摘要:
Aqueous-based thermally developable emulsions and photothermographic imaging materials include photosensitive silver halide core-shell grains that comprise at least 20 mol % iodide based on total silver, an amount of iodide in the core of the grains that can be up to the iodide saturation limit in silver iodobromide, and an amount of iodide in the shell of the grains that is at least 2 mol % less than the amount of iodide present in the core, and further provided that the total amount of silver in the shell is from about 10 to about 80 mol % of total silver in the grains. These materials provide desired Dmax and reduced image nullprint outnull.
摘要:
This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: 1 In the above Structure I, the substituents are as defined in the application. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
摘要:
A silver halide color photographic light-sensitive material containing at least one kind of a compound represented by formula (I): 1 Where each of R1, R3 and R4 independently represents a hydrogen atom or a substituent, R2 represents a substituent, a represents an integer of 0 to 4, wherein if a is not less than 2, a plurality of R2's may be the same or different, and if a is 1, R2 is selected from substituents having a up value of 0 to 0.53, and if a is 2 to 4, R2 is selected from substituents having a nullp value of 0 to 0.53 in total, Time represents a group which releases nullSnullR5 after being eliminated as (Time)t-SnullR5, t is 0 or 1, and R5 represents an organic group which is bonded with S by its sp3 carbon.
摘要:
A color photographic silver halide material having a support and at least one photosensitive silver halide emulsion layer which is associated with a cyan coupler of the formula (I): 1 in which R1, R2, R3, Z1, Y1 and n have the meaning stated in the description, is distinguished by elevated dye stability of the dye produced from the coupler by chromogenic processing.
摘要:
A photographic element is described comprising a support bearing one or more hydrophilic colloid layers including at least one photographic silver halide emulsion layer, wherein a photographically useful compound is incorporated into at least one hydrophilic colloid layer in the form of an intercalation composition comprising a layered host material having molecules of the photographically useful compound inserted as guest molecules between the layers of the host material. The invention provide novels materials and a method of incorporating active chemistry compounds such as developers or development inhibitors directly into a photographic imaging element with improved stability and keeping response versus known methods for incorporating active chemistry compounds.
摘要:
Aqueous-based thermally sensitive emulsions and photothermographic imaging materials include photosensitive silver halide grains that are predominantly homogeneous and comprise at least 20 mol % iodide based on total silver in the grains. These materials provide desired Dmax and reduced image nullprint outnull.
摘要:
An image forming assembly and method utilizes a laminate processing sheet. The laminate processing sheet is applied on an emulsion side of an exposed photosensitive film which includes sprocket holes along opposing edges. In a first feature of the present invention, a width of the laminate processing sheet is confined to an image area between the opposing sprocket holes, so as to reduce or eliminate the possibility of processing marks in or around an area of the opposing sprocket holes. In a further feature of the present invention, an absorbing sheet can be applied to the backside of the photosensitive film, to absorb any excess processing or wetting solution that is applied to the photosensitive film. This also aids in reducing or eliminating unwanted processing marks at the sprocket holes or an area in the vicinity of the sprocket holes.
摘要:
A photographic developer composition for use in the development of a black and white silver halide photographic element said composition comprises at least one developing agent and, in an amount sufficient to inhibit sludge deposition, one or more compounds selected from compounds having the formula XnullR1nullCONHnullAnullSnullSnullBnullNHCOnullR2nullY (I) wherein A and B are each independently a substituted or unsubstituted aliphatic, alicyclic, aromatic or heterocyclic group; R1 and R2 are each independently a substituted or unsubstituted aliphatic, alicyclic, aromatic or heterocyclic group; X and Y are each independently a solubilising group; and compounds having the formula XnullR1nullCONHnullAnullSnullM (II) wherein A, R1 and X are as defined above, and M is either a hydrogen atom or a cationic species if the sulfur atom is in its ionized form.
摘要:
A radiation sensitive imaging element is described comprising a support bearing one or more hydrophilic colloid layers, wherein a photographically useful compound is incorporated into at least one hydrophilic colloid layer in the form of a self-assembled composition comprising a substantially homogeneous and ordered array of the photographically useful compound and silver and halide atoms, wherein the average minimum distance from each Ag atom in the composition to an atom of the photographically useful compound in the composition is less than 50 null. In a particular embodiment, the self-assembled composition is of the general unit cell formulaAgaXb(PUC*)c.nH2Owhere X represents halogen atoms selected from Cl, Br, and I or any combination thereof, and PUC* is a photographically useful compound containing at least one positively charged onium ion group; and wherein a is an integer from 1-10 and b is an integer from 2-18, with the proviso b is greater than a, and the silver and halide atoms form silver halide sublattice structures having a net negative charge; c is an integer such that the onium ion group containing photographically useful compound forms a positively-charged sublattice which stabilizes the negatively charged silver halide sublattice, wherein charge neutrality for the composition is upheld; and n is any number from 0 to 10. The invention provides novel materials and a method of incorporating active chemistry compounds such as developers or development inhibitors directly into a photographic imaging element. The invention further provide materials, and a method for preparing materials, comprising silver halide co-crystallized with photographic useful compound molecules thereby creating a unique crystal lattice. The invention described herein provides materials in which active chemistry and silver halide are present together in an ordered array, or crystal lattice, separated by distances measured on the atomic scale (i.e., in angstroms (null), where 1 nullnull10null4 nullm).
摘要:
A method of providing an image in an imagewise exposed photographic silver halide material comprising at least one silver halide emulsion layer, which method comprises developing the silver halide and fixing the remaining silver halide by contacting it with a molten composition comprising a silver halide complexing agent which is present in sufficient amount to render the silver halide substantially clear. The photographic silver halide material may comprise at least one silver halide emulsion layer on a support wherein the material also comprises a layer of a composition comprising a silver halide complexing agent which is liquefiable by heat and which, when molten, is in reactive association with the silver halide. The image formed may be scanned to produce an electronic rendition of the image.