公开(公告)号：US09969659B2

公开(公告)日：2018-05-15

申请号：US14915553

申请日：2015-09-16

Applicant: LG CHEM, LTD.

Inventor： Yong Ho Lee ,  Seok Pil Sa ,  Eun Ji Shin ,  Ki Soo Lee ,  Jin Young Park ,  Seul Ki Im ,  Yoon Ki Hong

IPC: C07C11/00 ,  C07C13/12 ,  C07C13/11 ,  C07C9/14 ,  C07C2/42 ,  B01J31/18 ,  C07C13/10 ,  C07C2/32

CPC classification number: C07C2/42 ,  B01J31/188 ,  B01J2231/20 ,  B01J2531/62 ,  C07C2/32 ,  C07C13/10 ,  C07C13/11 ,  C07C13/12 ,  C07C2531/18 ,  C07C2601/08 ,  C07C2601/10 ,  Y02P20/52 ,  C07C11/02

Abstract: The present invention relates to a 1-octene composition. The 1-octene composition according to the present invention is prepared by ethylene oligomerization and comprises a high content of 1-octene and monomers useful for copolymerization of 1-octene at the same time.

公开(公告)号：US09926395B2

公开(公告)日：2018-03-27

申请号：US15026544

申请日：2014-10-15

Applicant: LG CHEM, LTD.

Inventor： Dae Sik Hong ,  Heon Yong Kwon ,  Eun Kyoung Song ,  Yong Ho Lee ,  Kyung Jin Cho ,  Ki Soo Lee ,  Yi Young Choi

IPC: C08F210/16 ,  C08F4/6592 ,  B01J31/12 ,  C07F17/00 ,  C08F4/64 ,  C07F7/08 ,  B01J31/22

CPC classification number: C08F210/16 ,  B01J31/12 ,  B01J31/2295 ,  B01J2531/48 ,  C07F7/0814 ,  C07F17/00 ,  C08F4/64 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F2420/02 ,  C08F2420/06 ,  C08F10/00 ,  C08F4/65904 ,  C08F4/65916 ,  C08F210/14 ,  C08F2500/04

Abstract: The present invention relates to a hybrid supported metallocene catalyst. More specifically, the present invention relates to a hybrid supported metallocene catalyst using two or more different types or more of metallocene compounds, among which one type of the metallocene compounds shows a high polymerization activity even when it is supported, and thus the catalyst has an excellent activity and can be utilized in the polymerization of olefinic polymers having ultra-high molecular weight. Based on the hybrid supported metallocene catalyst of the present invention, an olefinic polymer having high molecular weight and the desired physical property can be prepared.

公开(公告)号：US09828403B2

公开(公告)日：2017-11-28

申请号：US15037483

申请日：2015-08-12

Applicant: LG CHEM, LTD.

Inventor： Sung Min Lee ,  Ki Soo Lee ,  Heon Yong Kwon ,  Dae Sik Hong ,  Se Young Kim ,  Yong Ho Lee ,  Eun Young Shin ,  Sung Ho Park ,  Min Seok Cho ,  Kyung Jin Cho ,  Jin Young Park

IPC: C07F17/00 ,  C08F4/6592 ,  C08F10/00 ,  C08F4/659 ,  C08F110/02

CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/02

Abstract: The present invention relates to a transition metal compound that may exhibit high activity in olefin polymerization, and easily control the properties of synthesized olefin polymer such as a chemical structure, molecular weight distribution, a mechanical property, and the like, a catalyst composition comprising the same, and a method for olefin polymerization using the catalyst composition.

公开(公告)号：US09725472B2

公开(公告)日：2017-08-08

申请号：US14908819

申请日：2013-10-14

Applicant: LG CHEM, LTD.

