公开(公告)号：US20040229174A1

公开(公告)日：2004-11-18

申请号：US10827627

申请日：2004-04-20

Applicant: FUJI PHOTO FILM CO., LTD.

Inventor： Nobuyuki Haraguchi ,  Masayuki Kuramitsu ,  Naoto Matsuda

IPC: G03C001/46 ,  G03C001/00

CPC classification number: G03C7/3041 ,  G03C7/3029 ,  G03C7/3225 ,  G03C7/36 ,  G03C7/3825 ,  G03C2007/3031 ,  G03C2200/38

Abstract: A silver halide color reversal photosensitive material comprising a blue-sensitive emulsion layer unit containing a yellow color-forming coupler, a green-sensitive emulsion layer unit containing a magenta color-forming coupler and a red-sensitive emulsion layer unit containing a cyan color-forming coupler, on a transparent support, wherein the material includes at least one interimage effect-donating layer substantially forms no image; the wavelength, nullrmax, at which the maximum sensitivity of the spectral sensitivity distribution of the red-sensitive layer unit is given, satisfies the relation: 620 nmnullnullrmaxnull680 nm; and the sensitivities of the red-sensitive layer unit satisfy the following relationships: Sr(610) is null of Sr(nullrmax) or more; Sr(680) is {fraction (1/10)} of Sr(nullrmax) or more; and/or Sr(690) is {fraction (1/50)} of Sr(nullrmax) or more wherein Sr(610), Sr(680) and Sr(690) are the sensitivities of the red-sensitive unit at 610 nm, 680 nm and 690 nm, respectively, and Sr(nullrmax) is the maximum sensitivity at nullrmax.

Abstract translation: 一种卤化银颜色反转感光材料，其包含含有黄色成色剂的感蓝乳剂层单元，含有品红色成色剂的感绿乳剂层单元和含有青色色成色剂的感红乳剂层单元， 在透明支撑件上形成耦合器，其中所述材料包括基本上不形成图像的至少一个中间图像赋予层; 给出红色敏感层单元的光谱灵敏度分布的最大灵敏度的波长，lambdarmax满足关系：620nm <= lambdarmax <= 680nm; 并且红色敏感层单元的灵敏度满足以下关系：Sr（610）为Sr（lambdarmax）以上的1/5; Sr（680）为{部分（Sr（lambdarmax）或更高的1/10）和/或Sr（690）为{部分（Sr（兰德卡莫）的1/50）或更高，其中Sr（610） 和Sr（690）分别是在610nm，680nm和690nm处的红色敏感单元的敏感性，Sr（lambdarmax）是lambdarmax的最大灵敏度。

公开(公告)号：US20040058284A1

公开(公告)日：2004-03-25

申请号：US10375053

申请日：2003-02-28

Applicant: FUJI PHOTO FILM CO., LTD.

Inventor： Hiroyuki Yoneyama ,  Akira Ikeda ,  Shin Soejima ,  Kiyoshi Takeuchi ,  Naoto Matsuda

IPC: G03C001/46

CPC classification number: G03C1/08 ,  G03C1/0051 ,  G03C1/09 ,  G03C1/30 ,  G03C1/46 ,  G03C5/04 ,  G03C5/50 ,  G03C7/3013 ,  G03C7/3022 ,  G03C7/3041 ,  G03C7/3225 ,  G03C7/34 ,  G03C7/346 ,  G03C7/36 ,  G03C7/3825 ,  G03C7/3885 ,  G03C7/39208 ,  G03C7/4136 ,  G03C2001/03517 ,  G03C2001/03535 ,  G03C2001/03541 ,  G03C2001/03594 ,  G03C2001/0476 ,  G03C2001/093 ,  G03C2007/3025 ,  G03C2007/3027 ,  G03C2007/3043 ,  G03C2200/07 ,  G03C2200/27 ,  G03C2200/33

