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公开(公告)号：US12077455B2
公开(公告)日：2024-09-03
申请号：US17436780
申请日：2020-03-06
发明人： Jan Romanski , Damian Jagleniec , Marcin Karbarz
IPC分类号： C02F1/28 , C02F1/68 , C07D323/00 , G01N21/78 , G21F9/12 , G21F9/16 , C02F101/00 , C02F101/10 , C02F101/16
CPC分类号： C02F1/285 , C02F1/683 , C07D323/00 , G01N21/78 , G21F9/12 , G21F9/162 , C02F2101/006 , C02F2101/101 , C02F2101/163
摘要： A receptor for the simultaneous removal of oxoanions and their counterions from aqueous phase, particularly containing radioactive wastes, containing amide groups specifically coordinating the oxoanions, as well as moieties specifically coordinating cations, according to the present invention is characterised in that it contains within one molecule domains binding oxoanions and domains binding cations, preferably adapting a molecular structure of a general formula: (I) wherein Z this is a group containing crown ether, preferably a benzocrown group, X is any substituent, including the Y—Z grouping, and Y is any substituent or 0 (i.e. a direct bond between N and Z), where the oxoanion binding domain is a squaramide unit coordinating the oxoanions through amide groups, and squaramide contains additional substituents that increase or decrease the acidity of its amide protons, compared to unsubstituted squaramide, whereas the counter ion binding domain is a crown ether of a size adjusted to the type of binding cation, which forms part of at least one of the aforementioned substituents of squaramide, where the receptor has the ability to remove oxoanions and their counterions from aqueous phase to another water-immiscible phase, preferably to organic phase, and has the ability to form soluble complexes in at least one of the aforementioned phases. The invention considers also a method of removing oxoanions in the form of inorganic salts from aqueous phase, using receptors of the invention in the form of organic molecules containing amide groups, according to the invention is characterised in that it uses the aforementioned receptors for simultaneous binding of oxoanions and their counterions in aqueous phase, preferably acidic when using the receptor with substituents increasing acidity of squaramide protons, or alkaline when using the receptor with substituents decreasing acidity of squaramide protons. A sensor for detecting oxoanions according to the invention is characterised in that it uses the aforementioned receptors, dissolved or suspended in an organic solvent or in a mixture of organic solvents, forming coloured complexes in contact with the phase containing given oxoanions. The preparation for removing oxoanions from aqueous solutions, particularly containing radioactive waste at the stage preceding their disposal by vitrification, is characterised in that it contains the receptor according to the invention, dissolved or suspended in the water-immiscible phase, and the appropriate amount of counterion facilitating extraction. A process of utilisation of aqueous solutions by vitrification, particularly solutions containing radioactive waste, is characterised in that vitrification step is preceded by the step of oxoanions removal, preferably sulfate(VI) anions, by the method according to the invention, using the receptors according to the invention, preferably using the preparation according to the invention.
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公开(公告)号：US10020085B2
公开(公告)日：2018-07-10
申请号：US15134818
申请日：2016-04-21
申请人： Kurion, Inc.
发明人： Mark S. Denton
摘要： Apparatuses, processes and methods for the separation, isolation, or removal of radioactive isotopes from liquid radioactive waste, these processes and methods employing a plurality of microspheres. In some embodiments, the processes and methods further include the vitrification of the separated isotopes, generally with the plurality of microspheres. Vitrification is often a step in a larger scheme of preparing the radioactive isotopes for long-term storage or other disposition.
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3.发明授权公开(公告)号：US09978470B2
公开(公告)日：2018-05-22
申请号：US14967935
申请日：2015-12-14
申请人： Artem V. Gelis , Andrew J. Castiglioni , Dennis Kelley , Anatoliy Galkin , Nadezhda Bachilova , Alexandr Klepikov , Alexandr Blynskiy , Turgynbek Tolebayev
发明人： Artem V. Gelis , Andrew J. Castiglioni , Dennis Kelley , Anatoliy Galkin , Nadezhda Bachilova , Alexandr Klepikov , Alexandr Blynskiy , Turgynbek Tolebayev
IPC分类号： G21F9/16
摘要： A method for immobilizing liquid radioactive waste is provided, the method having the steps of mixing waste with polymer to form a non-liquid waste; contacting the non-liquid waste with a solidifying agent to create a mixture, heating the mixture to cause the polymer, waste, and filler to irreversibly bind in a solid phase, and compressing the solid phase into a monolith. The invention also provides a method for immobilizing liquid radioactive waste containing tritium, the method having the steps of mixing liquid waste with polymer to convert the liquid waste to a non-liquid waste, contacting the non-liquid waste with a solidifying agent to create a mixture, heating the mixture to form homogeneous, chemically stable solid phase, and compressing the chemically stable solid phase into a final waste form, wherein the polymer comprises approximately a 9:1 weight ratio mixture of styrene block co-polymers and cross linked co-polymers of acrylamides.
