Abstract:
A catalyst system for removing one or more components from a fluid stream includes a binder layer and a plurality of catalyst structures affixed to, and protruding from, the binder layer such that the catalyst structure surface is directly exposed to the fluid stream. Methods for preparing a catalyst system, and for selectively removing components from a fluid stream via a catalyst system are also disclosed.
Abstract:
An automotive exhaust gas noise attenuating device which treats exhaust gas emissions, the device having (a) a ceramic substrate for passing an automotive exhaust stream therethrough, the substrate having (i) an inlet face and an outlet face with a plurality of aligned thin porous channel walls defining channels extending between the faces, and (ii) a three dimensional aspect relationship where depth of the substrate between said faces is generally the same as either the height of width of a face, the substrate having first alternates of the channels blocked at the outlet face and second alternates of the channels blocked at the inlet face to promote lateral flow through the porous walls between each first channel and a multiple of second alternate channels while permitting laminar flow within such channels; (b) hollow shell pellets packed into and trapped in at least some of the first alternate channels which cooperate to define porous Darcy flow surfaces therein; and (c) dolomitic carbonate and catalyzing material on or in the surfaces of the channel walls and Darcy flow surfaces.
Abstract:
Nitrogen oxides contained in an exhaust gas emitted from a lean-burn engine-mounted internal combustion engines are eliminated with a high efficiency. In an exhaust gas purification apparatus and process for eliminating nitrogen oxides contained in a combustion exhaust gas emitted from an internal combustion engine with a reducing gas such as carbon monoxide, hydrocarbons, etc. contained in the exhaust gas in the presence of a catalyst, a catalyst comprising all of Rh, Pt and Pd, at least one member selected from alkali metals and alkaline earth metals, and Mn or its compound, supported on a porous carrier is used.
Abstract:
A catalytic converter (9) is interposed in an exhaust passage (3) of an internal combustion engine (1). In the converter (9), a plurality of carriers (21A-21D) are disposed in series with gaps (G1-G3). Each carrier (21A-21D) comprises a hydrocarbon trapping layer (25), a three-way catalyst layer (26) and a number of passages (24) facing the three-way catalyst layer (26). The gaps (G1-G3) interrupts heat transfer between the carriers in order to retard temperature increase in the hydrocarbon trapping layer (25) and promotes a turbulence in exhaust gas flow in the converter (9) in order to homogenize the exhaust gas dispersion in a radial direction, thereby enhancing the hydrocarbon purification performance of the converter (9).
Abstract:
A hydrocarbon trapping layer (25) is formed by coating a hydrocarbon trapping material onto a carrier (21A). A number of exhaust gas passages (34) are formed in the carrier (21A) and a plurality of slits (22) are formed on the carrier (21A) to cross the passages (24) in a transverse orientation. The slits (22) delay temperature increases in the downstream hydrocarbon trapping layer (25) and delay the release of trapped hydrocarbons therefrom. This is due to blocking the transmission of heat to the downstream hydrocarbon trapping layer (25) from the upstream hydrocarbon trapping layer (25). The slits (22) further produce a turbulent flow in the flow of exhaust gas and promote diffusion of exhaust gas over the entire surface of the carrier (21A).
Abstract:
The present invention relates to a layered catalyst composite of the type generally referred to as a three-way conversion catalyst having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides. The structure of the layered catalyst composite of the present invention is designed wherein there are three layers in conjunction with a carrier: a first layer deposited on the carrier and comprising a high surface area refractory metal oxide; a second layer deposited on the first layer and comprising palladium and/or platinum deposited on a high surface area refractory metal oxide, and having substantially no oxygen storage components; and a third layer deposited on the second layer and comprising platinum and/or rhodium as well as an oxygen storage component, deposited on a high surface area refractory metal oxide.
Abstract:
A rolling regeneration diesel particulate filter and filtering process that utilizes NO produced in the process to generate additional amounts of NO2 than the NO2 produced by the diesel engine. The process includes the step of flowing diesel engine combustion exhaust through a filter system including a first section and a second section. The first section is positioned upstream of the second section with respect to the direction of the flow of the diesel engine exhaust through the filter. The first section includes a foam constructed and arranged to trap carbon-based particulates in the exhaust. A first catalyst is carried by the foam to promote the conversion of NO in the exhaust from the diesel engine to NO2. The first catalyst also promotes the reaction of NO2 with at least a portion of the carbon-based particulates trapped by the foam to form CO and NO. The first catalyst carried by the foam also promotes the oxidation of CO to CO2, and the oxidation of NO, generated by the reaction of NO2 with carbon, to generate additional amounts of NO2. The additional amounts of NO2 are also utilized to oxidize the carbon-based particulates. The second section of the filter system includes a wall flow monolith having a plurality of through hole cells formed therein running the longitudinal length of the monolith. The monolith is constructed and arranged to trap particulates in the exhaust and to promote the reaction of NO2 and carbon to produce NO and CO. The ceramic foam may also be received in and surrounded by the wall flow filter.
Abstract:
An end cone for an exhaust emission control device is provided. The end cone comprises an outer shell and an end cone insulator. The outer shell has an inner surface. The end cone insulator comprises insulation and binder defining a passage therethrough. The end cone insulator has a first surface being disposed adjacent to the inner surface, and a second surface, at least a portion of which is exposed to the passage.
Abstract:
The present invention relates to an article comprising a catalyst composition and a method useful for the removal of NOx and SOx contaminants from a gaseous stream, especially gaseous streams containing sulfur oxide contaminants. More specifically, the present invention is concerned with catalysts of the type generally referred to as nullclose coupled catalystsnull which are designed to reduce pollutants in engine exhaust emissions during engine cold start conditions. The article comprises a lean burn gasoline engine having an exhaust outlet, an upstream section having a close coupled catalyst composite in communication with the exhaust outlet, and a downstream section. The upstream close coupled catalyst composite comprises a first support; a first platinum group component; and a SOx sorbent component selected from the group consisting of oxides and mixed oxides of barium, lanthanum, magnesium, manganese, neodymium, praseodymium, and strontium. The downstream section comprises a second support; a second platinum group component; and a NOx sorbent component. The upstream section has substantially no components adversely affecting three-way conversion under operating conditions.
Abstract:
A cell structure mounting container comprises a cell structure stored within a metal container. The cell structure is held within the metal container by providing a compressed resilience material having cushioning characteristics between the cell structure and the metal container in a compressed state. The compressed resilience material is a heat-resistant and low-expansion material containing ceramic fibers or ceramic fibers and heat-resistant metal fibers. Accordingly, compression characteristics which do not greatly fluctuate within the usage temperature range are obtained, the compression force acting on the periphery portion of the cell structure does not change greatly, and further, the compression force acts essentially uniformly on the periphery portion of the cell structure. Thus, a cell structure mounting container and an assembly thereof can be provided wherein there is little change in compressive pressure on the cell structure within the metal container within the usage temperature range of the catalytic converter or the like, and the compressive pressure distribution is uniform, thereby preventing damage to the cell structure.