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公开(公告)号：US4596838A
公开(公告)日：1986-06-24
申请号：US739251
申请日：1985-05-30
Applicant: Gregory Andreichuk
Inventor： Gregory Andreichuk
Abstract: A process for sealing geological formations and mine stoppings by applying to these substrates an aqueous, non-cementitious caulk composition comprising an alkali metal silicate; filler material including at least one silica product or silicate other than an alkali metal silicate; a water-soluble or water-dispersible acrylic polymer modifier; and water, and allowing the caulk composition to dry to form an air flow resistant seal on the substrates. A highly satisfactory polymeric modifier is used in the form of a polymer emulsion, such as an emulsion of a self-plasticizing acrylic polymer having a low Tg.
Abstract translation: 一种通过向这些基底施加包含碱金属硅酸盐的水性非水泥质填缝料组合物来密封地质构造和矿山停止的方法; 包括至少一种二氧化硅产物或不同于碱金属硅酸盐的硅酸盐的填料; 水溶性或水分散性丙烯酸类聚合物改性剂; 和水，并且允许填缝料组合物干燥以在基材上形成防气流密封。 高度令人满意的聚合物改性剂以聚合物乳液的形式使用，例如具有低Tg的自增塑丙烯酸聚合物的乳液。
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2.发明授权
公开(公告)号：US4307980A
公开(公告)日：1981-12-29
申请号：US127019
申请日：1980-03-04
Applicant: Frank Meyer , Hans Mehesch , Rolf Kubens , Martin Winkelmann
Inventor： Frank Meyer , Hans Mehesch , Rolf Kubens , Martin Winkelmann
IPC: C09K17/00 , C08G18/30 , C08G18/38 , C09K8/508 , C09K17/46 , C09K17/48 , E02D3/12 , E21D1/10 , E21D9/00 , C08G18/76 , E02B3/12 , E21B33/138
CPC classification number: E21D9/002 , C08G18/302 , C08G18/3895 , C09K17/46 , C09K8/5086 , E21D1/10
Abstract: Waterglass solutions are mixed with polyisocyanates and these emulsions are then left to harden in the formations. Introduction of the mixture into the formations which are required to be consolidated, e.g. deposits of coal, is mainly carried out by forcing the mixture under pressure into bore-holes in the formations. According to one variation of the process, the components of the mixture are introduced into the multi-chamber cartridges which are introduced into the bore-holes and then destroyed as the components are mixed. Certain additives such as accelerators, blowing agents, polyols, stabilizers and/or thixotropic agents are advantageous for the quality of the composite masses formed by hardening of the mixture.
Abstract translation: 将水玻璃溶液与多异氰酸酯混合，然后将这些乳液在地层中硬化。 将混合物引入需要固结的地层中，例如 煤的沉积主要是通过将混合物压在地层的钻孔中进行的。 根据该方法的一个变化，将混合物的组分引入多腔室筒中，多腔室筒被引入钻孔中，然后当组分混合时被破坏。 某些添加剂如促进剂，发泡剂，多元醇，稳定剂和/或触变剂对通过混合物硬化形成的复合材料的质量是有利的。
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公开(公告)号：US4072019A
公开(公告)日：1978-02-07
申请号：US585624
申请日：1975-06-10
Applicant: Leonard L. Pearson
Inventor： Leonard L. Pearson
CPC classification number: C09K17/46 , Y10S106/90
Abstract: A soil consolidation composition and method of use involving an aqueous composition of an alkali metal silicate and a gelling agent, the composition having a viscosity sufficiently low (about 1 or 2 cps) so that it can penetrate to a pre-determined depth in a friable sandstone substrate to consolidate the substrate with the concentration of the silicate being sufficient to be gelled by the gelling agent after achievement of the penetration into the substrate.
