摘要:
The present invention provides a halogen-free curable composition including a benzoxazine monomer, at least one epoxy resin, a catalyst, a toughening agent and a solvent. The halogen-free curable composition is especially suited for use in automobile and aerospace applications since the composition, upon curing, produces a composite having a high glass transition temperature.
摘要:
The invention relates to a method for preparing an epoxy prepolymer composition comprising glycidyl ethers, said method comprising the following steps:
a) placing a dianhydrohexitol into contact with another alcohol so as to obtain a composition of alcohols; b) reacting the composition of alcohols obtained in step a) with an epihalohydrin so as to obtain a reaction mixture comprising glycidyl ethers; c) recovering the epoxy prepolymer composition comprising glycidyl ethers from the reaction mixture obtained at the end of step b);
The invention also relates to an epoxy prepolymer composition that can be obtained by said method, a curable composition comprising said epoxy prepolymer composition, a polyepoxide obtained by curing said curable composition and a composite material, coating or adhesive comprising said polyepoxide.
摘要:
The present invention relates to a process for preparing hydrophobically associating macromonomers M and to the novel macromonomers prepared by means of the process according to the invention. The macromonomers M comprise a copolymerizable, ethylenically unsaturated group and a polyether structure in block form, the latter consisting of a polyethyleneoxy block and a hydrophobic polyalkyleneoxy block consisting of alkyleneoxy units having at least 4 carbon atoms. Optionally, the macromonomers M may have a terminal polyethyleneoxy block. The macromonomers prepared by the process according to the invention are suitable for reaction with further monomers, especially with acrylamide, to give a water-soluble, hydrophobically associating copolymer.
摘要:
The invention relates to a one-component, moisture-curing adhesive containing at least one polyoxyalkylene and/or poly(methyl)acrylate prepolymer having at least one hydrolyzable silane group, at least one filler, and auxiliary materials and additives, wherein the prepolymer has a molecular weight of 4,000 to 40,000 g/mol and the adhesive has a viscosity of 200 to 10,000 mPas.
摘要:
The present invention relates a process of the present invention for the preparation of an aqueous composition comprising a polyurethane carrying COOH groups and/or salt groups thereof, comprises the steps of (i) reacting at least one first polyisocyanate (A1) with at least one polyol carrying at least one COOH group (BX) and optionally at least one first polyol carrying no COOH group (B1) to form a first composition (C1), (ii) treating the first composition (C1) obtained in step (i) with at least one second polyol carrying no COOH group (B2), and optionally with at least one second polyisocyanate (A2), to form a second composition (C2), and (iii) optionally treating the second composition (C2) obtained in step (ii) with at least one third-polyisocyanate (A3), to form a third composition (C3), wherein step (i) is stopped at a reaction index in the range of 0.05 to 0.94, wherein reaction index=reaction rate×[mol initial NCO groups of all A1/(mol initial OH groups of all BX and, if present, mol initial OH groups of all B1)] (formula 1) wherein reaction rate=1 minus (mol NCO groups of C1/mol initial NCO groups of all A1), and to an aqueous composition comprising a polyurethane carrying COOH groups and/or salt groups thereof obtainableby this process, to a process for the preparation of an aqueous composition comprising a polyurethane/poly(meth)acrylate hybrid polymer using the aqueous composition comprising a polyurethane carrying COOH groups and/or salt groups thereof of the present invention, to aqueous compositions comprising a polyurethane/poly(meth)acrylate hybrid polymer obtainable by the this process, to coating compositions comprising the aqueous composition comprising a polyurethane carrying COOH groups and/or salt groups thereof or the aqueous compositions comprising a polyurethane/poly(meth)acrylate hybrid polymer, and to substrates coated with these coating compositions.
摘要:
A resin composition includes the following components or a prepolymer thereof: (A) 100 parts by weight of an unsaturated C═C double bond-containing polyphenylene ether resin; and (B) 10 parts by weight to 50 parts by weight of a compound of Formula (1), having a pH value of 10 or less. In Formula (1), n is an integer of 3 to 6, each Y and Z are independently selected from o-vinylphenoxy group and phenoxy group, and each Y and Z are not phenoxy group at the same time. The prepolymer is prepared by subjecting a mixture to a prepolymerization reaction, and the mixture at least comprises the component (A) and the component (B). An article is made from the resin composition. The article includes a prepreg, a resin film, a laminate or a printed circuit board and achieves improvements in one or more properties including resin filling uniformity, dissipation factor variation rate under heat, glass transition temperature, Z-axis ratio of thermal expansion, peeling strength and thermal resistance after moisture absorption.
摘要:
The curable composition is a curable composition containing an oxyalkylene polymer A having a reactive silicon group represented by —SiRa(X)3-a, wherein the oxyalkylene polymer A has 6 or more terminal groups per molecule; the terminal group contains at least one selected from the group consisting of a reactive silicon group represented by —SiRa(X)3-a, an active hydrogen-containing group, and an unsaturated group; the oxyalkylene polymer A has 0.3 or more reactive silicon groups per terminal group; and the number average molecular weight of the oxyalkylene polymer A is more than 25,000 and not more than 100,000.
摘要:
A method for forming a halogen-free curable composition containing a benzoxazine monomer, at least one epoxy resin, a catalyst, a toughening agent and a solvent. The halogen-free curable composition is especially suited for use in automobile and aerospace applications since the composition, upon curing, produces a composite having a high glass transition temperature.
摘要:
A polyester copolymer useful for food and beverage container coatings is disclosed. The copolymer is derived from ingredients including at least a diepoxide, such as a diglycidyl ether, and a glass transition increasing monomer, such as a pentaspiroglycol. In some approaches, the polyester copolymer is derived from reaction of a polyester prepolymer and a diepoxide resin.