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4.发明申请公开(公告)号：US20170169907A1
公开(公告)日：2017-06-15
申请号：US14967935
申请日：2015-12-14
申请人： Artem V. Gelis , Andrew J. Castiglioni , Dennis Kelly , Anatoliy Galkin , Nadezhda Bachilova , Alexandr Klepikov , Alexandr Blynskiy , Turgynbek Tolebayev
发明人： Artem V. Gelis , Andrew J. Castiglioni , Dennis Kelly , Anatoliy Galkin , Nadezhda Bachilova , Alexandr Klepikov , Alexandr Blynskiy , Turgynbek Tolebayev
IPC分类号： G21F9/16
摘要： A method for immobilizing liquid radioactive waste is provided, the method having the steps of mixing waste with polymer to form a non-liquid waste; contacting the non-liquid waste with a solidifying agent to create a mixture, heating the mixture to cause the polymer, waste, and filler to irreversibly bind in a solid phase, and compressing the solid phase into a monolith. The invention also provides a method for immobilizing liquid radioactive waste containing tritium, the method having the steps of mixing liquid waste with polymer to convert the liquid waste to a non-liquid waste, contacting the non-liquid waste with a solidifying agent to create a mixture, heating the mixture to form homogeneous, chemically stable solid phase, and compressing the chemically stable solid phase into a final waste form, wherein the polymer comprises approximately a 9:1 weight ratio mixture of styrene block co-polymers and cross linked co-polymers of acrylamides.
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公开(公告)号：US20160276049A1
公开(公告)日：2016-09-22
申请号：US15059709
申请日：2016-03-03
发明人： Hirofumi OKABE , Masaaki Kaneko , Tatsuaki Sato , Tetsuo Motohashi , Toshiaki Sugimori , Rie Arai , Yohei Sato
CPC分类号： G21F9/165 , C04B28/04 , C04B40/0039 , C04B2111/00767 , G21F9/06 , G21F9/08 , G21F9/162
摘要： A method for processing a radioactive liquid waste containing boron of the present invention includes: a molar ratio control step of adding an alkali metal or an alkali metal compound to a radioactive liquid waste containing boron to control an alkali metal/boron molar ratio in the radioactive liquid waste to be 0.8 or more; a drying step of drying the radioactive liquid waste having the controlled molar-ratio using a dryer to form a powdered waste; a dissolving step of mixing the powdered waste with kneading water to prepare a solution; and a kneading step of adding a hydraulic inorganic solidifying material to the solution, and kneading the hydraulic inorganic solidifying material and the solution for solidification.
摘要翻译： 本发明的含有硼的放射性废液处理方法包括：将摩尔比控制步骤，将碱金属或碱金属化合物加入到含硼的放射性废液中以控制放射性的碱金属/硼的摩尔比 液体废物为0.8以上; 干燥步骤，使用干燥器干燥具有受控摩尔比的放射性废液，以形成废粉; 将粉碎废料与捏合水混合以制备溶液的溶解步骤; 以及向该溶液中添加水硬性无机固化材料并捏合该水硬性无机固化材料和固化溶液的捏合步骤。
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公开(公告)号：US09437338B2
公开(公告)日：2016-09-06
申请号：US14323670
申请日：2014-07-03
发明人： Akio Sayano , Shohei Kawano , Yoshiyuki Kawaharada , Masamichi Obata , Hirotada Hayashi , Yusuke Nohara
摘要： A solidification method of radioactive waste is provided, including kneading a binder and an inorganic adsorbent to obtain a kneaded object, the in organic adsorbent included radionuclides; extruding the kneaded object to obtain an extruded material object; cutting the extruded material object to obtain at least one extruded material block; and firing the at least one extruded material block to solidify the at least one extruded material block.
摘要翻译： 提供放射性废物的固化方法，包括捏合粘合剂和无机吸附剂以获得捏合物，有机吸附剂包括放射性核素; 挤出捏合物以获得挤出物料; 切割挤压材料物体以获得至少一个挤压材料块; 以及烧制所述至少一个挤压材料块，以固化所述至少一个挤压材料块。
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7.发明授权Vitrified chemically bonded phosphate ceramics for immobilization of radioisotopes 有权用于固定放射性同位素的玻璃化化学键合磷酸盐陶瓷公开(公告)号：US09305672B2
公开(公告)日：2016-04-05
申请号：US14291980
申请日：2014-05-30
发明人： Arun S. Wagh
CPC分类号： G21F9/305 , C03C4/0042 , C03C14/006 , C03C14/008 , C03C2214/14 , C03C2214/20 , C04B35/447 , C04B35/62625 , C04B35/62685 , C04B2235/3201 , C04B2235/3206 , C04B2235/3418 , C04B2235/3454 , C04B2235/365 , C04B2235/447 , G21F9/162
摘要： A method of immobilizing a radioisotope and vitrified chemically bonded phosphate ceramic (CBPC) articles formed by the method are described. The method comprises combining a radioisotope-containing material, MgO, a source of phosphate, and optionally, a reducing agent, in water at a temperature of less than 100° C. to form a slurry; curing the slurry to form a solid intermediate CBPC article comprising the radioisotope therefrom; comminuting the intermediate CBPC article, mixing the comminuted material with glass frits, and heating the mixture at a temperature in the range of about 900 to about 1500° C. to form a vitrified CBPC article comprising the radioisotope immobilized therein.