Abstract translation: 包含碱金属硅酸盐和胶凝剂的水性组合物的土壤固结组合物和使用方法，所述组合物具有足够低的粘度（约1或2cps），使得其可以渗透到易碎的预定深度 砂浆基质，以使硅酸盐的浓度足以在实现渗透到基材中之后被胶凝剂凝胶化。
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公开(公告)号：US4004428A
公开(公告)日：1977-01-25
申请号：US629605
申请日：1975-11-06
Applicant: Shunsuke Tazawa , Kazuo Okabe
Inventor： Shunsuke Tazawa , Kazuo Okabe
CPC classification number: C09K17/46 , Y10S106/90
Abstract: In the stabilization of soil which comprises injecting into soil a mixture of (A) an aqueous sodium silicate solution and (B) at least one compound selected from the group consisting of chlorides, sulfates and nitrates of aluminum, magnesium and iron, and then gelling the injected mixture in soil, the formation of a large amount of the metal hydroxide precipitate on mixing the components (A) and (B) can be prevented by adding (C) at least one oxy acid selected from the group consisting of citric acid, tartaric acid and lactic acid to any one of the components (A) and (B).
Abstract translation: 在土壤稳定化中，包括将（A）硅酸钠水溶液和（B）至少一种选自铝，镁和铁的氯化物，硫酸盐和硝酸盐的化合物混合在一起，然后凝胶化 在土壤中注入的混合物可以通过添加（C）至少一种选自柠檬酸，柠檬酸，柠檬酸， 酒石酸和乳酸与组分（A）和（B）中的任何一种组合。
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公开(公告)号：US3306756A
公开(公告)日：1967-02-28
申请号：US29207363
申请日：1963-07-01
Applicant: DIAMOND ALKALI CO
Inventor： MILLER GEORGE A
CPC classification number: C09K17/46 , C04B28/26 , C09K17/48 , Y10S106/90 , C04B14/361 , C04B22/124 , C04B24/008 , C04B24/023 , C04B24/04 , C04B24/12 , C04B24/02 , C04B24/24 , C04B24/32
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Patent Agency Ranking
公开(公告)号：US3012405A
公开(公告)日：1961-12-12
申请号：US78602059
申请日：1959-01-12
Applicant: SOLETANCHE SOC
Inventor： CLAUDE CARON
IPC: C09K17/46
CPC classification number: C09K17/46 , Y10S106/90
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公开(公告)号：US06916366B2
公开(公告)日：2005-07-12
申请号：US09902555
申请日：2001-07-10
Applicant: Pierre Hirsbrunner , Ian Horman
Inventor： Pierre Hirsbrunner , Ian Horman
Abstract: A substrate treatment composition of an aqueous solution for imparting hydrophobicity to a substrate or for rendering the substrate hydrophobic. This solution preferably includes sodium and/or potassium methylsiliconate and sodium and/or potassium silicate. Also, the use of this composition for the treatment of a substrate to impart hydrophobicity or to render the substrate hydrophobic.
Abstract translation: 用于赋予基材疏水性或使基材疏水的水溶液的底物处理组合物。 该溶液优选包括甲基硅酸钠和/或钾，和硅酸钠和/或硅酸钾。 此外，使用该组合物来处理底物赋予疏水性或使底物具有疏水性。
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公开(公告)号：US5624599A
公开(公告)日：1997-04-29
申请号：US541994
申请日：1995-10-10
Applicant: Joel J. Gummeson , Alexandra Torres
Inventor： Joel J. Gummeson , Alexandra Torres
Abstract: Liquid hardeners for soil grouting formulations having an acid content no more than 0.1 mg KOH per gm in the form of dimethyl ester mixtures of dimethyl succinate, dimethyl glutarate and dimethyl adipate at a concentration in the mixtures lying within a bounded area in the graph of the drawing of the specification.
