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公开(公告)号：US12030831B2
公开(公告)日：2024-07-09
申请号：US16765620
申请日：2018-12-20
申请人： BASF SE
CPC分类号： C07C2/58 , B01J29/7007 , C07C2529/70
摘要： Disclosed is a process for the alkylation of an aliphatic organic compound comprising: (a) providing a catalyst comprising one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and optionally comprises X2O3, wherein Y is a tetravalent element, and X is a trivalent element, (b) contacting the catalyst with one or more aliphatic organic compounds in the presence of one or more alkylating agents in one or more reactors for obtaining one or more alkylated organic compounds, wherein the one or more zeolitic materials are obtainable from a synthetic process which does not employ an organotemplate as structure directing agent.
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公开(公告)号：US20220111372A1
公开(公告)日：2022-04-14
申请号：US17500164
申请日：2021-10-13
申请人： PHILLIPS 66 COMPANY
摘要： A solid metal organic framework composition comprising a solid metal organic framework supported heteropolyacid wherein the heteropolyacid loading is greater than 25% by weight; and the pore volume is less than 2.0 mL/g.
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公开(公告)号：US20220111371A1
公开(公告)日：2022-04-14
申请号：US17500120
申请日：2021-10-13
申请人： PHILLIPS 66 COMPANY
IPC分类号： B01J31/16 , B01J27/188 , B01J37/02 , B01J35/10 , C07C2/58
摘要： A process comprising a heterogenous reaction between a solid metal organic framework supported heteropolyacid catalyst and a hydrocarbon feed to form a modified hydrocarbon stream. The modified hydrocarbon stream comprises essentially of C6+ hydrocarbons.
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公开(公告)号：US10894751B2
公开(公告)日：2021-01-19
申请号：US16514247
申请日：2019-07-17
发明人： Greg Nyce , Peter Czerpak , Carlos Faz , Jarod McCormick , William Michalak , Bipinkumar Patel , Guido Radaelli , Tim A. Rappold , Ron Runnebaum , Erik C. Scher , Aihua Zhang , Joel Cizeron
IPC分类号： C07C1/04 , C07C1/06 , C07C1/12 , C07C2/12 , C07C2/58 , C07C2/84 , C07C5/05 , C07C5/09 , C07C5/327 , B01J19/00 , B01J19/24 , B01J29/40 , C10G3/00 , C10G9/00 , C10G11/00 , C10G50/00 , C10G57/02 , F25J3/02 , C07C4/02 , C10L3/10
摘要： Integrated systems are provided for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compositions, from methane using an oxidative coupling of methane system to convert methane to ethylene, followed by conversion of ethylene to selectable higher hydrocarbon products. Integrated systems and processes are provided that process methane through to these higher hydrocarbon products.
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公开(公告)号：US10464864B2
公开(公告)日：2019-11-05
申请号：US15834209
申请日：2017-12-07
发明人： Guang Cao , Jihad Dakka
摘要： In a process for upgrading an ethane-containing C5- paraffin stream, the paraffin stream is contacted with an oxygen containing gas in the presence of a selective oxidation catalyst under conditions to selectively oxidize at least part of the ethane in the paraffin stream and produce a first product stream comprising ethylene. At least part of the first product stream is then with an oligomerization catalyst under conditions to oligomerize at least part of the ethylene and produce a second product stream comprising gasoline and/or distillate boiling range hydrocarbons. Gasoline and/or distillate boiling range hydrocarbons are then recovered from the second product stream and at least a part of any residual C5- paraffin stream is recycled to the selective oxidation step.
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公开(公告)号：US10464863B2
公开(公告)日：2019-11-05
申请号：US15190063
申请日：2016-06-22
申请人： Exelus, Inc.