Inventor： Yong Ho Lee ,  Eun Kyoung Song ,  Kyung Jin Cho ,  Ki Soo Lee ,  Se Young Kim ,  Sung Min Lee ,  Hyuck Ju Kwon ,  Yi Young Choi ,  Heon Yong Kwon ,  Min Seok Cho ,  Dae Sik Hong

IPC: C07F17/00 ,  C08F4/6592 ,  C08F10/00 ,  C07F7/08 ,  B01J31/12 ,  C07F7/10 ,  C08F110/02 ,  C08F210/16

CPC classification number: C07F7/0803 ,  B01J31/12 ,  B01J31/1608 ,  B01J31/2295 ,  B01J2531/48 ,  C07F7/10 ,  C07F17/00 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2410/03 ,  C08F2420/06 ,  C08F210/14 ,  C08F2500/01

Abstract: The present invention relates to a novel metallocene compound, a catalyst composition including the same, and a method of preparing an olefinic polymer by using the same. The metallocene compound according to the present invention and the catalyst composition comprising the same can be used for producing olefinic polymers, have outstanding polymerizing ability, and can produce olefinic polymers of ultra high molecular weight. In particular, when the metallocene compound according to the present invention is employed, an olefinic polymer of ultra high molecular weight can be obtained because it shows high polymerization activity even when it is supported on a carrier and maintains high activity even in the presence of hydrogen because of its low hydrogen reactivity.

公开(公告)号：US09206272B2

公开(公告)日：2015-12-08

申请号：US14378548

申请日：2013-05-10

Applicant: LG CHEM, LTD.

Inventor： Heon Yong Kwon ,  Yong Ho Lee ,  Kyoung-Chan Lim ,  Ki Soo Lee ,  Min Seok Cho

IPC: B01J21/00 ,  B01J23/00 ,  B01J31/00 ,  C08F4/24 ,  C07C2/02 ,  C07C2/04 ,  C08F110/02 ,  B01J31/16 ,  C07F11/00 ,  C07F7/10 ,  C07F7/20 ,  C08F4/52 ,  C08F4/78

CPC classification number: C08F110/02 ,  B01J31/16 ,  C07F7/10 ,  C07F7/20 ,  C07F11/00 ,  C08F4/52 ,  C08F4/78 ,  C08F210/02 ,  C08F4/69215

Abstract: The present invention relates to a method for ethylene oligomerization. According to the method of the present invention, highly active ethylene oligomerization reaction is possible by using a catalyst system including a novel chromium compound exhibiting high activity for ethylene oligomerization reaction, and therefore, polyethylene can be prepared using a small amount of comonomers or using only ethylene without comonomers.

Abstract translation: 本发明涉及乙烯低聚方法。 根据本发明的方法，通过使用包含对乙烯低聚反应具有高活性的新型铬化合物的催化剂体系，可以进行高活性乙烯低聚反应，因此可以使用少量共聚单体或仅使用聚乙烯制备聚乙烯 没有共聚单体的乙烯。

公开(公告)号：US20150240010A1

公开(公告)日：2015-08-27

申请号：US14426656

申请日：2014-02-05

Applicant: LG CHEM, LTD.

Inventor： Dae Sik Hong ,  Ki Soo Lee ,  Heon Yong Kwon ,  Hyeon-Gook Kim ,  Eun Kyoung Song ,  Yong Ho Lee

IPC: C08F210/02 ,  C07F7/08

CPC classification number: C08F110/02 ,  B01J21/08 ,  B01J31/069 ,  B01J31/143 ,  B01J31/1616 ,  B01J31/2295 ,  B01J37/0209 ,  B01J2531/48 ,  C07F3/02 ,  C07F5/066 ,  C07F7/087 ,  C07F7/0876 ,  C07F17/00 ,  C08F4/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F10/02 ,  C08F210/02 ,  C08F2410/01 ,  Y02P20/52

Abstract: This disclosure relates to a silica support for a metallocene catalyst used for olefin polymerization, a preparation method thereof, a metallocene catalyst using the same, and olefin polymer. Specifically, according to the present invention, a silica support used for preparing a metallocene supported catalyst is treated with a specific halogenized metal compound, thereby diversifying reaction sites to a cocatalyst when preparing a metallocene catalyst, and thus, the molecular weight distribution of produced olefin polymer may be much broadened and polymer having high molecular weight may be obtained compared to the existing support, even if the same metallocene catalyst is supported.

Abstract translation: 本公开内容涉及用于烯烃聚合的茂金属催化剂的二氧化硅载体，其制备方法，使用它的金属茂催化剂和烯烃聚合物。 具体地，根据本发明，用于制备茂金属负载的催化剂的二氧化硅载体用特定的卤化金属化合物处理，从而在制备茂金属催化剂时将反应位点分散到助催化剂上，因此，制备的烯烃的分子量分布 聚合物可能会变宽，即使支持相同的茂金属催化剂，也可以获得与现有载体相比具有高分子量的聚合物。

公开(公告)号：US20150018502A1

公开(公告)日：2015-01-15

申请号：US14378548

申请日：2013-05-10

Applicant: LG CHEM, LTD.

