公开(公告)号：US12071569B2

公开(公告)日：2024-08-27

申请号：US17046091

申请日：2019-04-15

Applicant: SAINT-GOBAIN ISOVER

Inventor： Pierre Salomon ,  Edouard Obert

IPC: C09J167/04 ,  C03C25/321 ,  C03C25/323 ,  C08G63/40 ,  C08J5/04 ,  C08K3/32 ,  D04H1/4209 ,  D04H1/587 ,  D04H1/645 ,  D06M15/51

CPC classification number: C09J167/04 ,  C03C25/321 ,  C03C25/323 ,  C08G63/40 ,  C08J5/043 ,  C08K3/32 ,  D04H1/4209 ,  D04H1/587 ,  D04H1/645 ,  D06M15/51 ,  C08J2303/02 ,  C08J2305/00 ,  C08J2367/04 ,  C08J2397/00

Abstract: The present invention relates to a thermosetting binder composition containing water and a water-soluble oligomeric ester of at least one saccharide chosen from reducing sugars, non-reducing sugars and hydrogenated sugars, the hydrogenated sugars being chosen from the group consisting of erythritol, arabitol, xylitol, sorbitol, mannitol, iditol, maltitol, isomaltitol, lactitol, cellobitol, palatinitol, maltotritol and hydrogenation products of hydrolyzates of starch or of lignocellulose materials, and of at least one polycarboxylic acid, the binder composition having a dry matter content of between 50% and 80% by weight, the water-soluble oligomeric ester representing at least 80% by weight, preferably at least 90% by weight, of the cry matter content of the thermosetting binder composition, and the thermosetting binder composition containing less than 10% by weight, preferably less than 5% by weight, with respect to its dry matter content, of free sorbitol.
It also relates to the use of such a binder composition for the manufacture of a product based on mineral or organic fibers which are bonded by an insoluble organic binder.

公开(公告)号：US11946582B2

公开(公告)日：2024-04-02

申请号：US16405566

申请日：2019-05-07

Applicant: KNAUF INSULATION SPRL ,  KNAUF INSULATION, INC.

Inventor： Carl Hampson

IPC: F16L59/02 ,  C03C13/06 ,  C03C25/32 ,  C03C25/321 ,  C03C25/34 ,  C08H8/00 ,  C08K5/17 ,  C08K7/14 ,  C08L97/02 ,  C08L99/00 ,  C08L101/02 ,  C08L101/06 ,  C09D197/02 ,  C09D199/00 ,  C09D201/02 ,  C09D201/06 ,  C09K3/00 ,  D04H1/4209 ,  D04H1/4218 ,  D04H1/64 ,  E04B1/76

CPC classification number: F16L59/028 ,  C03C13/06 ,  C03C25/32 ,  C03C25/321 ,  C03C25/34 ,  C08H8/00 ,  C08K5/175 ,  C08K7/14 ,  C08L97/02 ,  C08L99/00 ,  C08L101/025 ,  C08L101/06 ,  C09D197/02 ,  C09D199/00 ,  C09D201/025 ,  C09D201/06 ,  C09K3/00 ,  D04H1/4209 ,  D04H1/4218 ,  D04H1/64 ,  E04B1/7658 ,  E04B1/7662

Abstract: An un-reacted substantially formaldehyde free curable binder solution for binding loose matter consists essentially of a solution obtainable by dissolving a reducing sugar, an ammonium salt acid precursor, optionally a carboxylic acid or a precursor thereof and optionally ammonia in water.

公开(公告)号：US11814761B2

公开(公告)日：2023-11-14

申请号：US16771354

申请日：2018-12-10

Applicant: SAINT-GOBAIN ISOVER

Inventor： Marie Savonnet ,  Victor Maruani ,  Eric Framery ,  Bruno Andrioletti

IPC: C03C25/00 ,  D04H1/587 ,  C03C13/06 ,  C03C25/26 ,  C03C25/321 ,  C03C25/34 ,  C09D5/00 ,  D04H1/4218

CPC classification number: D04H1/587 ,  C03C13/06 ,  C03C25/26 ,  C03C25/321 ,  C03C25/34 ,  C09D5/00 ,  D04H1/4218 ,  C03C2213/00

Abstract: The present invention relates to a process for producing insulating products based on mineral fibers, in particular on mineral wool, comprising



providing a first binder composition containing

(a) from 50% to 85% by weight of water, preferably from 70 to 82% of water
(b) from 10% to 45% by weight, preferably 15 to 35% by weight of a saccharide component containing sucrose,
(c) from 3% to 15% by weight, preferably from 5 to 12% by weight of one or more ammonium salts or primary amine salts of an acid,


preparing a second binder composition comprising the dilution of the first aqueous binder composition with water to a solids content of between 3 and 7% by weight,
applying the second binder composition to mineral fibers,
forming an assembly of mineral fibers coated with the second binder composition, and
heating the assembly of coated mineral fibers so as to form an assembly of mineral fibers bound by an insoluble binder,

said process being characterized in that the first aqueous binder composition has a pH of less than 5.5, in that the ammonium salt or primary amine salt is a salt of strong acid or a salt of an acid having a pKa of less than or equal to 2.2, and in that the first and second binder compositions are devoid of salts of weak acids having at least a pKa of between 2.5 and 6.9.