Abstract translation: 用于土壤灌浆制剂的液体固化剂，其酸含量不超过0.1mg KOH / g，以琥珀酸二甲酯，戊二酸二甲酯和己二酸二甲酯的二甲酯混合物的形式，其浓度位于图中的有界区域内 图纸说明书。
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9.发明授权Method for improving the strength and impermeability of soils and engineering structures 失效提高土壤和工程结构强度和不渗透性的方法
公开(公告)号：US4988238A
公开(公告)日：1991-01-29
申请号：US429945
申请日：1989-10-31
Applicant: Tamas Szekely , Gabor Nagy , Andras Danko , Janos Szepvolgyi , Andras Gal , Oszkar Libor
Inventor： Tamas Szekely , Gabor Nagy , Andras Danko , Janos Szepvolgyi , Andras Gal , Oszkar Libor
Abstract: A method is disclosed for improving the strength and impermeability of soils or engineering structures, which comprises the steps of:(a) applying to the site of the soil or of the engineering structure, an alkaline water glass solution comprising water glass in an amount of 15 to 40% by weight, calculated as dry substance;(b) allowing a time period to pass sufficient to permit the alkali present in the water glass solution to move by diffusion;(c) applying to the same site as in step (a), a silicic acid sol comprising SiO.sub.2 in an amount of 5 to 50% by weight calculated as dry substance, and an organic dispersion medium in which 10 to 100% by volume of the dispersion medium consists of a water-miscible organic solvent capable of reacting with the alkali content of the water glass solution applied during step (a), thereby gellifying the water glass so that the reaction product of the water-miscible organic solvent and the alkali content of the water glass is trapped within the gelled water glass; and(d) allowing a time period to pass sufficient to permit the respective organic dispersion medium present in the silicic acid sol to move by diffusion, so that gellification of the water glass takes place evenly when mixing of the water glass solution applied during step (a) and the silicic acid sol applied during step (c) to the soils or to the engineering structures takes place to effect a plasticizing effect on the resulting water glass gel.
Abstract translation: 公开了一种用于改善土壤或工程结构的强度和不渗透性的方法，其包括以下步骤：（a）向土壤或工程结构的位置施加包含水玻璃的碱性水玻璃溶液，其量为 15〜40重量％，以干物质计算; （b）允许时间段通过足以允许水玻璃溶液中存在的碱通过扩散而移动; （c）在与步骤（a）相同的部位施用含有按干物质计5〜50重量％SiO 2的硅酸溶胶，以及有机分散介质，其中10〜100体积％ 分散介质由与步骤（a）中施加的水玻璃溶液的碱含量反应的水混溶性有机溶剂组成，从而将水玻璃凝胶化，使水溶性有机溶剂与碱的反应产物 水玻璃的含量被凝固在凝胶水玻璃内; 和（d）允许一段时间通过足以使存在于硅酸溶胶中的各有机分散介质通过扩散移动，使得在步骤期间施加的水玻璃溶液的混合时水玻璃的胶凝化发生均匀（ a）和在步骤（c）中施加的硅酸溶胶施加到土壤或工程结构上以对所得水玻璃凝胶进行增塑作用。
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10.发明授权Process for consolidation and sealing coal and/or rock, soil and brick formations in mining, tunnelling and construction 失效在采矿，隧道和施工中固结和密封煤和/或岩石，土壤和砖块的过程
公开(公告)号：US4669919A
公开(公告)日：1987-06-02
申请号：US741561
申请日：1985-06-05
Applicant: Karl-Heinz Hilterhaus , Hans Norkus
Inventor： Karl-Heinz Hilterhaus , Hans Norkus
IPC: C09K3/10 , C04B28/26 , C08G18/08 , C08G18/09 , C08G18/16 , C08G18/30 , C08G18/38 , C09K8/508 , C09K17/00 , C09K17/30 , C09K17/46 , C09K17/48 , E21D11/00 , E21D11/38 , E21F17/00 , E02D3/12 , C09K7/00
CPC classification number: E21F17/00 , C04B28/26 , C08G18/0885 , C08G18/092 , C08G18/16 , C08G18/302 , C08G18/3895 , C09K8/5086 , C08G2270/00
Abstract: The invention relates to a process for consolidating and sealing coal and/or rock, soil and brick formations in mining, tunnelling and construction by reacting polyisocyanates and aqueous alkali silicate solutions in the presence of a catalyst prompting the trimerization of the polyisocyanate. The catalyst is used in an amount of 6.0 to 14.5 mmole per mole of NCO groups in the reaction mixture.When the reaction mixture is introduced into the coal and/or rock, soil and brick formation to be consolidated and is cured, excellent consolidation results are achieved on account of the formation of an "interpermeated network" of inorganic and organic polymer.
Abstract translation: 本发明涉及一种在催化剂存在下使多异氰酸酯和碱金属硅酸盐溶液反应促成多异氰酸酯的三聚反应，在采矿，隧道和施工中固结和密封煤和/或岩石，土壤和砖地层的方法。 反应混合物中每摩尔NCO基团的催化剂的用量为6.0至14.5毫摩尔。 当将反应混合物引入到煤和/或岩石中时，土壤和砖的形成被固化并固化，由于形成无机和有机聚合物的“间隔网络”，实现了优异的固结结果。
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