Abstract: A silver halide color photographic light-sensitive material, having at least one each of blue-, green-, and red-sensitive emulsion layers containing yellow, magenta, and cyan couplers, respectively, on a support; wherein said blue-sensitive emulsion layer contains at least one coupler of formula (I); and wherein the light-sensitive material satisfies expression a-1) and/or b-1): 1 wherein, Q forms a 5- to 7-membered ring with the nullNnullCnullN(R1)-; R1 and R2 each are a substituent; m is 0 to 5; and X is a hydrogen atom, or a coupling split-off group; a-1): 0.5nullDmax(UV)/Dmin(UV)null1.1 wherein Dmax(UV)/Dmin(UV) is the smallest of the value in a wavelength range of 340 to 450 nm; b-1): 1300null(BnullC)/Anull20000 wherein B is yellow Dmax, C is yellow Dmin; and A is an amount mol/m2 of the coupler of formula (I).

Abstract translation: 一种卤化银彩色照相感光材料，其分别在载体上具有含有黄色，品红色和青色成色剂的蓝色，绿色和红色感光乳剂层中的至少一种; 其中所述感蓝乳剂层含有至少一种式（I）的成色剂; 并且其中所述感光材料满足表达式a-1）和/或b-1）：其中Q与-N = C-N（R1） - 形成5-至7-元环; R1和R2各自为取代基; m为0〜5; X为氢原子或偶联分离基团; a-1）：0.5 <= Dmax（UV）/ Dmin（UV）<= 1.1其中Dmax（UV）/ Dmin（UV）是340至450nm波长范围内的最小值; b-1）：1300 <=（B-C）/ A <= 20000其中B为黄色Dmax，C为黄色Dmin; 并且A是式（I）的成色剂的mol / m 2的量。

公开(公告)号：US20030203327A1

公开(公告)日：2003-10-30

申请号：US10352035

申请日：2003-01-28

Applicant: FUJI PHOTO FILM CO.,LTD.

Inventor： Yasuhiro Kato ,  Hisashi Mikoshiba ,  Naoto Matsuda

IPC: G03C007/32 ,  C07D249/00

CPC classification number: C07D487/04 ,  G03C7/3212 ,  G03C7/383

Abstract: A silver halide color photosensitive material comprises at least one layer on a support. At least one of the layers contains a coupler represented by general formula (I): 1 wherein X represents H or split-off group; R1 and R2 independently represents an electron withdrawing group whose Hammett nullp value is 0.20 or greater, provided that the sum of R1 and R2 nullp values is 0.65 or greater; R3 represents a group selected from alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, aryl and heterocyclic, each of which may have a substituent; R4 represents H, or a group selected from alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, aryl, acyl, alkoxycarbonyl, aryloxycarbonyl and carbamoyl, each of which may have a substituent, provided that R3 and R4 may be bonded to form a ring; R11, R12 and R13 independently represent an alkyl group having 1-30 carbon atoms; R represents a substituent; and n represents an integer of 0-3.

Abstract translation: 卤化银色感光材料在载体上包含至少一层。 至少一层包含由通式（I）表示的成色剂：其中X表示H或分离基团; R 1和R 2独立地表示其Hammett sigmap值为0.20或更大的吸电子基团，条件是R 1和R 2 sigmap值之和为0.65或更大; R 3表示选自烷基，烯基，炔基，环烷基，环烯基，芳基和杂环的基团，各自可以具有取代基; R 4表示H，或选自烷基，烯基，炔基，环烷基，环烯基，芳基，酰基，烷氧基羰基，芳氧基羰基和氨基甲酰基的基团，其各自可以具有取代基，条件是R 3和R 4 >可以键合形成环; R 11，R 12和R 13独立地表示具有1-30个碳原子的烷基; R表示取代基; n表示0〜3的整数。

公开(公告)号：US20040091825A1

公开(公告)日：2004-05-13

申请号：US10373653

申请日：2003-02-26

Applicant: FUJI PHOTO FILM CO., LTD.

