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    Propylene polymer and block copolymer
    3.
    发明授权
    Propylene polymer and block copolymer 失效
    丙烯聚合物和嵌段共聚物

    公开(公告)号：US06545099B2

    公开(公告)日：2003-04-08

    申请号：US09899134

    申请日：2001-07-06

    申请人： Tetsunori Shinozaki ,  Kazumitsu Kawakita ,  Mamoru Kioka

    发明人： Tetsunori Shinozaki ,  Kazumitsu Kawakita ,  Mamoru Kioka

    IPC分类号： C08F29300

    CPC分类号： C08F297/083 ,  C08F10/06 ,  C08F110/06 ,  C08F297/06 ,  C08F2500/15 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/26

    摘要： Disclosed are a propylene polymer having a high crystallinity of a boiled heptane-insoluble component contained therein, a high stereoregularity and an extremely long mesochain (continuous propylene units wherein directions of &agr;-methyl carbons are the same as each other), and a process for preparing said polymer. Also disclosed are a propylene block copolymer containing a crystalline polypropylene portion having a high crystallinity of a boiled heptane-insoluble component contained therein, a high stereoregularity and an extremely long mesochain, and a process for preparing said copolymer. Further disclosed is a propylene polymer composition comprising the above propylene polymer or propylene block copolymer and at least one stabilizer selected from a phenol type stabilizer, an organophosphite type stabilizer, a thioether type stabilizer, a hindered amine type stabilizer and a metallic salt of higher aliphatic acid. The propylene polymer of the invention is excellent in rigidity, heat resistance and moisture resistance, and can be favorably used for sheet, film, filament, injection molded product, blow molded product, etc. The propylene block polymer of the invention is well-balanced between rigidity, heat resistance and moisture resistance, and can be favorably used for sheet, filament, injection molded product, blow molded product, etc.

    摘要翻译： 公开了具有高沸点庚烷不溶性组分的高结晶度丙烯聚合物，高立构规整性和极长的分散信号（其中α-甲基碳的方向彼此相同的连续丙烯单元），以及 制备所述聚合物。 还公开了含有其中所含的沸腾庚烷不溶性组分具有高结晶度的结晶聚丙烯部分，高立构规整性和极长的间轴的丙烯嵌段共聚物以及制备所述共聚物的方法。 还公开了一种丙烯聚合物组合物，其包含上述丙烯聚合物或丙烯嵌段共聚物和至少一种选自酚类稳定剂，有机亚磷酸酯类稳定剂，硫醚型稳定剂，受阻胺型稳定剂和高级脂肪族金属盐 酸。 本发明的丙烯聚合物的刚性，耐热性和耐湿性优异，可有利地用于片材，薄膜，长丝，注塑产品，吹塑产品等。本发明的丙烯嵌段聚合物是均衡的 在刚性，耐热性和耐湿性之间，可以有利地用于片材，长丝，注塑产品，吹塑产品等。

    Curable resin composition
    6.
    发明授权
    Curable resin composition 失效
    可固化树脂组合物

    公开(公告)号：US06437069B1

    公开(公告)日：2002-08-20

    申请号：US09630561

    申请日：2000-08-02

    申请人： Katsutoshi Yokoyama

    发明人： Katsutoshi Yokoyama

    IPC分类号： C08F29300

    CPC分类号： C08F218/16 ,  C08F218/00 ,  C08F290/061

    摘要： A curable resin composition comprising (A) at least one aromatic diallyl compound, (B) at least one maleate diester and/or fumarate diester, (C) at least one (meth)allyl carbonate compound and (D) at least one radical chain transfer agent gives a cured material having excellent optical and mechanical properties.

    摘要翻译： 一种可固化树脂组合物，其包含（A）至少一种芳族二烯丙基化合物，（B）至少一种马来酸酯二酯和/或富马酸二酯，（C）至少一种（甲基）烯丙基碳酸酯化合物和（D）至少一个基团链 转印剂得到具有优异的光学和机械性能的固化材料。

    Thermoplastic elastomeric block copolymers
    7.
    发明授权
    Thermoplastic elastomeric block copolymers 失效
    热塑性弹性体嵌段共聚物

    公开(公告)号：US06197889B1

    公开(公告)日：2001-03-06

    申请号：US08981051

    申请日：1997-12-11

    申请人： Konrad Knoll ,  Hermann Gausepohl ,  Norbert Niessner ,  Paul Naegele ,  Wolfgang Fischer

    发明人： Konrad Knoll ,  Hermann Gausepohl ,  Norbert Niessner ,  Paul Naegele ,  Wolfgang Fischer

    IPC分类号： C08F29300

    CPC分类号： C08F297/04

    摘要： Elastomeric block copolymers comprising at least one hard block A composed of styrene monomers and at least one elastomeric block (B/A) composed of styrene monomers and dienes, the glass transition temperature Tg of the block A being more than 25° C. and that of block (B/A) being less than 25° C. and the phase volume ratio of block A to block (B/A) being chosen so that the proportion of the hard phase in the total block copolymer is from 1 to 40% by volume and the amount by weight of the diene is less than 50% by weight, and the relative proportion of 1,2 linkages of the polydiene, based on the sum of 1,2- and 1,4-cis/trans linkages, being below 15%, are prepared by anionic polymerization by means of a lithium alkyl in a nonpolar solvent in the presence of a soluble potassium salt and are used for the production of shaped articles.

