摘要:
Disclosed is a method of producing a polymerizable compound that enables production of, in high yield, a polymerizable compound used for producing an optical film or the like. The disclosed method of producing a polymerizable compound comprises reacting a compound represented by formula (I) with a compound represented by formula (II) in an organic solvent in which a base having a pKa from 6.1 to 9.5 is present, so as to obtain a reaction solution containing a polymerizable compound represented by formula (III).
摘要:
A polymerizable compound has a practical low melting point, excellent solubility in a general-purpose solvent, and can produce an optical film at low cost, exhibits low reflected luminance, and achieves uniform conversion of polarized light over a wide wavelength band, an optically anisotropic article.
摘要:
Provided is a polymerizable composition that is capable of forming an optical film, etc. having excellent reverse wavelength dispersibility, can be prepared at relatively low temperature, and has excellent stability around room temperature. A mixture comprises a polymerizable compound represented by the following Formula (I) and a polymerizable compound represented by the following Formula (II):
摘要:
A polymerizable compound indicated by the following formula (I). In formula (I): Ar represents an optionally substituted aromatic hydrocarbon cyclic group/aromatic heterocyclic group; D represents an organic group having a carbon number of 1 to 67 and including an aromatic ring; Z1, Z2, and Y0 to Y4 each represent atomic bonding; L1 and L2 each represent a chain group; G represents an optionally substituted alicyclic group/aromatic group/alkylene group; A1, A2, B1, and B2 each represent an alicyclic group or an aromatic group; P1 and P2 each represent a hydrogen atom or a polymerizable group; and p and q are each, independently of one another, an integer of 0 to 2, with a proviso that cases in which p=0 and q=1 and in which p=1 and q=2 are excluded.
摘要:
Provided is a method of producing an acid halide solution that is useful in production of a polymerizable liquid-crystal compound. The method of producing an acid halide solution includes: a first step of reacting a specific dicarboxylic acid compound with a halogenating agent in a water-immiscible organic solvent in the presence of at least 1.1 equivalents and not more than 3.0 equivalents of an activator relative to the dicarboxylic acid compound to obtain a reaction liquid including a solution that contains an acid halide compound and an oily liquid that is immiscible with the solution containing the acid halide compound; and a second step of removing the oily liquid from the reaction liquid obtained in the first step to obtain a purified liquid containing the acid halide compound.
摘要:
The present invention relates to: a polymerizable compound represented by a formula (I); a polymerizable composition comprising the polymerizable compound and an initiator; a polymer obtained by polymerizing the polymerizable compound or the polymerizable composition; and an optically anisotropic article comprising the polymer [in the formula, Y1 to Y8 are a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O—, or the like; G1 and G2 are a divalent aliphatic group having 1 to 20 carbon atoms, or the like; Z1 and Z2 are an alkenyl group having 2 to 10 carbon atoms, or the like; A1 is a tetravalent aromatic group, or the like; A2 and A3 are a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms, or the like; A4 and A5 are a divalent aromatic group having 4 to 30 carbon atoms, or the like; Ax1 and Ax2 are an organic group having 2 to 30 carbon atoms that includes an aromatic ring, or the like; Ay1 and Ay2 are a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like; Q1 and Q2 are a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like; and m and n are 0 or 1]. According to the present invention, a polymerizable compound, a polymerizable composition, and a polymer that have a practical low melting point, exhibit excellent solubility in a general-purpose solvent, can be produced at low cost, and can produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band, and also provide an optically anisotropic article.
摘要:
Disclosed is a mixture containing compound (I) and polymerizable compound (II) wherein compound (I) accounts for 50 mol % or more of the entire mixture and 1,4-cyclohexanedicarboxylic acid accounts for less than 5 mol % of the entire mixture; a method of producing the mixture which includes reacting in a water-immiscible organic solvent 1,4-cyclohexanedicarboxylic acid dichloride with compound (IV) in the presence of a base, and washing the obtained reaction solution with a weakly acidic buffer solution; etc. The disclosure provides mixtures useful for low-cost production of polymerizable compounds which have low melting points suitable for practical use, show superior solubility to general-purpose solvents, can be produced at low costs, and allow for provision of optical films capable of uniform polarized light conversion over a wide wavelength range, and methods of producing the mixtures. where A represents hydrogen, methyl group or chlorine, and n represents an integer of 1 to 20.
摘要:
The objective is to enable production of an optical film having good reverse wavelength dispersion. A mixture contains polymerizable compounds indicated by formulae (I) and (V), shown below. In the formulae: Ar1 and Ar2 are each a prescribed heterocyclic group; A1 to A4 and B1 to B4 are each an optionally substituted alicyclic group or aromatic group; Y1 to Y4, L1 to L4, and Z1 to Z4 are each a prescribed group such as —O—, —CO—O—, or —O—CO—; R1 to R6 are each a hydrogen atom, a methyl group, or a chlorine atom; one of e and f is an integer of 1 to 3 and the other of e and f is an integer of 0 to 3; c, d, i, and j are each an integer of 1 to 20; and a, b, g, and h are each 0 or 1.
摘要:
A compound represented by a formula (IIa) is provided. In formula (IIa), Y1 to Y8 represent —O—, —S—, —O—C(═O)—, —C(═O)—O— or the like, G1 and G2 represent a divalent linear aliphatic group having 1 to 20 carbon atoms or the like, Z1 and Z2 represent an alkenyl group having 2 to 10 carbon atoms or the like, Ax represents a group represented by a formula (II), wherein X represents an oxygen atom, a sulfur atom or the like, D represents an alkylene group having 1 to 20 carbon atoms or the like, A1 represents a trivalent aromatic group or the like, A2 and A3 represent a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms or the like, A4 and A5 represent a divalent aromatic group having 4 to 30 carbon atoms or the like, Q1 represents an alkyl group having 1 to 6 carbon atoms or the like, and m and n are 0 or 1.
摘要:
The present invention relates to: a polymerizable compound (I), wherein Y1 to Y6 are a chemical single bond, —O—C(═O)—, —C(═O)—O— or the like, G1 and G2 are a divalent aliphatic group, Z1 and Z2 are an alkenyl group, Ax is a fused ring group represented by a formula (II), wherein X is —NR3—, an oxygen atom, a sulfur atom or the like, R3 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and D is a substituted or unsubstituted ring having 1 to 20 carbon atoms that includes at least one nitrogen atom, Ay is a hydrogen atom, an alkyl group, A1 is a trivalent aromatic group or the like, A2 and A3 are a divalent aromatic group having 6 to 30 carbon atoms or the like, and Q1 is a hydrogen atom, or an alkyl group having 1 to 6 carbon atoms.