Inventor： Hiroyuki Yoneyama ,  Yasuaki Deguchi ,  Naoto Ohshima ,  Kiyoshi Takeuchi ,  Akira Ikeda ,  Naoto Matsuda

IPC: G03C001/08 ,  G03C007/26 ,  G03C007/32

CPC classification number: G03C7/3013 ,  G03C1/0051 ,  G03C1/09 ,  G03C5/50 ,  G03C7/3022 ,  G03C7/3041 ,  G03C7/3225 ,  G03C7/34 ,  G03C7/346 ,  G03C7/36 ,  G03C7/3825 ,  G03C7/3885 ,  G03C7/39208 ,  G03C2001/03517 ,  G03C2001/03535 ,  G03C2001/03541 ,  G03C2001/093 ,  G03C2007/3025 ,  G03C2007/3043 ,  G03C2200/07 ,  G03C2200/33

Abstract: A silver halide color photographic light-sensitive material comprising at least one yellow color developable light-sensitive silver halide emulsion layer, at least one magenta color developable light-sensitive silver halide emulsion layer, and at least one cyan color developable light-sensitive silver halide emulsion layer, each of which is provided on a support: which comprises at least one yellow coupler of formula (I) and at least one cyan coupler of formula (A); 1 wherein Q represents a group of non-metal atoms that form a 5- to 7-membered ring in combination with nullNnullCnullN(R1)null, each of R1 and R2 represents a substituent, m represents an integer of 0 to 5, and X represents a hydrogen atom or a group capable of being split-off upon a coupling reaction; 2 wherein R11 and R12 each represent an alkyl group or an aryl group, J represents an alkylene group, and X represents a hydrogen atom or a group that can split off upon a coupling reaction.

Abstract translation: 一种卤化银彩色照相感光材料，其包含至少一种黄色可显影感光卤化银乳剂层，至少一种品红色可显影感光卤化银乳剂层和至少一种青色显影性感光卤化银 乳剂层，其各自设置在载体上：其包含至少一种式（I）的黄色偶联剂和至少一种式（A）的青色成色剂; 其中Q表示与-N = CN（R1） - 组合形成5-至7-元环的一组非金属原子，R 1和R 2各自表示取代基，m表示0至5的整数， X表示氢原子或能够在偶联反应时分裂的基团; 其中R11和R12各自表示烷基或芳基，J表示亚烷基，X表示氢原子或可以在偶联反应时分裂的基团。

公开(公告)号：US20030091945A1

公开(公告)日：2003-05-15

申请号：US10134614

申请日：2002-04-30

Applicant: FUJI PHOTO FILM CO., LTD.

Inventor： Yasuhiro Kato ,  Hisashi Mikoshiba ,  Naoto Matsuda

IPC: G03C001/34 ,  G03C007/32

CPC classification number: G03C7/301

Abstract: A silver halide color photographic material comprises a lightsensitive emulsion layer on a support. The material contains a cyan coupler of formula (CC-1) and a compound of formulas (SC-I) to (SC-V): 1 wherein Ga and Gb represent nullC(R13)null or nullNnull; R11 and R12 represents an electron-withdrawing group having nullp of 0.20 to 1.0; and R13 represents a substituent; 2 wherein Q1, Q2 Q3, Q4, Q5 represent a non-metallic atomic group capable of forming a 5- or 6-membered ring; Y represents a carbonyl or sulfonyl group; X represents CnullRx or N, wherein Rx represents a hydrogen atom or substituent; R1 represents an aryl or substituted carbonyl group; R2, R3, R4, R5 and R6 represent a substituent; and L1, L2 and L3 represent a group that does not leave in its reaction with an aromatic primary amine color developer.

