Abstract:
A liquid filter article, including: a housing having an inlet, an outlet, and an adsorbent bed there between, the bed comprising: a first stage having a first adsorbent, the first adsorbent including an activated carbon honeycomb infused with a plurality of zero valent iron nanoparticles (“Fe-AC”); and a second stage having a second adsorbent, the second adsorbent being selected from iron oxide particles supported on activated carbon honeycomb (“FEOX-AC”), iron oxide particles supported on activated alumina honeycomb (“FeOX-AA”), or a combination thereof, wherein the first stage is in fluid communication with the second stage. Also disclosed is a method of using the liquid filter article to remediate heavy metals in water.
Abstract:
Methods of making a porous cordierite ceramic honeycomb article are provided. In example methods, a batch composition includes a quantity of non-crosslinked pore former provided as a superaddition of about 20% or less of a dry weight of a quantity of inorganic components. Batch compositions are also provided that include a quantity of clay and other substantially nonfibrous inorganic components sufficient to yield an article including cordierite. Example batch compositions can include clay having a median particle size of about 7 μm or less and/or provided in an amount that is 10% or less of the dry weight of the quantity of inorganic components.
Abstract:
The disclosure relates to methods for making carbon-supported transition metal-based nanoparticles, comprising (a) mixing at least one carbon feedstock, at least one transition metal-containing feedstock, at least one organic binder, and at least one resin binder to form a feedstock mixture, (b) extruding the feedstock mixture, and (c) heating the extruded feedstock mixture at a temperature and for a time sufficient to carbothermally reduce the transition metal-containing feedstock. Also disclosed herein are carbon-supported transition metal-based nanoparticles produced by such methods. Further disclosed herein are methods for treating water and waste streams comprising contacting the water or waste streams with the carbon-supported transition metal-based nanoparticles.
Abstract:
A method for providing a catalyst on a substrate is disclosed comprising providing a first washcoat comprising a soluble washcoat salt species, a polar organic solvent, and an insoluble particulate material, contacting the first washcoat with a substrate to form a coated substrate, and then contacting the coated substrate with a second washcoat comprising an oxide or an oxide-supported catalyst to physisorb, chemisorb, bond, or otherwise adhere the oxide or the oxide-supported catalyst to the coated substrate. Also disclosed is a catalyst on a substrate comprising: a substrate; an anchor layer comprising a soluble washcoat salt species, a polar organic solvent, and an insoluble particulate material; and a second layer comprising an oxide. The catalyst on a substrate can be in either green or fired form.
Abstract:
An absorbent structure for CO2 capture includes a honeycomb substrate having a plurality of partition walls extending in an axial direction from an inlet end to an outlet end thereby forming a plurality of flow channels. The honeycomb substrate comprises a powder component and a binder that are solidified. The absorbent structure also includes a functional mer group dispersed throughout the powder component of the partition walls of the honeycomb substrate. The functional mer group is positioned in and on the partition walls such that, when a gas stream containing CO2 flows in the flow channels from the inlet end to the outlet end, the functional mer group absorbs the CO2 by forming a coordinated bond that forms carbonate, bicarbonate, carbamates, or another coordinated or ionic compound with the CO2.
Abstract:
Described herein is a substrate including a central longitudinal axis, a first support web, and a second support web. A sinuous web may be positioned between the first support web and the second support web. The sinuous web may include transverse web portions and bridging web portions, where the bridging web portions alternatively connect ends of adjacent transverse web portions. The sinuous web may be connected to the first support web by support legs extending between bridging web portions and a surface of the first support web. The sinuous web may be connected to the second support web by support legs extending between bridging web portions and a surface of the second support web. A support leg length to distance between transverse web portions ratio may be from about 1.0 to about 4.0.
Abstract:
A method of making a filter article having a honeycomb substrate having adsorbent filled channels, including: sealing the first end of a porous, cellular honeycomb substrate; filling the channels of the cellular honeycomb substrate with a dry adsorbent source material; sealing the second end of the filled honeycomb to form a sealed honeycomb; contacting the sealed honeycomb and water for a time sufficient to convert the dry precursor material in-situ to a paste; removing the seals from the first and second ends; and heating the contacted honeycomb to convert the paste to an adsorbent. Also disclosed is a filter article having a honeycomb substrate having adsorbent filled channels and methods of using the article.
Abstract:
A liquid filter article, including: a housing having an inlet, an outlet, and an adsorbent bed there between, the bed comprising: a first stage having a first adsorbent, the first adsorbent including an activated carbon honeycomb infused with a plurality of zero valent iron nanoparticles (“Fe-AC”); and a second stage having a second adsorbent, the second adsorbent being selected from iron oxide particles supported on activated carbon honeycomb (“FEOX-AC”), iron oxide particles supported on activated alumina honeycomb (“FeOX-AA”), or a combination thereof, wherein the first stage is in fluid communication with the second stage. Also disclosed is a method of using the liquid filter article to remediate heavy metals in water.
Abstract:
Methods for making activated carbon-supported transition metal-based nanoparticles include (a) impregnated activated carbon with at least one transition metal-containing compound, and (b) heating the impregnated activated carbon at a temperature and for a time sufficient to carbothermally reduce the transition metal-containing compound. Also disclosed are activated carbon-supported transition metal-based nanoparticles produced by such methods. Further disclosed are methods for treating water and waste streams that include contacting the water or waste streams with the activated carbon-supported transition metal-based nanoparticles.
Abstract:
Described herein is a substrate including a central longitudinal axis, a first support web, and a second support web. A sinuous web may be positioned between the first support web and the second support web. The sinuous web may include transverse web portions and bridging web portions, where the bridging web portions alternatively connect ends of adjacent transverse web portions. The sinuous web may be connected to the first support web by support legs extending between bridging web portions and a surface of the first support web. The sinuous web may be connected to the second support web by support legs extending between bridging web portions and a surface of the second support web. A support leg length to distance between transverse web portions ratio may be from about 1.0 to about 4.0.