摘要:
This disclosure describes polymerization processes and processes for quenching polymerization reactions using reactive particulates, such as high molecular weight functionalized olefin copolymers, as quenching agents, typically in solution or bulk polymerization processes.
摘要:
Provided is a binder composition for a non-aqueous secondary battery positive electrode that can form a positive electrode with which it is possible to obtain a non-aqueous secondary battery having excellent life characteristics even when aging treatment is carried out under low-temperature and low-depth of charge conditions. The binder composition contains a first binder, iron, and at least one of ruthenium and rhodium. The total iron, ruthenium, and rhodium content is no greater than 5×10−3 parts by mass per 100 parts by mass of the first binder.
摘要:
Novel hydrogenated nitrile rubbers are provided, which, as well as having reduced contents of phosphines and/or diphosphines, include phosphine oxides and a specific content of halogens, and which enable access to vulcanizable mixtures and corresponding vulcanizates that possess improved moduli and compression set values and good values for heat buildup under dynamic stress. These novel hydrogenated nitrile rubbers are obtained by a specific production process, in the course of which the hydrogenated nitrile rubbers are reacted with at least one specific oxidizing agent.
摘要:
The present invention relates to a method of reducing type IV rubber allergy of synthetic rubber latex products caused by chemical residues remaining after manufacture of the synthetic rubber products by reducing levels of chemical residues found for said products, said method comprising the steps of: subjecting said products to a wash in a strong alkaline solution to remove the chemical residues remaining after manufacture of the rubber latex products, and a system for reducing type IV allergenicity of synthetic rubber products caused by chemical residues remaining after manufacture of the synthetic rubber latex products by reducing residual levels of chemical residues found for said products, and a product, such as a glove, manufactured from synthetic rubber latex processed in accordance with the method and/or using the system. Further the invention relates to a use of a method of subjecting products to said wash and raising the temperature to at least 100 C to remove the chemical residues remaining after manufacture of the synthetic rubber products.
摘要:
The present invention provides: a process for preparing a vinyl polymer containing a halogen in an amount of 1,000 mg or less per kilogram, in which a vinyl polymer containing the halogen produced by atom transfer radical polymerization of a vinyl monomer is heated at a temperature in the range of 140 to 250° C. to dehalogenate the vinyl polymer; a vinyl polymer obtained by the process; and a hydrosilylation-reactive curable composition containing the vinyl polymer.
摘要:
Conductive polymers are purified using a solid scavenger. The solid scavengers include metal-scavenging functional groups linked to the surface of a particle support material. To improve the functionalization of the support material, the support materials are first treated with sulfuric acid or nitric acid before attaching the molecules containing the metal-scavenging functional groups. The solid scavengers used in the purification methods are more efficient at removing impurities in conductive polymers than existing scavengers.
摘要:
The present invention relates to a method of reducing hydrolysis and coupling of substituents of siloxane end capped polymers containing hydrolyzable substituents during contact with water. The Mooney viscosity of siloxane terminated polymers is stabilized during such contact by treating the polymer with a stabilizing amount of stabilizing agent selected from the group consisting of: an acid, an acyl halide, methane sulfonic acid, toluene sulfonic acid, sulfuryl chloride, thionylchloride, phosgene, carbon dioxide, sulfur dioxide, sulfur trioxide, SOCl.sub.2 and SO.sub.2 Cl.sub.2, prior to contacting the siloxane terminated polymer with water.
摘要:
This is an improvement in a process for the hydrogenation of conjugated diolefin polymers which comprises polymerizing or copolymerizing at least one conjugated diolefin with an organo alkali metal polymerization initiator in a suitable solvent thereby creating a living polymer, terminating the polymerization by the addition of hydrogen, thereby generating an alkali metal hydride, and effecting selective hydrogenation of the unsaturated double bonds in the conjugated diolefin units of the terminated polymer by contacting the polymer, in the absence of hydrocarbon lithium and alkoxy lithium compounds, with hydrogen in the presence of at least one bis(cyclopentadienyl)titanium compound. The improvement comprises treating the polymer, before hydrogenation, with a reagent to increase catalyst activity, the reagent being such that it will react with the alkali metal hydride present in the polymer.
摘要:
A process is provided for removing rhodium-containing catalyst residue from a solution of hydrogenated nitrile rubber. The process utilizes an ion exchange resin which must be both macroreticular and modified with a selected amine, thiol, carbodithioate, thiourea and/or dithiocarbamate functional group. The process is capable of removing rhodium from viscous rubber solutions containing less than 10 ppm rhodium. In a preferred embodiment, the process is undertaken in an ion-exchange column.