Abstract translation: 卤化银彩色照相材料在载体上包含光敏乳剂层。 该材料含有式（CC-1）的青色成色剂和式（SC-I）至（SC-V）的化合物：其中Ga和Gb表示-C（R 13）=或-N = R11和R12表示具有0.20至1.0的sigmap的吸电子基团; R 13表示取代基。 其中Q1，Q2 Q3，Q4，Q5表示能够形成5-或6-元环的非金属原子团; Y表示羰基或磺酰基; X表示C-Rx或N，其中Rx表示氢原子或取代基; R1表示芳基或取代的羰基; R2，R3，R4，R5和R6表示取代基; 并且L1，L2和L3表示不与芳族伯胺显色剂反应的基团。

公开(公告)号：US20020081540A1

公开(公告)日：2002-06-27

申请号：US09897043

申请日：2001-07-03

Applicant: Fuji Photo Film Co., Ltd.

Inventor： Hisashi Mikoshiba ,  Yoshio Shimura ,  Naoto Matsuda

IPC: G03C007/32 ,  G03C005/31 ,  G03C005/50

CPC classification number: G03C7/3835 ,  G03C7/3212

Abstract: A silver halide color photosensitive material comprising each at least one blue-, green-, and red-sensitive emulsion layer on a support. The material contains a magenta coupler of formula (MC-1): 1 wherein R1 represents a t-alkyl group, s, m, and n represent 0 or 1, R2 to R7 represent H, halogen atom, alkyl, or aryl group, L represents nullNR8SO2null, nullSO2NR8null, nullSO2NR8COnull, nullNR8COOnull, nullNR8CONR9null, or nullCOOnull, R8 and R9 represent H, alkyl, or aryl group, J represents nullCOnull, nullCOOnull, nullOnull, nullSnull, nullCONR10null, nullNR10COnull, nullNR10COOnull, nullNR10NR11null, nullSO2null, nullSO2NR10null, or nullCONR10SO2null, R10 and R11 represent H, alkyl, or aryl group, B represents an alkyl group of C1-70 or an aryl group of C6-70 , p represents an integer from 1 to 5, G represents halogen atom, alkyl, aryl, or alkoxy group, and q represents an integer from 0 to 4, provided that 2 is exclused from the magenta coupler.

Abstract translation: 一种卤化银色感光材料，其在载体上包含至少一种蓝，绿和红敏感乳剂层。 该材料含有式（MC-1）的品红成色剂：其中R1表示叔烷基，s，m和n表示0或1，R2至R7表示H，卤素原子，烷基或芳基，L 表示-NR8SO2-，-SO2NR8-，-SO2N8C-，-NR8COO-，-NR8CONR9-或-COO-，R8和R9表示H，烷基或芳基，J表示-CO-，-COO-，-O - ， - S - ， - CONR 10 - ， - NR 10 CO - ， - NR 10 COO - ， - NR 10 NR 11 - ， - SO 2 - ， - SO 2 NR 10 - 或-CONR 10 SO 2 - ，R 10和R 11表示H，烷基或芳基，B表示 C 1-7的烷基或C 6-70的芳基，p表示1〜5的整数，G表示卤素原子，烷基，芳基或烷氧基，q表示0〜4的整数，条件是 从洋红色耦合器中解除。

公开(公告)号：US20040185392A1

公开(公告)日：2004-09-23

申请号：US10701386

申请日：2003-11-05

Applicant: FUJI PHOTO FILM CO., LTD.

Inventor： Makoto Suzuki ,  Takanori Hioki ,  Naoto Matsuda

IPC: G03C001/38

CPC classification number: G03C1/12 ,  G03C1/815 ,  G03C1/8155 ,  G03C5/26

Abstract: A silver halide photographic photosensitive material, containing at least one residual-color-reducing agent having at least one aromatic ring or aromatic heterocycle in its molecule; a processing method thereof; and an image-forming method.

