HYDROGENATED NITRILE RUBBER CONTAINING PHOSPHINE OXIDE OR DIPHOSPHINE OXIDE
    3.
    发明申请
    HYDROGENATED NITRILE RUBBER CONTAINING PHOSPHINE OXIDE OR DIPHOSPHINE OXIDE 审中-公开
    含氢氧化镍或二氢氧化铁的加氢硝基橡胶

    公开(公告)号:US20160326272A1

    公开(公告)日:2016-11-10

    申请号:US15108990

    申请日:2014-12-29

    发明人: WERNER OBRECHT

    IPC分类号: C08C2/04 C08J3/24 C08C19/02

    摘要: Novel hydrogenated nitrile rubbers are provided, which, as well as having reduced contents of phosphines and/or diphosphines, include phosphine oxides and a specific content of halogens, and which enable access to vulcanizable mixtures and corresponding vulcanizates that possess improved moduli and compression set values and good values for heat buildup under dynamic stress. These novel hydrogenated nitrile rubbers are obtained by a specific production process, in the course of which the hydrogenated nitrile rubbers are reacted with at least one specific oxidizing agent.

    摘要翻译: 提供了新的氢化丁腈橡胶,其具有减少的膦和/或二膦的含量,包括氧化膦和特定含量的卤素,并且能够进入具有改进的模量和压缩永久变形值的可硫化混合物和相应的硫化橡胶 并且在动态应力下热积聚的良好价值。 这些新型氢化丁腈橡胶通过特定的制备方法获得,其中氢化丁腈橡胶与至少一种特定的氧化剂反应。

    Method for treatment of synthetic rubber products, a system for treatment, the resulting rubber products, and use of a method to reduce type IV allergenicity of rubber products
    4.
    发明授权
    Method for treatment of synthetic rubber products, a system for treatment, the resulting rubber products, and use of a method to reduce type IV allergenicity of rubber products 有权
    用于处理合成橡胶制品的方法,处理系统,所得橡胶制品以及使用减少橡胶制品的IV型过敏原的方法

    公开(公告)号:US09018341B2

    公开(公告)日:2015-04-28

    申请号:US14122064

    申请日:2012-05-24

    摘要: The present invention relates to a method of reducing type IV rubber allergy of synthetic rubber latex products caused by chemical residues remaining after manufacture of the synthetic rubber products by reducing levels of chemical residues found for said products, said method comprising the steps of: subjecting said products to a wash in a strong alkaline solution to remove the chemical residues remaining after manufacture of the rubber latex products, and a system for reducing type IV allergenicity of synthetic rubber products caused by chemical residues remaining after manufacture of the synthetic rubber latex products by reducing residual levels of chemical residues found for said products, and a product, such as a glove, manufactured from synthetic rubber latex processed in accordance with the method and/or using the system. Further the invention relates to a use of a method of subjecting products to said wash and raising the temperature to at least 100 C to remove the chemical residues remaining after manufacture of the synthetic rubber products.

    摘要翻译: 本发明涉及一种通过减少所述产品的化学残留物含量,在合成橡胶制品制造后残留的化学残留物引起的合成橡胶胶乳产品的IV型橡胶过敏的方法,所述方法包括以下步骤: 产品在强碱性溶液中洗涤以除去制造橡胶胶乳产品后残留的化学残留物,以及用于减少由合成橡胶胶乳产品制造后残留的化学残留物引起的合成橡胶产品的IV型过敏原的体系,通过减少 对于所述产品发现的残余水平的化学残留物,以及根据该方法和/或使用该系统由合成橡胶胶乳制造的产品,例如手套。 此外,本发明涉及使产品进行所述洗涤并将温度升至至少100℃的方法的用途,以去除合成橡胶产品制造后留下的化学残留物。

    Methods for purifying polymers using solid scavengers
    6.
    发明授权
    Methods for purifying polymers using solid scavengers 失效
    使用固体清除剂纯化聚合物的方法

    公开(公告)号:US07687601B2

    公开(公告)日:2010-03-30

    申请号:US11538339

    申请日:2006-10-03

    IPC分类号: C08F8/00 C08F6/02 C08C2/04

    摘要: Conductive polymers are purified using a solid scavenger. The solid scavengers include metal-scavenging functional groups linked to the surface of a particle support material. To improve the functionalization of the support material, the support materials are first treated with sulfuric acid or nitric acid before attaching the molecules containing the metal-scavenging functional groups. The solid scavengers used in the purification methods are more efficient at removing impurities in conductive polymers than existing scavengers.

    摘要翻译: 使用固体清除剂纯化导电聚合物。 固体清除剂包括连接到颗粒载体材料表面的金属清除官能团。 为了改善载体材料的功能化,首先在将含有金属清除功能基团的分子连接之前,用硫酸或硝酸处理载体材料。 净化方法中使用的固体清除剂在除去导电聚合物中的杂质比现有的清除剂更有效。

    Stabilization of siloxane terminated polymers
    7.
    发明授权
    Stabilization of siloxane terminated polymers 失效
    硅氧烷封端的聚合物的稳定化

    公开(公告)号:US5659056A

    公开(公告)日:1997-08-19

    申请号:US630298

    申请日:1996-04-10

    CPC分类号: C08C2/04 C08C19/44

    摘要: The present invention relates to a method of reducing hydrolysis and coupling of substituents of siloxane end capped polymers containing hydrolyzable substituents during contact with water. The Mooney viscosity of siloxane terminated polymers is stabilized during such contact by treating the polymer with a stabilizing amount of stabilizing agent selected from the group consisting of: an acid, an acyl halide, methane sulfonic acid, toluene sulfonic acid, sulfuryl chloride, thionylchloride, phosgene, carbon dioxide, sulfur dioxide, sulfur trioxide, SOCl.sub.2 and SO.sub.2 Cl.sub.2, prior to contacting the siloxane terminated polymer with water.

    摘要翻译: 本发明涉及在与水接触期间减少含有可水解取代基的硅氧烷封端聚合物的水解和偶联的方法。 硅烷封端的聚合物的门尼粘度在这种接触期间通过用稳定量的稳定剂处理聚合物而稳定,稳定剂选自:酸,酰卤,甲磺酸,甲苯磺酸,磺酰氯,亚硫酰氯, 在将硅氧烷封端的聚合物与水接触之前,将光气,二氧化碳,二氧化硫,三氧化硫,SOCl 2和SO 2 Cl 2。

    Selective hydrogenation of conjugated diolefin poylmers
    9.
    发明授权
    Selective hydrogenation of conjugated diolefin poylmers 失效
    共轭二烯烃聚合物的选择性氢化

    公开(公告)号:US5173537A

    公开(公告)日:1992-12-22

    申请号:US811219

    申请日:1991-12-20

    CPC分类号: C08C19/02 C08C2/04

    摘要: This is an improvement in a process for the hydrogenation of conjugated diolefin polymers which comprises polymerizing or copolymerizing at least one conjugated diolefin with an organo alkali metal polymerization initiator in a suitable solvent thereby creating a living polymer, terminating the polymerization by the addition of hydrogen, thereby generating an alkali metal hydride, and effecting selective hydrogenation of the unsaturated double bonds in the conjugated diolefin units of the terminated polymer by contacting the polymer, in the absence of hydrocarbon lithium and alkoxy lithium compounds, with hydrogen in the presence of at least one bis(cyclopentadienyl)titanium compound. The improvement comprises treating the polymer, before hydrogenation, with a reagent to increase catalyst activity, the reagent being such that it will react with the alkali metal hydride present in the polymer.