公开(公告)号：US20230288013A1

公开(公告)日：2023-09-14

申请号：US18199966

申请日：2023-05-21

Applicant: KNAUF INSULATION SPRL ,  KNAUF INSULATION, INC.

Inventor： Carl Hampson ,  Gert Mueller ,  Charles Appley

IPC: F16L59/02 ,  E04B1/76 ,  C09D199/00 ,  C09D201/02 ,  C09D197/02 ,  D04H1/64 ,  C08L97/02 ,  C03C25/32 ,  D04H1/4218 ,  D04H1/4209 ,  C03C25/34 ,  C08H8/00 ,  C09K3/00 ,  C08L99/00 ,  C08K5/17 ,  C03C25/321 ,  C08L101/02 ,  C08K7/14 ,  C09D201/06 ,  C08L101/06 ,  C03C13/06

CPC classification number: F16L59/028 ,  E04B1/7662 ,  C09D199/00 ,  C09D201/025 ,  C09D197/02 ,  D04H1/64 ,  C08L97/02 ,  C03C25/32 ,  D04H1/4218 ,  D04H1/4209 ,  E04B1/7658 ,  C03C25/34 ,  C08H8/00 ,  C09K3/00 ,  C08L99/00 ,  C08K5/175 ,  C03C25/321 ,  C08L101/025 ,  C08K7/14 ,  C09D201/06 ,  C08L101/06 ,  C03C13/06

Abstract: A method of manufacturing a mineral fibre thermal insulation product comprises the sequential steps of:



Forming mineral fibres from a molten mineral mixture;
Spraying a substantially formaldehyde free binder solution on to the mineral fibres, the binder solution comprising: a reducing sugar, an acid precursor derivable from an inorganic salt and a source of nitrogen;
Collecting the mineral fibres to which the binder solution has been applied to form a batt of mineral fibres; and
Curing the batt comprising the mineral fibres and the binder which is in contact with the mineral fibres by passing the batt through a curing oven so as to provide a batt of mineral fibres held together by a substantially water insoluble cured binder.

公开(公告)号：US20230109800A1

公开(公告)日：2023-04-13

申请号：US18074643

申请日：2022-12-05

Applicant: KNAUF INSULATION SPRL ,  KNAUF INSULATION, INC.

Inventor： Carl Hampson ,  Gert Mueller ,  Charles Appley

IPC: F16L59/02 ,  C08L99/00 ,  C08L101/06 ,  D04H1/4218 ,  C09D201/06 ,  C09D199/00 ,  E04B1/76 ,  C03C25/32 ,  C03C25/34 ,  C08L101/02 ,  C09D197/02 ,  C09D201/02 ,  C03C25/321 ,  C08H8/00 ,  C08L97/02 ,  D04H1/4209 ,  D04H1/64 ,  C09K3/00 ,  C08K5/17 ,  C03C13/06 ,  C08K7/14

Abstract: A method of manufacturing a mineral fibre thermal insulation product comprises the sequential steps of: Forming mineral fibres from a molten mineral mixture;
Spraying a substantially formaldehyde free binder solution on to the mineral fibres, the binder solution comprising: a reducing sugar, an acid precursor derivable from an inorganic salt and a source of nitrogen;
Collecting the mineral fibres to which the binder solution has been applied to form a batt of mineral fibres; and
Curing the batt comprising the mineral fibres and the binder which is in contact with the mineral fibres by passing the batt through a curing oven so as to provide a batt of mineral fibres held together by a substantially water insoluble cured binder.

公开(公告)号：US11590747B2

公开(公告)日：2023-02-28

申请号：US16301232

申请日：2017-05-11

Applicant: Rockwool International A/S

Inventor： Thomas Hjelmgaard ,  Oskar Meres ,  Bent Jacobsen

IPC: B32B37/12 ,  C09J101/28 ,  C09J103/02 ,  C09J105/04 ,  C09J105/06 ,  C09J189/06 ,  D04H1/4218 ,  D04H1/74 ,  C09J105/12 ,  B32B5/12 ,  B32B5/26 ,  C08L5/12 ,  C03C25/26 ,  B32B19/04 ,  B32B15/14 ,  C09J105/00 ,  B32B37/14 ,  D04H1/413 ,  D04H1/64 ,  D04H3/002 ,  E04B1/94 ,  C03C13/06 ,  C08L1/28 ,  C08L3/02 ,  D04H3/004 ,  E04B1/88 ,  C09J189/00 ,  C08J5/04 ,  C03C25/32 ,  C09J11/06 ,  D04H1/587 ,  E04B1/74 ,  C08L89/06 ,  D04H1/4266 ,  D04H1/724 ,  B32B7/12 ,  B32B37/18 ,  B32B38/00 ,  C03C25/321 ,  C03C25/328 ,  C09J5/00 ,  D04H1/4209 ,  D04H1/593 ,  E04B1/80 ,  E04C2/284 ,  E04D3/35 ,  E04F13/08 ,  E04B1/76 ,  C12N9/06 ,  C12N9/02 ,  C12N9/08 ,  C12N9/10 ,  C12N9/90

