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公开(公告)号：US20090137758A1
公开(公告)日：2009-05-28
申请号：US11921535
申请日：2006-05-29
CPC分类号： C08F220/36
摘要： The instant invention relates to a process for the preparation of polymeric nitroxide radicals by group transfer polymerization. Further aspects of the invention are the polymers containing the nitroxide radicals as well as their use, in particular as active electrode materials in organic radical batteries.
摘要翻译： 本发明涉及通过基团转移聚合制备聚合氮氧自由基的方法。 本发明的其它方面是含有氮氧自由基的聚合物及其用途，特别是作为有机基团电池中的活性电极材料。
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公开(公告)号：US20130289174A1
公开(公告)日：2013-10-31
申请号：US13976045
申请日：2011-12-15
申请人： Philippe Bugnon , Peter Nesvadba
发明人： Philippe Bugnon , Peter Nesvadba
CPC分类号： C09D7/007 , C07C245/04 , C07C255/65 , C07C281/20 , C07C309/51 , C07C2601/14 , C07C2601/20 , C07F9/3808 , C07F9/3882 , C07F9/4006 , C09B67/0004 , C09B67/0034 , C09B68/26 , C09B68/4475 , C09D7/41 , C09D11/037
摘要： A pigment preparation is provided, said preparation comprises an organic pigment comprising a chromophore Q1 and a derivative thereof comprising specific organic substituents via an aliphatic carbon atom in an amount of from 0.1 to 30 mol, based on 100 mol of the organic pigment as well as a process for its preparation and to its use in coloring an organic material such as plastics, coatings or inks.
摘要翻译： 提供颜料制剂，所述制剂包含有机颜料，其包含发色团Q1及其衍生物，其衍生物含有基于100mol有机颜料的0.1-30mol脂族碳原子的特定有机取代基，以及 其制备方法和用于着色有机材料如塑料，涂料或油墨的方法。
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公开(公告)号：US08507569B2
公开(公告)日：2013-08-13
申请号：US13255543
申请日：2010-03-17
CPC分类号： G03F7/028 , C07D211/94 , C07D491/113 , C08F110/02 , C08F110/06 , C08F265/02 , C08K5/3435 , G03F7/0007 , G03F7/031 , G03F7/40 , C08L33/06
摘要： The present invention relates to a radically polymerizable composition comprising a hydroxylamine ester used to manufacture color filters. The invention further relates to novel hydroxylamine esters. The invention further relates to the use of hydroxylamine esters in all liquid crystal display components requiring post-baking. The present invention relates to a radically polymerizable composition comprising: (a) at least one alkaline developable resin; (b) at least one acrylate monomer; (c) at least a photoinitiator; (d) at least one hydroxylamine ester compound of formula (I) wherein Ra represents an acyl radical; one of Rb and Rc represents hydrogen and the other one represents a substituent; or Rb and Rc both represent hydrogen or identical or different substituents; or Rb and Rc together represent oxygen; or Rb and Rc together form a ring; R1-R4 each represent C1-C6 alkyl; and R5 and R6 each represent independently of one another hydrogen, C1-C6 alkyl or C6-C10 aryl; or R5 and R6 together represent oxygen.
摘要翻译： 本发明涉及一种可自由基聚合的组合物，其包含用于制造滤色器的羟胺酯。 本发明还涉及新的羟胺酯。 本发明还涉及在需要后烘烤的所有液晶显示组件中使用羟胺酯。 本发明涉及可自由基聚合的组合物，其包含：（a）至少一种碱性显影树脂; （b）至少一种丙烯酸酯单体; （c）至少一种光引发剂; （d）至少一种式（I）的羟胺酯化合物，其中R a表示酰基; Rb和Rc之一表示氢，另一个表示取代基; 或Rb和Rc都表示氢或相同或不同的取代基; 或Rb和Rc一起代表氧; 或Rb和Rc一起形成环; R1-R4各自表示C1-C6烷基; R 5和R 6各自独立地表示氢，C 1 -C 6烷基或C 6 -C 10芳基; 或R5和R6一起表示氧。
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14.发明授权公开(公告)号：US08134009B2
公开(公告)日：2012-03-13
申请号：US12854677
申请日：2010-08-11
IPC分类号： C07D211/00 , C07D213/72 , C07D401/00
CPC分类号： C07D491/10 , C07B61/02 , C07D211/94
摘要： The invention relates to a process for the preparation of secondary nitroxide radicals from their corresponding secondary amines by oxidation with an organic peracid, comprising the steps a) adding to a reaction vessel a secondary amine, optionally together with an organic solvent and in one batch a base selected from the group consisting of alkali metal, alkaline earth metal or ammonium bicarbonates and alkaline earth metal or ammonium carbonates or mixtures thereof in the form of a solid together with water or as an aqueous slurry; b) dosing a peracid under stirring to the reaction mixture in an amount of 1.0 to 2.5 mol per mol of secondary amine; and c) isolating the organic phase.