IPC分类号： B01J29/06 , C07C2/58 , B01J29/08 , B01J29/70 , B01J37/30 , B01J37/02 , C01B39/20 , C01B39/02 , C01B39/46 , C10G29/20 , B01J29/12 , B01J29/14 , B01J37/08 , B01J38/10 , B01J29/74 , B01J29/90
摘要： Improved alkylation catalysts, alkylation methods, and methods of making alkylation catalysts are described. The alkylation method comprises reaction over a solid acid, zeolite-based catalyst and can be conducted for relatively long periods at steady state conditions. The alkylation catalyst comprises a crystalline zeolite structure, a Si/Al molar ratio of 20 or less, less than 0.5 weight percent alkali metals, and further having a characteristic catalyst life property. Some catalysts may contain rare earth elements in the range of 10 to 35 wt %. One method of making a catalyst includes a calcination step following exchange of the rare earth element(s) conducted at a temperature of at least 575° C. to stabilize the resulting structure followed by an deammoniation treatment. An improved method of deammoniation uses low temperature oxidation.
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公开(公告)号：US10450264B2
公开(公告)日：2019-10-22
申请号：US15866393
申请日：2018-01-09
申请人： UOP LLC
IPC分类号： C07C233/89 , C07C231/12 , C07C2/58
摘要： Non-cyclic amide or thioamide based ionic liquids and methods of making them are disclosed. The non-cyclic amide or thioamide based ionic liquid comprises a cation and an anion and has the formula:
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公开(公告)号：US20180282241A1
公开(公告)日：2018-10-04
申请号：US16002206
申请日：2018-06-07
发明人： Vinit Choudhary , Jihad Dakka , Matthew S. Mettler , Ivy D. Johnson , Joshua W. Allen , Ajit B. Dandekar , Cynthia F. Omilian
IPC分类号： C07C2/58 , B01J29/70 , C10L10/10 , B01J37/00 , C07C2/62 , C10L1/16 , B01J37/06 , B01J37/08 , C07C9/16 , C07C9/21
摘要： In a process for the catalytic alkylation of an olefin with an isoparaffin, an olefin-containing feed is contacted with an isoparaffin-containing feed under alkylation conditions in the presence of a solid acid catalyst comprising a crystalline microporous material of the MWW framework types, wherein the olefin-containing feed consists essentially of pentenes.
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公开(公告)号：US20180170838A1
公开(公告)日：2018-06-21
申请号：US15834183
申请日：2017-12-07
发明人： Guang CAO , Jihad M. DAKKA
CPC分类号： C07C5/48 , C07C2/12 , C07C2/24 , C07C2/58 , C07C2523/28 , C07C2523/30 , C07C2523/72 , C07C2523/755 , C07C2529/068 , C07C2529/072 , C07C2529/40 , C07C2529/48 , C10G50/00 , C10G2400/02 , Y02P20/52 , C07C11/04 , C07C11/02
摘要： A process for upgrading an ethane-containing C5− paraffin stream comprises contacting the paraffin stream with an oxygen containing gas in the presence of a selective oxidation catalyst under conditions to selectively oxidize at least part of the ethane in the paraffin stream and produce a first product stream comprising ethylene. At least part of the first product stream may then be contacted with an isoparaffin-containing feed in the presence of a solid alkylation catalyst and under conditions to alkylate at least part of the isoparaffin with at least part of the ethylene and produce a second product stream comprising C6+ alkylate. Alternatively, at least part of the ethylene in the first product stream may be dimerized before the alkylation step.
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10.发明授权公开(公告)号：US09956553B2
公开(公告)日：2018-05-01
申请号：US15194979
申请日：2016-06-28
申请人： Chevron U.S.A. Inc.
IPC分类号： B01J21/04 , B01J23/38 , B01J23/42 , B01J23/44 , B01J35/10 , B01J31/02 , B01J31/40 , B01J38/48 , C07C2/58 , B01D15/18
CPC分类号： B01J31/40 , B01D15/1871 , B01J23/44 , B01J31/0284 , B01J38/48 , B01J2231/32 , C07C2/58 , C07C2527/125 , C07C2531/02 , C07C9/16
摘要： The present disclosure provides a macroporous noble metal catalyst and processes employing such catalysts for the regeneration of deactivated ionic liquid catalyst containing conjunct polymer.
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