Abstract: A method and a mineral wool product include a multiple of lamellae, such as a sandwich panel core. The product includes a plurality of lamellae cut from a mineral wool web, and bonded together by applying an adhesive on the surfaces of two adjacent lamellae to form a web-like product, wherein the adhesive comprises at least one hydrocolloid.

公开(公告)号：US20210348013A1

公开(公告)日：2021-11-11

申请号：US17276841

申请日：2019-10-01

Applicant: SAINT-GOBAIN ADFORS

Inventor： Bohuslav MIKULECKY ,  Lukás KULHAVY ,  Matej CESKA

IPC: C09D103/02 ,  C03C25/321 ,  D06N3/06 ,  D06N3/00 ,  C09D5/02

Abstract: The invention is drawn to a method of coating a glass fiber textile comprising the following steps: —Preparing an aqueous coating composition comprising (a) 5 to 95% by weight, with respect to the total weight of (a) and (b), of a synthetic polymer or oligomer dissolved or dispersed in the aqueous coating composition, and (b) 5 to 95% by weight, with respect to the total weight of (a) and (b), of a dextrin exhibiting a weight-average molecular weight ranging from 250 000 to 2 000 000 Da and a solubility, measured according to a test A, ranging from 50 to 85%, —Applying said aqueous coating composition to a glass fiber textile, thereby obtaining a wet-coated glass fiber textile, —Submitting the wet-coated glass fiber textile to a step of drying and/or curing thereby obtaining a glass fiber textile coated with a water-insoluble polymer coating.

公开(公告)号：US11142631B2

公开(公告)日：2021-10-12

申请号：US16737699

申请日：2020-01-08

Applicant: JOHNS MANVILLE

Inventor： Kiarash Alavi

IPC: C08K7/14 ,  D04H1/587 ,  D04H1/64 ,  C03C25/321 ,  B05D7/24 ,  C07H17/02 ,  F16L59/02 ,  C08L1/02 ,  C08L3/02

Abstract: Fiber-containing composites are described that contain woven or non-woven fibers, and a cured binder formed from a binder composition that includes (1) a reducing sugar and (2) a crosslinking agent that includes a reaction product of a urea compound and a polycarbonyl compound. Exemplary reaction products for the crosslinking agent may include the reaction product of urea and an α,β-bicarbonyl compound or an α,γ-bicarbonyl compound. Exemplary fiber-containing composites may include fiberglass insulation.

公开(公告)号：US20200340156A1

公开(公告)日：2020-10-29

申请号：US16771354

申请日：2018-12-10

Applicant: SAINT-GOBAIN ISOVER

Inventor： Marie SAVONNET ,  Victor MARUANI ,  Eric FRAMERY ,  Bruno ANDRIOLETTI

IPC: D04H1/587 ,  C03C13/06 ,  C09D5/00 ,  D04H1/4218 ,  C03C25/26 ,  C03C25/321 ,  C03C25/34

Abstract: The present invention relates to a process for producing insulating products based on mineral fibers, in particular on mineral wool, comprising providing a first binder composition containing (a) from 50% to 85% by weight of water, preferably from 70 to 82% of water (b) from 10% to 45% by weight, preferably 15 to 35% by weight of a saccharide component containing sucrose, (c) from 3% to 15% by weight, preferably from 5 to 12% by weight of one or more ammonium salts or primary amine salts of an acid, preparing a second binder composition comprising the dilution of the first aqueous binder composition with water to a solids content of between 3 and 7% by weight, applying the second binder composition to mineral fibers, forming an assembly of mineral fibers coated with the second binder composition, and heating the assembly of coated mineral fibers so as to form an assembly of mineral fibers bound by an insoluble binder, said process being characterized in that the first aqueous binder composition has a pH of less than 5.5, in that the ammonium salt or primary amine salt is a salt of strong acid or a salt of an acid having a pKa of less than or equal to 2.2, and in that the first and second binder compositions are devoid of salts of weak acids having at least a pKa of between 2.5 and 6.9.

公开(公告)号：US20200318351A1

公开(公告)日：2020-10-08

申请号：US16904535

申请日：2020-06-17

Applicant: Knauf Insulation SPRL ,  Knauf Insulation, Inc.

Inventor： Roger JACKSON ,  Tony AINDOW ,  George BAYBUTT

IPC: E04C2/16 ,  E04B1/80 ,  C03C25/321

Abstract: A high density mineral fibre board having a formaldehyde free binder has acceptable strength and good dimensional stability.