Inventor： Heon Yong Kwon ,  Yong Ho Lee ,  Kyoung-Chan Lim ,  Ki Soo Lee ,  Min Seok Cho

IPC: C08F110/02

CPC classification number: C08F110/02 ,  B01J31/16 ,  C07F7/10 ,  C07F7/20 ,  C07F11/00 ,  C08F4/52 ,  C08F4/78 ,  C08F210/02 ,  C08F4/69215

Abstract: The present invention relates to a method for ethylene oligomerization. According to the method of the present invention, highly active ethylene oligomerization reaction is possible by using a catalyst system including a novel chromium compound exhibiting high activity for ethylene oligomerization reaction, and therefore, polyethylene can be prepared using a small amount of comonomers or using only ethylene without comonomers.

Abstract translation: 本发明涉及乙烯低聚方法。 根据本发明的方法，通过使用包含对乙烯低聚反应具有高活性的新型铬化合物的催化剂体系，可以进行高活性乙烯低聚反应，因此可以使用少量共聚单体或仅使用聚乙烯制备聚乙烯 没有共聚单体的乙烯。

公开(公告)号：US10688473B2

公开(公告)日：2020-06-23

申请号：US15518431

申请日：2015-12-02

Applicant: LG CHEM, LTD.

Inventor： Yong Ho Lee ,  Eun Ji Shin ,  Jin Young Park ,  Seok Pil Sa ,  Ki Soo Lee

IPC: B01J23/26 ,  C07F11/00 ,  C07C2/36 ,  B01J31/18 ,  C07F9/90 ,  C07F9/66 ,  C07F9/02 ,  C07F9/46 ,  C07F9/50 ,  C07F9/70 ,  C08F4/78

Abstract: The present invention relates to a ligand compound, a catalyst system for oligomerization of olefins including the ligand compound and the organic chromium compound, and a method for oligomerizing olefins using the same. The catalyst system for olefin oligomerization according to the present invention invention exhibits high selectivity to 1-hexene or 1-octene while having excellent catalytic activity, thereby enabling more efficient production of alpha-olefins.

公开(公告)号：US10472302B2

公开(公告)日：2019-11-12

申请号：US15302840

申请日：2015-06-18

Applicant: LG CHEM, LTD.

Inventor： Yong Ho Lee ,  Eun Ji Shin ,  Jin Young Park ,  Seok Pil Sa ,  Ki Soo Lee

IPC: C07C2/00 ,  C07C2/32 ,  C07F9/02 ,  C08F4/22 ,  C08F10/00 ,  B01J31/14 ,  B01J31/24 ,  C07F9/46 ,  C07F11/00

Abstract: The present invention relates to a ligand compound, a catalyst system for oligomerization of olefins, and a method for oligomerization of olefins using the catalyst system. The catalyst system for oligomerization of olefins according to the present invention not only has excellent catalytic activity, but also exhibits high selectivity to 1-hexene or 1-octene, thus enabling more efficient preparation of alpha-olefin.

公开(公告)号：US10427991B2

公开(公告)日：2019-10-01

申请号：US15570133

申请日：2016-01-11

Applicant: LG CHEM, LTD.

Inventor： Yong Ho Lee ,  Eun Ji Shin ,  Jin Young Park ,  Ki Soo Lee ,  Seok Pil Sa ,  Seul Ki Im

IPC: C07C2/36 ,  C08F10/00 ,  C07C2/26 ,  C07C11/02 ,  C08F4/69 ,  C08F10/02 ,  C07C2/32 ,  B01J21/02 ,  B01J31/14 ,  B01J31/18 ,  B01J31/24 ,  B01J31/34 ,  C07C11/04 ,  B01J31/16 ,  B01J21/08

Abstract: The present invention relates to a catalyst system for olefin oligomerization and a method for olefin oligomerization, and more specifically, a catalyst system for olefin oligomerization and a method for olefin oligomerization that have more improved supporting efficiency due to a ligand compound capable of functioning as a tether to a support, and thus, exhibit high activity in the olefin oligomerization even with smaller amounts of catalyst composition and cocatalyst, thus enabling more efficient preparation of alpha-olefins.