Abstract translation: 一种卤化银照相感光材料，其在其分子中含有至少一种具有至少一个芳族环或芳族杂环的残留色素还原剂; 其处理方法; 和成像方法。

公开(公告)号：US20040122238A1

公开(公告)日：2004-06-24

申请号：US10679466

申请日：2003-10-07

Applicant: Fuji Photo Film Co., Ltd.

Inventor： Kiyoshi Takeuchi ,  Shigeki Uehira ,  Mario Aoki ,  Jun Ogasawara ,  Yasuhiro Shimada ,  Seiji Ichijima ,  Yasuaki Deguchi ,  Naoto Matsuda ,  Akira Ikeda ,  Hisashi Mikoshiba ,  Masaharu Sugai ,  Taiji Katsumata

IPC: C07D249/00 ,  C07D209/02

CPC classification number: C09B55/00 ,  C07D239/90 ,  C07D285/18 ,  C07D285/24 ,  C07D403/06 ,  C07D417/06 ,  C07D417/12 ,  C07D513/04 ,  C09B55/003 ,  G03C7/30535 ,  G03C7/36

Abstract: A dye-forming coupler and compound of formula (I): formula (I) 1 wherein Q is nullC(nullR11)nullC(nullR12)nullSO2null; R11 and R12 bond with each other to form, together with the nullCnullCnull moiety, a 5- to 7-membered ring, or each represent a hydrogen atom or a substituent; R1, R3 and R4 each represent a substituent; m is an integer of 0 to 4; when m is 2 or more, R4s may be the same or different or bond together to form a ring, and X represents a hydrogen atom or a group that splits off upon a coupling reaction with an oxidized product of a developing agent; with the proviso that the following compound (I-A) is excluded from formula (I): 2

Abstract translation: 染料形成成色剂和式（I）化合物：式（I）其中Q是-C（-R 11）= C（-R 12）-SO 2 - ; R 11和R 12彼此键合，与-C = C部分一起形成5-至7-元环，或各自表示氢原子或取代基; R1，R3和R4各自表示取代基; m为0〜4的整数。 当m为2以上时，R 4可以相同也可以不同，也可以结合形成环，X表示氢原子或与显影剂的氧化物进行偶联反应时分裂的基团。 条件是从式（I）中排除下列化合物（I-A）：

公开(公告)号：US20020168595A1

公开(公告)日：2002-11-14

申请号：US10061212

申请日：2002-02-04

Applicant: FUJI PHOTO FILM CO., LTD.

Inventor： Masahiko Taniguchi ,  Naoto Matsuda

IPC: G03C001/43 ,  G03C001/50

CPC classification number: G03C7/30541 ,  G03C5/50 ,  G03C7/30 ,  G03C7/30552

Abstract: A silver halide color photographic light-sensitive material containing at least one kind of a compound represented by formula (I): 1 Where each of R1, R3 and R4 independently represents a hydrogen atom or a substituent, R2 represents a substituent, a represents an integer of 0 to 4, wherein if a is not less than 2, a plurality of R2's may be the same or different, and if a is 1, R2 is selected from substituents having a up value of 0 to 0.53, and if a is 2 to 4, R2 is selected from substituents having a nullp value of 0 to 0.53 in total, Time represents a group which releases nullSnullR5 after being eliminated as (Time)t-SnullR5, t is 0 or 1, and R5 represents an organic group which is bonded with S by its sp3 carbon.

Abstract translation: 含有至少一种式（I）表示的化合物的卤化银彩色照相感光材料：其中，R 1，R 3和R 4各自独立地表示氢原子或取代基，R 2表示取代基，a表示整数 为0〜4，其中如果a不小于2，则多个R 2可以相同或不同，如果a为1，则R2选自上​​述值为0至0.53的取代基，如果a为2 至4，R2选自总共为0至0.53的sigmap值的取代基，Time表示在作为（时间）tS-R5，t为0或1之后将-S-R5消除后释放的基团，t表示0或1，R5表示 通过其sp3碳与S结合的有机基团。