公开(公告)号：US20200002509A1

公开(公告)日：2020-01-02

申请号：US16570450

申请日：2019-09-13

Applicant: International Business Machines Corporation

Inventor： Scott B. King ,  Brandon M. Kobilka ,  Joseph Kuczynski ,  Jason T. Wertz

IPC: C08K5/5337 ,  C07F9/30 ,  C07F9/655 ,  C08K5/5373 ,  C08K5/529 ,  C08K5/5313 ,  C09J11/06 ,  H05K1/03 ,  C07F9/40

Abstract: A flame retardant sugar-derived molecule, a process for forming a flame retardant sugar-derived molecule, and an article of manufacture comprising a flame retardant sugar-derived molecule are disclosed. The flame retardant sugar-derived molecule can be synthesized from arabitol, xylitol, arabic acid, or xylonic acid obtained from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety. The process for forming the flame retardant sugar-derived molecule can include reacting arabitol, xylitol, arabic acid, or xylonic acid and a flame retardant phosphorus-based molecule to form the flame retardant sugar-derived molecule.

公开(公告)号：US20190336425A1

公开(公告)日：2019-11-07

申请号：US16513235

申请日：2019-07-16

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION

Inventor： Scott B. King ,  Brandon M. Kobilka ,  Joseph Kuczynski ,  Jacob T. Porter ,  Jason T. Wertz

IPC: A61K8/40 ,  A61K8/19 ,  A61Q17/04 ,  A61K8/02 ,  A61K8/35 ,  A61K8/37 ,  A61K8/27 ,  A61K8/26 ,  A61K8/29

Abstract: A method for forming a photosensitizer product that is resistant to absorption by living tissue that may include binding a photosensitizer compound with an oxide-containing particle to provide the photosensitizer derivative having a microscale size, and mixing the photosensitizer derivative into a lotion. The microscale size of the photosensitizer derivative obstructs absorption by cell tissue.

公开(公告)号：US10470290B2

公开(公告)日：2019-11-05

申请号：US15589153

申请日：2017-05-08

Applicant: International Business Machines Corporation

Inventor： Bruce J. Chamberlin ,  Scott B. King ,  Joseph Kuczynski ,  David J. Russell

IPC: H05K3/30 ,  H05K7/20 ,  H01L23/00 ,  C09K5/00 ,  C09K5/06 ,  H05K1/02 ,  H05K1/18 ,  H05K3/34

Abstract: An apparatus is configured with a component having a coating comprising a material in a first phase (e.g., solid and/or liquid phase) with a transition temperature. The component is mechanically and/or electrically attached to a substrate. Exposure of the coating to a temperature that meets or exceeds the transition temperature causes the material to undergo a phase change. The phase change of the material alters the position of the component, including separation of the component from the substrate. The separation disrupts the attachment, thereby mitigating damage to the substrate and/or component.

公开(公告)号：US10377799B2

公开(公告)日：2019-08-13

申请号：US15404784

申请日：2017-01-12

Applicant: International Business Machines Corporation

Inventor： Scott B. King ,  Brandon M. Kobilka ,  Joseph Kuczynski ,  Jason T. Wertz

IPC: C07K14/415 ,  C09K21/14 ,  C08L101/00

Abstract: A process of forming a gluten-derived flame retardant material includes forming an amine-functionalized flame retardant molecule that includes an aryl halide group and a phosphorus moiety. The process also includes chemically reacting the amine-functionalized flame retardant molecule with a gluten protein under transamidation conditions to bind the phosphorus moiety to a first portion of the gluten protein. The process further includes initiating a cross-coupling reaction between the aryl halide group and amine group of a second portion of the gluten protein to form a gluten-derived flame retardant material.

公开(公告)号：US10329488B2

公开(公告)日：2019-06-25

申请号：US15726248

申请日：2017-10-05

Applicant: International Business Machines Corporation

Inventor： Scott B. King ,  Brandon M. Kobilka ,  Joseph Kuczynski ,  Jason T. Wertz

IPC: C09K21/10 ,  C08K3/016 ,  C07D207/04 ,  C08K3/32 ,  C08G79/04 ,  C07C211/12 ,  C09K21/04

Abstract: A flame retardant lysine-based derivative, a process for forming a flame retardant lysine-based derivative, and an article of manufacture comprising a flame retardant lysine-based derivative are disclosed. The flame retardant lysine-derived molecule can be synthesized from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety. A flame retardant proline-based derivative, a process for forming a flame retardant proline-based derivative, and an article of manufacture comprising a flame retardant proline-based derivative are also disclosed. The flame retardant proline-derived molecule can be synthesized from a bio-based source and can have at least one phosphoryl or phosphonyl moiety.

公开(公告)号：US10125206B1

公开(公告)日：2018-11-13

申请号：US15673500

申请日：2017-08-10

Applicant: International Business Machines Corporation

Inventor： Scott B. King ,  Brandon M. Kobilka ,  Joseph Kuczynski ,  Jason T. Wertz

IPC: C08F230/02 ,  C09K21/14

Abstract: A process of forming a non-halogenated flame retardant hindered amine light stabilizer (HALS) impact modifier is disclosed. The process includes forming a mixture of monomers that includes an acryloyl-functionalized 2,2,6,6-tetramethylpiperidine (TMP) monomer, a styrene monomer, a butadiene monomer, and a phosphorus-functionalized monomer. The process also includes initiating a polymerization reaction of the mixture of monomers to form a non-halogenated flame retardant HALS impact modifier.