摘要翻译： 本发明涉及通过用有机过酸氧化从其相应的仲胺制备二级氮氧自由基的方法，包括以下步骤：a）向反应容器中加入仲胺，任选与有机溶剂一起加入一次 碱选自碱金属，碱土金属或碳酸氢铵，碱土金属或铵的碳酸盐或其混合物，其形式为水，或与水相混合; b）在搅拌下将过酸给予反应混合物，其量为每摩尔仲胺为1.0至2.5摩尔; 和c）分离有机相。
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公开(公告)号：US08105504B2
公开(公告)日：2012-01-31
申请号：US11660534
申请日：2005-08-22
申请人： Michèle Gerster , Peter Nesvadba
发明人： Michèle Gerster , Peter Nesvadba
CPC分类号： C07C69/604 , C07C255/34 , C07C255/41 , C07C317/24 , C07C317/44 , C07C2602/08 , C07C2603/18 , C07D307/83 , C08K5/005 , C08K5/1535 , C08K5/315 , C08K5/41 , C08L21/00 , C08L23/02 , C08L69/00 , C08L75/04
摘要： Organic materials which possess outstanding stability to oxidative, thermal or light-induced degradation comprise as stabilizers at least one compound of the formula (I) wherein the general symbols are as defined in claim 1. The compounds of formula I are especially useful as stabilizers for protecting polymers and lubricants against oxidative, thermal or light-induced degradation and as scavengers for oxidized developer in color photographic material.
摘要翻译： 具有优异的氧化，热或光诱导降解稳定性的有机材料包含至少一种式（I）化合物作为稳定剂，其中通式为如权利要求1所定义。式I化合物特别用作 保护聚合物和润滑剂免受氧化，热或光诱导的降解和作为彩色照相材料中氧化显影剂的清除剂。
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公开(公告)号：US20100233537A1
公开(公告)日：2010-09-16
申请号：US12225333
申请日：2007-03-12
申请人： Peter Nesvadba , Lucienne Bugnon
发明人： Peter Nesvadba , Lucienne Bugnon
IPC分类号： H01M4/60 , C07D401/14 , C07D487/18
CPC分类号： H01M4/60 , H01M4/13 , H01M4/131 , H01M4/136 , H01M4/137 , H01M4/364 , H01M4/62 , H01M2004/028
摘要： The invention relates to a stable secondary battery utilizing as active element the oxidation and reduction cycle of a sterically hindered nitroxide radical, which is bonded to a triazine structural element. Further aspects of the invention are a method for providing such a secondary battery, the use of the respective compounds as active elements in secondary batteries and selected novel nitroxide compounds as such.
摘要翻译： 本发明涉及一种稳定的二次电池，其利用与三嗪结构元件结合的空间位阻的氮氧自由基的氧化和还原循环作为活性元素。 本发明的另外的方面是提供这种二次电池的方法，各种化合物作为二次电池中的活性元素的用途以及选择的新的氮氧化物化合物。
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17.发明授权公开(公告)号：US07358365B2
公开(公告)日：2008-04-15
申请号：US11339214
申请日：2006-01-25
IPC分类号： C07D471/02
CPC分类号： C07D491/10 , C07C239/22 , C07D209/44 , C07D211/94 , C07D233/32 , C07D233/38 , C07D241/08 , C07D295/24 , C07D401/14 , C07D487/10 , C07F9/59 , C08F2/38 , C08F4/00 , C08F8/30 , C08F8/50 , C08F110/02 , C08F110/06 , C08K5/3435 , C08L23/06 , C08L23/10 , C08L2023/44 , C08L2205/02 , C08L2666/06 , C08F8/00
摘要： The invention relates to novel cyclic hydroxylamine esters and to the use of known hydroxylamine esters selected from the group consisting of HALS (sterically hindered amine) compounds and the novel hydroxylamine esters achieving a controlled increase in the molecular weight of polyethylene.
