公开(公告)号：US20040096786A1

公开(公告)日：2004-05-20

申请号：US10036669

申请日：2001-12-21

Applicant: Eastman Kodak Company

Inventor： Joseph F. Bringley ,  Krishnamohan Sharma ,  Kenneth J. Lushington

IPC: G03C001/295 ,  G03C001/34 ,  G03C001/38 ,  G03C001/42 ,  G03C001/43

CPC classification number: G03C1/04

Abstract: A photographic element is described comprising a support bearing one or more hydrophilic colloid layers including at least one photographic silver halide emulsion layer, wherein a photographically useful compound is incorporated into at least one hydrophilic colloid layer in the form of an intercalation composition comprising a layered host material having molecules of the photographically useful compound inserted as guest molecules between the layers of the host material. The invention provide novels materials and a method of incorporating active chemistry compounds such as developers or development inhibitors directly into a photographic imaging element with improved stability and keeping response versus known methods for incorporating active chemistry compounds.

Abstract translation: 描述了一种照相元件，其包含一个支承有一个或多个亲水胶体层的载体，该亲水胶体层包括至少一个照相卤化银乳剂层，其中将照相有用的化合物并入包含分层宿主的嵌入组合物形式的至少一个亲水胶体层 具有在宿主材料层之间作为客体分子插入的照相有用化合物的分子的材料。 本发明提供新颖材料和将活性化学化合物如显影剂或显影抑制剂直接掺入照相成像元件中的方法，其具有改进的稳定性并且与已知的掺入活性化学化合物的方法保持响应。

公开(公告)号：US20040067455A1

公开(公告)日：2004-04-08

申请号：US10244270

申请日：2002-09-16

Applicant: Eastman Kodak Company

Inventor： John E. Keevert ,  Stephen P. Singer ,  Kenneth J. Reed ,  Kenneth J. Lushington ,  Mary C. Brick ,  James A. Friday

IPC: G03C001/035 ,  G03C001/295 ,  G03C007/34 ,  G03C007/32

CPC classification number: G03C7/30594 ,  G03C1/0051 ,  G03C1/04 ,  G03C7/3022 ,  G03C7/3029 ,  G03C7/30541 ,  G03C2007/3034 ,  Y10S430/156

Abstract: This invention relates to a photographic element comprising a support and at least two silver halide emulsion layers further comprising an electron transfer agent releasing compound represented by the formula (I): CAR1-(L)n-ETAnullnull(I) wherein: CAR1 is a carrier moiety which is capable of releasing -(L)n-ETA on reaction with oxidized developing agent; L is a divalent linking group, n is 0, 1 or 2; and ETA is a releasable 1-aryl-3-pyrazolidinone electron transfer agent having a calculated log partition coefficient (c log P) greater than or equal to 2.40 and the total sum of the Hammett sigma(para) values of the substituents on the 1-aryl ring is 0.51 or less, the ETA being bonded to L or CAR1 through either the nitrogen atom in the 2-position or the oxygen attached to the 3-position of the pyrazolidinone ring; and a development accelerator releasing compound represented by the formula (II): CAR2-(SAM)-NX1nullNX2X3nullnull(II) wherein: CAR2 is a carrier moiety which is capable of releasing -(SAM)-NX1nullNX2X3 on reaction with oxidized developing agent; SAM is a silver absorbable moiety attached to the carrier moiety and is released on reaction with oxidized development agent; and nullNX1nullNX2X3 is a hydrazine group wherein X1, X2 and X3 are individually hydrogen or a substituent chosen from alkyl, aryl, carbonyl or sulfonyl groups with the proviso that at least one of X1, X2 and X3 is hydrogen.

Abstract translation: 本发明涉及一种照相元件，其包括载体和至少两个卤化银乳剂层，其还包含由式（I）表示的电子转移剂释放化合物：CAR 1 - （L）n -ETA（I）其中： CAR 1是能够与氧化显影剂反应释放 - （L）n-ETA的载体部分。 L是二价连接基团，n是0,1或2; 并且ETA是具有大于或等于2.40的计算对数分配系数（c log P）的可释放的1-芳基-3-吡唑烷酮电子转移剂，并且1位上的取代基的哈米特σ（对）值的总和） 芳基环为0.51以下，ETA通过2-位的氮原子或与吡唑烷酮环的3-位相连的氧键与L或CAR 1键合; 和式（II）表示的显影促进剂释放化合物：CAR 2 - （SAM）-NX 1 -X 2 X 3（II）其中：CAR 2是载体部分，其中 能够与氧化显影剂反应释放 - （SAM）-NX 1 -XX 2 X 3; SAM是与载体部分连接的银可吸收部分，与氧化显影剂反应释放; 和-NX 1 -XX 2 X 3是肼基团，其中X 1，X 2和X 3独立地是氢或选自烷基，芳基，羰基或磺酰基的取代基 条件是X 1，X 2和X 3中的至少一个是氢。