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    Triphendioxazine pigments
    3.
    发明授权
    Triphendioxazine pigments 失效
    三苯并二恶嗪颜料

    公开(公告)号：US07524953B2

    公开(公告)日：2009-04-28

    申请号：US10586093

    申请日：2005-01-12

    Applicant: David Blum ,  Carsten Plueg ,  Tanja Reipen

    Inventor： David Blum ,  Carsten Plueg ,  Tanja Reipen

    IPC: C07D498/02 ,  C09B19/02

    CPC classification number: C09B19/02

    Abstract: The invention relates to novel triphendioxazine pigments of formula (I) wherein X represents hydrogen or chlorine, while R1 represents phenyl substituted by one to five radicals from the group comprising C1-C4-alkyl, halogen, C1-C4-alkoxy, acetylamino, aminocarbonyl, methylaminocarbonyl and C1-C4-alkoxycarbonyl, or phenyl annelated in the 2,3- or 3,4- with a divalent radical of the formula —NH—(CO)m—NR2—, —CR2═CH—CO—NH—, —CR2═N—CO—NH—, —CO—NH—CO—NR2—, —CO—(NH)m—CO— or —O—(CO)m—NH— so as to form a five- or six-membered ring, R2 representing hydrogen, methyl, ethyl or phenyl and m representing 1 or 2.

    Abstract translation: 本发明涉及式（I）的新型三苯并二恶嗪颜料，其中X表示氢或氯，而R1表示被一至五个基团取代的苯基，该基团包括C 1 -C 4烷基，卤素，C 1 -C 4 - 烷氧基，乙酰氨基，氨基羰基 或甲基氨基羰基和C 1 -C 4烷氧基羰基，或在2,3-或3,4-中与式-NH-（CO）m -NR 2 - ，-CR 2 -CH-CO-NH- ，-CR2-N-CO-NH-，-CO-NH-CO-NR2-，-CO-（NH）m -CO-或-O-（CO）m-NH-，以便形成五 六元环，R 2代表氢，甲基，乙基或苯基，m代表1或2。

    Triphendioxazine
    5.
    发明授权
    Triphendioxazine 失效
    三苯并二恶嗪

    公开(公告)号：US6162261A

    公开(公告)日：2000-12-19

    申请号：US103946

    申请日：1998-06-24

    Applicant: Peter Kempter ,  Bansi Lal Kaul

    Inventor： Peter Kempter ,  Bansi Lal Kaul

    IPC: C07D498/22 ,  C09B19/02 ,  C09D7/12 ,  C09D11/00 ,  C09D11/02 ,  G03G9/09 ,  C07D498/14

    CPC classification number: C09B19/02

    Abstract: The invention relates to triphendioxazine compounds of the formula (I) ##STR1## where the rings marked with A comprise, independently of one another, rings which are fused linearly in positions 2,3 and 9,10 or angularly in positions 1,2 and 8,9 or 3,4 and 10,11 and have the radical members of the formula (i) --NR.sub.1 (CO).sub.m --NH--, (ii) --CR.sub.1 .dbd.CH--CO--NH--, (iii) --O--CH.sub.2 --CO--NH--, (iv) --CO--CH.dbd.CR.sub.1 --NH--, (v) --CO--NH--CO--NH--, (vi) --CO--NH--CR.sub.2 .dbd.N--, (vii) --CR.sub.2 .dbd.N--CO--NH--, (viii) --NR.sub.1 --(CO).sub.m --O--, (ix) --NH--CR.sub.1 .dbd.N--, (x) --NH--CO--CR.sub.1 .dbd.N--, (xi) --NH--CO--CHR.sub.1 --NH--, (xii) --NR.sub.3 --(CO).sub.m --NR.sub.4 --, (xiii) --NR.sub.5 --(CO).sub.m --NR.sub.6 --, (xiv) --NR.sub.4 --CO--O-- or (xv) --NR.sub.6 --CO--O--,m is 1 or 2,R.sub.1 is hydrogen, C.sub.1-4 alkyl or phenyl, preferably hydrogen, methyl or ethyl,R.sub.2 is hydrogen, C.sub.1-4 alkyl or phenyl, preferably hydrogen, methyl or ethyl,R.sub.3, R.sub.4, R.sub.5 and R.sub.6 independently of one another are hydrogen, a C.sub.1-8 alkyl radical, a substituted or unsubstituted phenyl, benzyl, naphthyl or benzanilide radical, a substituted or unsubstituted C.sub.5-6 cycloalkyl radical or a radical of the formula ##STR2## and the angular molecules in positions 3 and 10 and/or positions 2 and 9 can each carry a C.sub.1-2 alkoxy group,to the process for their preparation and to their use as pigments having high migration and solvent fastness.

