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公开(公告)号:US12157794B2
公开(公告)日:2024-12-03
申请号:US17882076
申请日:2022-08-05
Applicant: Natural Fiber Welding, Inc.
Inventor: Aaron Kenneth Amstutz , Luke Michael Haverhals , Isaiah Amstutz , Skylar Clement , Shang-Min Li
Abstract: A curative for epoxidized plant-based oils and epoxidized natural rubber is created from the reaction between a naturally occurring polyfunctional acid and an epoxidized plant-based oil is disclosed. The curative may be used to produce at least one of six different materials, wherein each type of material may be configured as a thermosetting elastomer that is crosslinked with β-hydroxyester linkages. The materials may be configured as a leather-like material, a foam material, a molded elastomer, a coating, an adhesive, and/or a rigid or semi-rigid material. Illustrative articles made from any combination of the six materials may be recycled using a mechano-chemical process to de-crosslink the thermosetting elastomer.
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公开(公告)号:US20240239954A1
公开(公告)日:2024-07-18
申请号:US18561973
申请日:2022-05-26
Applicant: SWIMC LLC
Inventor: Nusrah HUSSAIN , George K. BARTLEY, III , Beverly A. ACCIPITER , Brenda E. HOHMAN , Arthur RIAZZI
IPC: C08G63/42 , C08G63/78 , C09D5/08 , C09D167/04
CPC classification number: C08G63/42 , C08G63/78 , C09D5/08 , C09D167/04 , C08G2150/90 , C08G2650/36
Abstract: A polyester copolymer useful for food and beverage container coatings is disclosed. The copolymer is derived from ingredients including at least a diepoxide, such as a diglycidyl ether, and a glass transition increasing monomer, such as a pentaspiroglycol. In some approaches, the polyester copolymer is derived from reaction of a polyester prepolymer and a diepoxide resin.
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公开(公告)号:US20240140961A1
公开(公告)日:2024-05-02
申请号:US17768686
申请日:2020-10-14
Inventor: Jeremy LUTERBACHER , Lorenz MANKER , Graham Dick , Stefania BERTELLA
IPC: C07D493/14 , C08G63/42 , C08L97/02
CPC classification number: C07D493/14 , C08G63/42 , C08L97/02 , C08G2230/00 , C08L2207/20
Abstract: Described is a compound having the structure (I), (II) or (V), Formulae(I), (II), (V), wherein R1 is —H, —CH2OH or —CH(OH)CH2OH; R2 is —H, —OH, or —CH2OH; R3 is —H, —OH, or —CH2OH; n is 0 or 1; p is 0 or 1; R10 is hydrogen or a hydrocarbon moiety with 1 to 20 carbon atoms, wherein each hydrogen atom of the hydrocarbon moiety may optionally be substituted with a C1-C4-alkyl group or a halogen atom; R is either —Z—F or Y and wherein Z is a hydrocarbon moiety with 0 to 10 carbon atoms, optionally substituted with 1 to 4 C1-C4-alkyl groups or 1 to 4 halogen atoms, and F is —COOH, —CH(COOH)2, —COOR4, —CHO, —CH(CHO)2, C2H3, —C2H, —N3, —NH2, —NHR7, —OH, —CH(CH2OH)2, wherein R4 is a C1-C4-alkyl group and R7 is a C1-C4-alkyl group and wherein Y is hydrogen or a linear, branched or cyclic organic residue having 1 to 20 carbon atoms with the proviso that if R is Y and n is 0 at least one of R1 or R2 is not hydrogen. Also described is a method for the preparation of the compound, a polymer derived from the compound as well as a method for the preparation of the polymer.
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公开(公告)号:US11760836B2
公开(公告)日:2023-09-19
申请号:US17155000
申请日:2021-01-21
Applicant: Natural Fiber Welding, Inc.
Inventor: Aaron Kenneth Amstutz , Luke Michael Haverhals , Albert C Pierz , Ian T Pierz , Nima Ezatollah Amini , Skylar Clement
CPC classification number: C08G63/42 , B32B5/022 , B32B5/024 , B32B9/06 , B32B25/10 , B32B25/12 , C08C19/06 , C08G63/81 , C08J3/24 , B32B2305/72 , B32B2307/50 , B32B2319/00 , C08J2315/00
Abstract: A coating created entirely from plant-derived ingredients is disclosed. Illustrative embodiments of the coating may be particularly well suited for use on leather-like materials created from epoxidized natural rubber-based formulations. Illustrative embodiments of the coating created may be comprised of substantially the reaction product between epoxidized vegetable oil and a polyfunctional naturally occurring acid (such as citric acid). Illustrative embodiments this reaction product may be used to produce porosity-free castable resins and vulcanize rubber formulations based on epoxidized natural rubber. Materials made from disclosed materials may be advantageously used as leather substitutes.