    摘要翻译： 弹性体嵌段共聚物包含至少一个由苯乙烯单体组成的硬嵌段A和至少一个由苯乙烯单体和二烯构成的弹性嵌段（B / A），嵌段A的玻璃化转变温度Tg高于25℃， （B / A）小于25℃，并且选择块A与嵌段（B / A）的相体积比，使得总嵌段共聚物中硬相的比例为1〜40％ 并且二烯的重量百分比小于50重量％，并且基于1,2-和1,4-顺/反键的总和的聚二烯的1,2-键的相对比例， 低于15％，通过在非极性溶剂中在可溶性钾盐的存在下通过烷基锂进行阴离子聚合制备，并用于生产成型制品。

    Multiblock interpolymers and processes for the preparation thereof
    8.
    发明授权
    Multiblock interpolymers and processes for the preparation thereof 失效
    多嵌段互聚物及其制备方法

    公开(公告)号：US06777499B2

    公开(公告)日：2004-08-17

    申请号：US10152184

    申请日：2002-05-20

    申请人： Yang Li ,  Dingyi Hong ,  Mingchu Gu ,  Jinzong Yang ,  Yurong Wang ,  Hongde Xu ,  Xingjun Lu ,  Li Yang ,  Jian Ding ,  Zhanxia Lv ,  Yongjun Lu ,  Yuchun Song

    发明人： Yang Li ,  Dingyi Hong ,  Mingchu Gu ,  Jinzong Yang ,  Yurong Wang ,  Hongde Xu ,  Xingjun Lu ,  Li Yang ,  Jian Ding ,  Zhanxia Lv ,  Yongjun Lu ,  Yuchun Song

    IPC分类号： C08F29300

    CPC分类号： C08F297/04 ,  C08F297/02

    摘要： The present invention relates to multiblock interpolymers having the following symmetric structures and processes for their preparation: Y-X-Y, wherein Y represents a block of a random copolymer of conjugated diene and monovinyl aromatic monomer; and X represents a block of butadiene homopolymer, a block of isoprene homopolymer, or a block of butadiene/isoprene copolymer, and processes for the preparation thereof. The present multiblock interpolymers have in the same molecule both a rubber block of random copolymer of conjugated diene and monovinyl aromatic monomer and a rubber block selected from blocks of butadiene homopolymer, isoprene homopolymer and butadiene/isoprene copolymers, and hence possess excellent properties of the both two kinds of rubbers, and can be used widely as integrated rubber materials with excellent property balance, the present processes can simply prepare the above integrated rubber material in situ in a single reactor.

    摘要翻译： 本发明涉及具有以下对称结构的多嵌段互聚物及其制备方法：Y-X-Y，其中Y表示共轭二烯和单乙烯基芳族单体的无规共聚物的嵌段; X表示丁二烯均聚物嵌段，异戊二烯均聚物嵌段或丁二烯/异戊二烯共聚物嵌段，以及其制备方法。 本发明的多嵌段互聚物在同一分子中具有共轭二烯和单乙烯基芳族单体的无规共聚物的橡胶嵌段和选自丁二烯均聚物，异戊二烯均聚物和丁二烯/异戊二烯共聚物的嵌段的橡胶嵌段，因此具有优异的性能 两种橡胶，可广泛用作具有优异性能平衡的综合橡胶材料，本方法可以简单地在单个反应器中原位制备上述一体化橡胶材料。

    Method of making graft, block-graft and star-shaped copolymers by in-situ coupling reaction
    9.
    发明授权
    Method of making graft, block-graft and star-shaped copolymers by in-situ coupling reaction 失效
    通过原位偶联反应制备接枝，嵌段接枝和星形共聚物的方法

    公开(公告)号：US06639013B1

    公开(公告)日：2003-10-28

    申请号：US09609541

    申请日：2000-07-03

    申请人： Eli Ruckenstein ,  Hongmin Zhang

    发明人： Eli Ruckenstein ,  Hongmin Zhang

    IPC分类号： C08F29300

    CPC分类号： C08F297/026 ,  C08G81/021

    摘要： The present invention provides a method for the preparation of graft, block, and star-shaped copolymers. The method involves in situ coupling reaction between a living anionic backbone polymer possessing epoxy side chains and other living anionic polymers. The present method is simple, the coupling reaction is fast, pure copolymers are produced and the molecular weight, graft number and grafting position can be controlled to a greater extent than in existing methods.

    摘要翻译： 本发明提供了制备接枝，嵌段和星形共聚物的方法。 该方法涉及具有环氧侧链的活性阴离子主链聚合物和其它活性阴离子聚合物之间的原位偶联反应。 本发明方法简单，偶联反应快，产生纯共聚物，分子量，接枝数和接枝位置可以比现有方法更大程度地控制。