公开(公告)号：US20180324946A1

公开(公告)日：2018-11-08

申请号：US15805995

申请日：2017-11-07

Applicant: International Business Machines Corporation

Inventor： Bruce J. Chamberlin ,  Scott B. King ,  Joseph Kuczynski ,  David J. Russell

IPC: H05K1/02 ,  H05K3/28 ,  H05K1/18

CPC classification number: H05K1/0293 ,  H05K1/0201 ,  H05K1/181 ,  H05K3/28 ,  H05K2203/176

Abstract: A component having a coating comprising a material in a first phase (e.g., solid and/or liquid phase) with a transition temperature. The component is mechanically and/or electrically attached to a substrate. Exposure of the coating to a temperature that meets or exceeds the transition temperature causes the material to undergo a phase change. The phase change of the material alters the position of the component, including separation of the component from the substrate. The separation disrupts the attachment, thereby mitigating damage to the substrate and/or component.

公开(公告)号：US20180324944A1

公开(公告)日：2018-11-08

申请号：US15589153

申请日：2017-05-08

Applicant: International Business Machines Corporation

Inventor： Bruce J. Chamberlin ,  Scott B. King ,  Joseph Kuczynski ,  David J. Russell

IPC: H05K1/02 ,  H05K3/28 ,  H05K1/18

CPC classification number: H05K1/0201 ,  H05K1/181 ,  H05K3/3431 ,  H05K2201/10575 ,  H05K2203/175 ,  H05K2203/176

Abstract: An apparatus is configured with a component having a coating comprising a material in a first phase (e.g., solid and/or liquid phase) with a transition temperature. The component is mechanically and/or electrically attached to a substrate. Exposure of the coating to a temperature that meets or exceeds the transition temperature causes the material to undergo a phase change. The phase change of the material alters the position of the component, including separation of the component from the substrate. The separation disrupts the attachment, thereby mitigating damage to the substrate and/or component.

公开(公告)号：US20180114911A1

公开(公告)日：2018-04-26

申请号：US15857763

申请日：2017-12-29

Applicant: International Business Machines Corporation

Inventor： Scott B. King ,  Brandon M. Kobilka ,  Joseph Kuczynski ,  Jason T. Wertz

IPC: H01L51/00 ,  C07D495/14 ,  C08G61/12 ,  C07D307/68 ,  H01L51/05 ,  H01L51/42

CPC classification number: H01L51/0036 ,  C07D307/68 ,  C07D495/14 ,  C08G61/122 ,  C08G61/125 ,  C08G61/126 ,  C08G2261/228 ,  C08G2261/3222 ,  C08G2261/3241 ,  C08G2261/3242 ,  C08G2261/3243 ,  C08G2261/3246 ,  C08G2261/3247 ,  C08G2261/334 ,  C08G2261/411 ,  C08G2261/414 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/94 ,  H01L51/0043 ,  H01L51/0071 ,  H01L51/0558 ,  H01L51/42 ,  H01L51/4253

Abstract: An organic semiconducting donor-acceptor (D-A) small molecule, as well as a semiconductor device that can incorporate the D-A small molecule, are disclosed. The D-A small molecule can have electron deficient substituents and R group substituents that can be C1-C20 linear alkyl chains, C2-C24 branched alkyl chains, hydrogen atoms, etc. The D-A small molecule can be can be synthesized in a reaction between a dithienofuran (DTF) core monomer and an electron deficient monomer. Additionally, the D-A small molecule can be part of an organic semiconducting copolymer. A semiconductor device that can incorporate the D-A small molecule in a photoactive layer is also disclosed herein. Additionally, 3,4-dibrominated furan compound that can, in some embodiments, be a precursor for the D-A small molecule is disclosed. The 3,4-dibrominated furan compound can be synthesized in a reaction involving a furan-2,5-dicarboxylic dimethyl ester (FDME), which can have a bio-renewable precursor.

公开(公告)号：US09657130B1

公开(公告)日：2017-05-23

申请号：US14965263

申请日：2015-12-10

Applicant: International Business Machines Corporation

Inventor： Scott B. King ,  Brandon M. Kobilka ,  Joseph Kuczynski ,  Jason T. Wertz

IPC: C08G18/32 ,  C08G18/72 ,  C08G101/00 ,  C07C29/147 ,  G10K11/162

CPC classification number: C08G18/3206 ,  C07C29/14 ,  C07C29/143 ,  C07C29/147 ,  C07C29/56 ,  C07C29/58 ,  C07C29/62 ,  C07C45/26 ,  C08G18/72 ,  C08G2101/00 ,  C08G2350/00 ,  G10K11/162 ,  C07C33/025 ,  C07C33/02 ,  C07C31/36 ,  C07C33/042 ,  C07C33/04 ,  C07C47/19 ,  C07C49/185 ,  C07C31/20 ,  C07C31/22 ,  C07C31/24

Abstract: A process of forming a polyurethane material includes forming an unsaturated alcohol from an unsaturated plant oil via a reduction reaction. The process includes forming an alkyne-terminated alcohol from the unsaturated alcohol and forming a polyol having two primary hydroxyl groups from the alkyne-terminated alcohol. The process further includes polymerizing a mixture that includes the polyol having the two primary hydroxyl groups to form a polyurethane material.