    Abstract translation: 本发明涉及式（I）的三苯并二恶嗪化合物，其中用A标记的环彼此独立地包含在2,3和9,10位上线性融合或在1,2和8,9位上成角度稠合的环 或者3,4和10,11，并具有式（ⅰ）-NR1（CO）m-NH-，（ⅱ）-CR1 = CH-CO-NH-，（ⅲ）-O-CH2- CO-NH-，（iv）-CO-CH = CR1-NH-，（v）-CO-NH-CO-NH-，（vi）-CO-NH-CR2 = N-，（vii） N-CO-NH-，（viii）-NR1-（CO）mO-，（ix）-NH-CR1 = N-，（x）-NH-CO-CR1 = N-，（Ⅺ） （xii）-NR5-（CO）m-NR6-，（xiv）-NR4-CO-O-或（xv）-NR6 -CO-O-，m是1或2，R1是氢，C1-4烷基或苯基，优选氢，甲基或乙基，R2是氢，C1-4烷基或苯基，优选氢，甲基或乙基，R3，R4， R 5和R 6彼此独立地是氢，C 1-8烷基，取代或未取代的苯基，苄基，萘基或苯甲酰苯胺基，取代或未取代的C 5-6环烷基或 3号和10号和/或2号和9号角分子可以分别载有C1-2烷氧基，制备方法和用作具有高迁移和耐溶剂牢度的颜料。

    Asymmetric dioxazine compounds, intermediate compounds therefor and application of the asymmetric dioxazine compounds
    7.
    发明授权
    Asymmetric dioxazine compounds, intermediate compounds therefor and application of the asymmetric dioxazine compounds 失效
    不对称二恶嗪化合物，其中间体化合物和不对称二嗪化合物的应用

    公开(公告)号：US5837869A

    公开(公告)日：1998-11-17

    申请号：US788816

    申请日：1997-01-23

    Applicant: Masato Inoue ,  Junya Hada ,  Toshiyuki Araki

    Inventor： Masato Inoue ,  Junya Hada ,  Toshiyuki Araki

    IPC: C07D498/04 ,  C09B19/02 ,  C09B62/04 ,  C09B62/503 ,  D06P1/382 ,  D06P1/384 ,  C09B19/00 ,  C07D265/38

    CPC classification number: C09B19/02

    Abstract: An asymmetric dioxazine compound represented, when shown in free acid form, by the general formula (I): ##STR1## wherein T.sub.1 and T.sub.2 represent a hydrogen atom, a chlorine atom, a bromine atom, a lower alkyl group, a phenoxy group or others, A.sub.1 represents an alkyl group, a chlorine atom, a carboxyl group or others, A.sub.2 represents a hydrogen atom, an alkyl group, a chlorine atom, a carboxyl group or others, R represents a hydrogen atom or a lower alkyl group, X and Y represent a halogen atom, a fiber-reactive group or others, respectively, with the proviso that at least one of X and Y is a fiber-reactive group is provided. The compound is suitable for dyeing or printing of a fiber material or the like which has a hydroxy group and/or an amide group, and provides a blue-dyed product with various fastness, including particularly chlorine fastness.

    Abstract translation: 以游离酸形式表示的通式（I）表示的不对称二嗪类化合物：其中，T1和T2表示氢原子，氯原子，溴原子，低级烷基 基，苯氧基等，A1表示烷基，氯原子，羧基等，A2表示氢原子，烷基，氯原子，羧基等，R表示氢原子或 低级烷基，X和Y分别表示卤素原子，纤维反应性基团等，条件是提供X和Y中的至少一个是纤维反应性基团。 该化合物适用于具有羟基和/或酰胺基的纤维材料等的染色或印刷，并提供具有各种牢度的蓝色染色产品，特别是耐氯牢度。

    Triphenedioxazines, their preparation and the use thereof
    10.
    发明授权
    Triphenedioxazines, their preparation and the use thereof 失效
    三苯二恶嗪，其制备及其用途

    公开(公告)号：US5439486A

    公开(公告)日：1995-08-08

    申请号：US116773

    申请日：1993-09-03

    Applicant: Urs Lauk

    Inventor： Urs Lauk

    IPC: C07D498/04 ,  C07D519/00 ,  C09B19/00 ,  C09B19/02 ,  C09B62/04 ,  C09B67/22 ,  D06P3/10 ,  D06P3/66 ,  D06P3/82 ,  D06P3/874 ,  C09B62/02 ,  D06P1/382 ,  D06P1/40

    CPC classification number: C07D498/04 ,  C07D519/00 ,  C09B19/02 ,  C09B62/043

    Abstract: Dye mixtures obtainable by condensing a compound of the formula ##STR1## and a compound of the formula ##STR2## with a compound of the formulaT--B--T (9)where the ring substituents are as defined herein, B is a bivalent organic linking group and T is halogen are suitable for use as direct dyes for dyeing and printing a wide range of materials and especially of cellulosic fibre materials, to give dyeings and prints of good allround fastness properties.

    Abstract translation: 通过将式（8）的化合物和式（IMAGE）（10）的化合物与式TBT（9）的化合物缩合得到的染料混合物，其中环取代基如本文所定义，B为 二价有机连接基团和T为卤素适合用作染色和印刷各种材料，特别是纤维素纤维材料的直接染料，以提供良好的全面牢度特性的染色和印花。

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