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公开(公告)号:US11421075B2
公开(公告)日:2022-08-23
申请号:US17129239
申请日:2020-12-21
Applicant: Natural Fiber Welding, Inc.
Inventor: Aaron Kenneth Amstutz , Luke Michael Haverhals , Albert C Pierz , Ian T Pierz
Abstract: A curative for epoxidized plant-based oils and epoxidized natural rubber is created from the reaction between a naturally occurring polyfunctional acid and an epoxidized plant-based oil is disclosed. The curative may be used to produce porosity-free castable resins and vulcanize rubber formulations based on epoxidized natural rubber. Materials made from disclosed materials may be advantageously used as leather substitutes.
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公开(公告)号:US11352718B2
公开(公告)日:2022-06-07
申请号:US16348407
申请日:2017-11-09
Inventor: Ronald D. Moffitt , Robert Kriegel , Marlon Salvador Morales , Haiyu Ren , Yang Yi , Jing Liu , Hongbin Qi
IPC: D01F6/84 , C08G63/183 , C08G63/42 , D01F6/62
Abstract: Disclosed are bio-based polyester fibers, particularly a PET fibers, and a method of making the same by: contacting bio-based MEG composition with a diacid composition to form a polyester composition; and spinning and/or drawing the resulting polyester composition into a fiber; wherein the bio-based MEG composition comprises: a) monoethylene glycol (MEG); and b) from about 1 ppm to about 5000 ppm of at least one C3-Cy2 1,2-diol, wherein the C3-Cj2 1, 2-diol is linear, branched, or cyclic.
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公开(公告)号:US10995177B2
公开(公告)日:2021-05-04
申请号:US16013474
申请日:2018-06-20
Applicant: International Business Machines Corporation , Agency for Science, Technology and Research
Inventor: James L. Hedrick , Yi Yan Yang , Chuan Yang
Abstract: Compositions and methods regarding guanidinium functionalized polycarbonates that provide potent antimicrobial activity against multidrug resistant (MDR) bacteria, including Klebsiella pneumoniae (K. pneumoniae) are provided. According to an embodiment, an antimicrobial guanidinium-functionalized polymer is provided that comprises a hydrophobic molecular backbone with cationic guanidinium moieties respectively bound to the hydrophobic molecular backbone via butyl spacer groups. The antimicrobial guanidinium-functionalized polymer self-assembles into a micelle structure with hydrophobic residuals of the antimicrobial guanidinium-functionalized polymer buried inside the micelle structure and the cationic guanidinium moieties exposed on an external surface of the micelle structure to target pathogens.
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公开(公告)号:US20210115189A1
公开(公告)日:2021-04-22
申请号:US17129267
申请日:2020-12-21
Applicant: Natural Fiber Welding, Inc.
Inventor: Aaron Kenneth Amstutz , Luke Michael Haverhals , Albert C. Pierz , Ian T. Pierz
Abstract: A curative for epoxidized plant-based oils and epoxidized natural rubber is created from the reaction between a naturally occurring polyfunctional acid and an epoxidized plant-based oil is disclosed. The curative may be used to produce porosity-free castable resins and vulcanize rubber formulations based on epoxidized natural rubber. Materials made from disclosed materials may be advantageously used as leather substitutes.
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公开(公告)号:US20210108030A1
公开(公告)日:2021-04-15
申请号:US17129239
申请日:2020-12-21
Applicant: Natural Fiber Welding, Inc.
Inventor: Aaron Kenneth Amstutz , Luke Michael Haverhals , Albert C Pierz , Ian T Pierz
Abstract: A curative for epoxidized plant-based oils and epoxidized natural rubber is created from the reaction between a naturally occurring polyfunctional acid and an epoxidized plant-based oil is disclosed. The curative may be used to produce porosity-free castable resins and vulcanize rubber formulations based on epoxidized natural rubber. Materials made from disclosed materials may be advantageously used as leather substitutes.
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公开(公告)号:US10975192B2
公开(公告)日:2021-04-13
申请号:US15538847
申请日:2015-11-19
Applicant: Rohm and Haas Company
Inventor: Joseph J. Zupancic , David E. Vietti , Amira A. Marine
IPC: C08G59/42 , C08G63/42 , C08G63/672 , C08G63/676 , C08G63/91 , C08L67/02 , C08L75/04 , C08L67/06 , C08L77/08 , C08K5/103 , C09J167/00 , C08L63/00 , C08L71/02 , C09J163/00 , C08L67/07
Abstract: The instant invention provides a curable formulation suitable for laminating adhesive applications, and laminating adhesives made therefrom. The curable formulation suitable for laminating adhesive applications according to the present invention comprises a) a blend comprising i) an epoxy terminated polyester and at least one of ii) a maleate (poly) ester or iii) a diacrylate terminated oligomer or polymer and b) an aliphatic amine curing agent.
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