摘要翻译： 本发明涉及新的环状羟胺酯，以及选自HALS（空间位阻胺）化合物和新型羟胺酯的已知羟胺酯的用途，可实现聚乙烯分子量的可控增加。
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公开(公告)号：US20080045662A1
公开(公告)日：2008-02-21
申请号：US11661450
申请日：2005-08-31
申请人： Michael Roth , Peter Nesvadba , David Horst
发明人： Michael Roth , Peter Nesvadba , David Horst
IPC分类号： C08K5/3435 , C08J11/28 , C08K5/37 , C08L23/02
CPC分类号： C08J11/28 , C08J2323/10 , C08J2323/12 , Y02W30/706
摘要： The invention relates to novel composition comprising hydroxylamine esters and thio compounds, which are suitable for lowering the molecular weight of polypropylene, propylene copolymers or polypropylene blends and result in an excellent degradation performance at temperatures below 220° C.
摘要翻译： 本发明涉及包含羟胺酯和硫代化合物的新型组合物，其适用于降低聚丙烯，丙烯共聚物或聚丙烯共混物的分子量，并在低于220℃的温度下产生优异的降解性能。
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19.发明授权N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding N-oxides and controlled radical polymerization therewith 失效N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶化合物，它们相应的N-氧化物和受控自由基聚合公开(公告)号：US07288613B2
公开(公告)日：2007-10-30
申请号：US11364537
申请日：2006-02-28
CPC分类号： C07D211/94 , C07D491/113 , C07D491/22 , C07D519/00 , C08F2/46 , C08F4/00
摘要： The present invention relates to selected 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.
摘要翻译： 本发明涉及选择的1-烷氧基-2,2,6,6四甲基哌啶，1-烷氧基-2,2二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,3,6-二甲基 哌啶衍生物，其在4位被两个形成开链或环状缩酮结构的氧原子取代，所述可聚合组合物包含a）至少一种烯属不饱和单体和b）所述哌啶衍生物。 本发明的另外的方面是使烯键式不饱和单体聚合的方法，以及使用1-烷氧基-2,2,6,6四甲基哌啶，1-烷氧基-2,2二乙基-6,6二甲基哌啶和1- 烷氧基-2,6-二乙基-2,3,6二甲基哌啶衍生物，其在4位被两个氧原子取代，形成用于受控聚合的开链或环状缩酮结构。 中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂的组合物以及聚合方法也是本发明的主题。
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公开(公告)号：US20070232768A1
公开(公告)日：2007-10-04
申请号：US11596436
申请日：2005-05-17
申请人： Peter Nesvadba , Andreas Kramer , Lucienne Bugnon
发明人： Peter Nesvadba , Andreas Kramer , Lucienne Bugnon
IPC分类号： C08F4/00 , C07D211/94 , C07D241/08 , C07F9/40
CPC分类号： C07D241/08 , C07D211/94
摘要： The instant invention relates to novel alkoxyamine initiators/regulators containing an ethylenically unsaturated, radically polymerizable group. The compounds are useful for the preparation of complex polymeric architectures. Further aspects of the invention are a polymerizable composition and a polymerization process comprising the alkoxyamine initiators/regulators, a macroinitiator obtainable by said polymerization process and a process for polymerizing with the macroinitiator.
摘要翻译： 本发明涉及含有烯属不饱和的，可自由基聚合的基团的新的烷氧基胺引发剂/调节剂。 该化合物可用于制备复合聚合物结构。 本发明的其它方面是可聚合组合物和包含烷氧基胺引发剂/调节剂的聚合方法，通过所述聚合方法获得的大分子引发剂和与大分子引发剂聚合的方法。
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