyl group or chlorine, and n represents an integer of 1 to 20.

    POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC MATERIAL
    20.
    发明申请
    POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC MATERIAL 审中-公开
    可聚合化合物,聚合物,聚合物和光学非均质材料

    公开(公告)号:US20170044279A1

    公开(公告)日:2017-02-16

    申请号:US15338987

    申请日:2016-10-31

    申请人: ZEON CORPORATION

    摘要: The present invention relates to: a polymerizable compound (I), wherein Y1 to Y6 are a chemical single bond, —O—C(═O)—, —C(═O)—O— or the like, G1 and G2 are a divalent aliphatic group, Z1 and Z2 are an alkenyl group, Ax is a fused ring group represented by a formula (II), wherein X is —NR3—, an oxygen atom, a sulfur atom or the like, R3 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and D is a substituted or unsubstituted ring having 1 to 20 carbon atoms that includes at least one nitrogen atom, Ay is a hydrogen atom, an alkyl group, A1 is a trivalent aromatic group or the like, A2 and A3 are a divalent aromatic group having 6 to 30 carbon atoms or the like, and Q1 is a hydrogen atom, or an alkyl group having 1 to 6 carbon atoms.

    摘要翻译: 本发明涉及:可聚合化合物(1),其中Y 1至Y 6为化学单键,-OC(= O) - , - C(= O)-O-等,G 1和G 2为碳原子数为1〜20的二价脂肪族基团,Z 1和Z 2为未取代或被卤素原子取代的碳原子数2〜10的烯基,A x为 式(II)其中X为-NR 3 - ,氧原子,硫原子等,R 3为氢原子或碳原子数1〜6的烷基,D为取代或未取代的环 具有1至20个碳原子,包括至少一个氮原子,A y是氢原子,具有1至20个碳原子的烷基等,A 1是三价芳族基团等,A 2和A 3 是碳原子数为6〜30的二价芳香族基团,Q 1为氢原子或碳原子数为1〜6的烷基。 本发明提供一种具有实用低熔点,在通用溶剂中表现出优异溶解性的聚合性化合物,聚合性组合物和聚合物,可以制造出低成本的光学膜, 在宽波长带上的偏振光,以及光学各向异性物品。