摘要:
Phenolic age resistors such as 4-(3,5-ditertiary butyl-4-hydroxyphenyl)-2-butyl 2-methyl-4-thia-6-octanoyloxy-hexanoate are used as antioxidants in diene rubbers, such as butadiene-styrene types and in polyolefins, such as polypropylene.
摘要:
3,5-Di-tert alkyl-4-hydroxybenzylpyridinium salts are reacted under basic conditions with compounds containing active methylene groups to form phenolic antioxidants. For example, 3,5-di-tert.butyl-4-hydroxybenzylpyridinium chloride is reacted with 2-nitropropane to produce 1,1-dimethyl-2-(3,5-di tert.butyl-4-hydroxyphenyl)-1-nitroethane.
摘要:
Antioxidants such as 3,5-di tert.butyl-4-hydroxyphenyl acrylate and 3,5-di tert.butyl-4-hydroxyphenyl methacrylate, age resistant polymers having age resistors physically combined therewith and age resistant polymeric compositions prepared by emulsion free radical polymerization techniques involving the use of said age resistors as monomers.
摘要:
Antioxidants such as 3,5-di tert.butyl-4-hydroxy-cinnamonitrile and ethyl 3,5-di tert.hexyl-4-hydroxycinnamate, age resistant polymers having monomeric age resistors physically combined therewith and age resistant polymeric compositions prepared by free radical polymerization techniques involving the use of said antioxidants as monomers.
摘要:
An expanded metal battery grid and process for making same which grid has a supporting border comprising a thermoplastic ribbon folded lengthwise around the grid's edge and ultrasonically bonded to itself through interstices in the grid.
摘要:
A battery container, the walls of which, include integrally molded, resilient ribs extending at acute angles from the walls to retain the battery's electrochemical innards firmly in the container. Each as-molded rib is plastically deformed and reshaped so that a lead-in portion thereof near the container opening is at a lesser angle with respect to the wall than the undeformed portion of the rib which serves to resiliently retain the innards. The section of rib between the lead-in portion and retaining portion extends at various angles intermediate the other angles and provide an incline or ramp for facilitating insertion of the battery's innards into the container. The tooling used to plastically deform the lead-in portion of the rib may also include means for tearing the bottom of the rib away from the bottom of the container.
摘要:
Compounds of the formula: ##STR1## wherein R, R' and R.sup.2 are alkyl radicals having 1 to 20 carbon atoms, phenyl radicals which may be substituted by 1 or 2 alkyl groups having 1 to 8 carbon atoms, aralkyl radicals having 7 to 12 carbon atoms, or cycloalkyl radicals having 5 to 12 carbon atoms; and wherein R.sup.3 is hydrogen or an alkyl radical having from 1 to 4 carbon atoms. These compounds have utility as synergistic stabilizers with phenolic type antioxidants for the stabilization of organic materials such as natural and synthetic polymers, rubbers, lubricants and oils, etc.
摘要:
A battery container, the walls of which, include integrally molded, resilient ribs extending at acute angles from the walls to retain the battery's electrochemical innards firmly in the container. Each as-molded rib is plastically deformed and reshaped so that a lead-in portion thereof near the container opening is at a lesser angle with respect to the wall than the undeformed portion of the rib which serves to resiliently retain the innards. The section of rib between the lead-in portion and retaining portion extends at various angles intermediate the other angles and provide an incline or ramp for facilitating insertion of the battery's innards into the container. The tooling used to plastically deform the lead-in portion of the rib may also include means for tearing the bottom of the rib away from the bottom of the container.
摘要:
There is a process disclosed for alkylating the nucleus of a phenol, said process comprising reacting an .alpha., .omega.alkanediol containing from 3 to 8 carbon atoms with a phenol having an unsubstituted nuclear position para to the phenolic hydroxyl group; said phenol being selected from the group of alkylated phenols having tertiary alkyl groups of 4 to 8 carbon atoms in both positions ortho to the phenolic hydroxyl group, in the presence of an alkali metal hydroxide or alkoxide or alkali metal at a temperature from 200.degree. to 300.degree. C. while continuously removing the water by-product as it forms and obtaining as a product said phenol having a primary hydroxy terminated alkyl group of 3 to 8 carbon atoms in said para position.
摘要:
Compounds of the formula: ##STR1## wherein R is selected from (1) alkyl radicals having 6 to 20 carbon atoms; (2) phenyl radicals which may be substituted by 1 or 2 alkyl groups having 1 to 8 carbon atoms; or (3) aralkyl radicals having 7 to 12 carbon atoms; and wherein R.sup.1 is selected from (1) alkylene radicals having 2 to 6 carbon atoms; (2) cycloalkylene radicals having 5 to 12 carbon atoms; (3) alkylcycloalkylene radicals of the formula --R.sub.3 --R.sub.2 (R.sub.4).sub.n, wherein R.sub.2 is a cycloalkylene radical having 5 to 12 carbon and R.sub.3 and R.sub.4 are alkylene radicals having 1 to 6 carbon atoms, and n equals 1 or 0; (4) or a group of the formula --R.sub.5 --YR.sub.6, wherein R.sub.5 and R.sub.6 are alkylene radicals having 2 to 6 carbon atoms and Y is oxygen, sulfur, or a 1,4-phenylene radical. These compounds have utility as synergistic stabilizers with phenolic type antioxidants in the stabilization of organic materials such as natural and synthetic polymers, rubbers, lubricants and oils, etc.