摘要翻译： 描述了通过该方法形成的放射性同位素和玻璃化化学键合磷酸盐陶瓷（CBPC）制品的固定方法。 该方法包括在低于100℃的温度下将含放射性同位物的材料，MgO，磷酸盐源和任选的还原剂混合在水中以形成浆料; 固化浆料以形成包含其中的放射性同位素的固体中间体CBPC制品; 粉碎中间体CBPC制品，将粉碎的材料与玻璃料混合，并在约900至约1500℃的温度范围内加热混合物以形成包含固定在其中的放射性同位素的玻璃化CBPC制品。
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8.发明申请VITRIFIED CHEMICALLY BONDED PHOSPHATE CERAMICS FOR IMMOBILIZATION OF RADIOISOTOPES 有权用于固定放射性物质的化学化学粘结磷酸盐陶瓷公开(公告)号：US20150348661A1
公开(公告)日：2015-12-03
申请号：US14291980
申请日：2014-05-30
发明人： Arun S. WAGH
IPC分类号： G21F9/30 , C03C4/00 , C03C14/00 , G21F9/16 , C04B35/447
CPC分类号： G21F9/305 , C03C4/0042 , C03C14/006 , C03C14/008 , C03C2214/14 , C03C2214/20 , C04B35/447 , C04B35/62625 , C04B35/62685 , C04B2235/3201 , C04B2235/3206 , C04B2235/3418 , C04B2235/3454 , C04B2235/365 , C04B2235/447 , G21F9/162
摘要： A method of immobilizing a radioisotope and vitrified chemically bonded phosphate ceramic (CBPC) articles formed by the method are described. The method comprises combining a radioisotope-containing material, MgO, a source of phosphate, and optionally, a reducing agent, in water at a temperature of less than 100° C. to form a slurry; curing the slurry to form a solid intermediate CBPC article comprising the radioisotope therefrom; comminuting the intermediate CBPC article, mixing the comminuted material with glass frits, and heating the mixture at a temperature in the range of about 900 to about 1500° C. to form a vitrified CBPC article comprising the radioisotope immobilized therein.
摘要翻译： 描述了通过该方法形成的放射性同位素和玻璃化化学键合磷酸盐陶瓷（CBPC）制品的固定方法。 该方法包括在低于100℃的温度下将含放射性同位物的材料，MgO，磷酸盐源和任选的还原剂混合在水中以形成浆料; 固化浆料以形成包含其中的放射性同位素的固体中间体CBPC制品; 粉碎中间体CBPC制品，将粉碎的材料与玻璃料混合，并在约900至约1500℃的温度范围内加热混合物以形成包含固定在其中的放射性同位素的玻璃化CBPC制品。
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公开(公告)号：US20150252303A1
公开(公告)日：2015-09-10
申请号：US13801493
申请日：2013-03-13
CPC分类号： C11D3/32 , B08B3/08 , B08B3/12 , C11D1/28 , C11D3/042 , C11D3/046 , C11D3/048 , C11D3/065 , C11D3/222 , C11D3/26 , G21F9/002 , G21F9/162 , G21F9/167
摘要： A composition of matter includes water, at least one acid, at least one surfactant, at least one fluoride salt, and ammonium nitrate. A method of decontaminating a surface includes exposing a surface to such a composition and removing the composition from the surface. Other compositions of matter include water, a fatty alcohol ether sulfate, nitrilotriacetic acid, at least one of hydrochloric acid and nitric acid, sodium fluoride, potassium fluoride, ammonium nitrate, and gelatin.
摘要翻译： 物质组合物包括水，至少一种酸，至少一种表面活性剂，至少一种氟化物盐和硝酸铵。 净化表面的方法包括将表面暴露于这种组合物并从表面除去组合物。 物质的其它组合物包括水，脂肪醇醚硫酸盐，次氮基三乙酸，盐酸和硝酸中的至少一种，氟化钠，氟化钾，硝酸铵和明胶。
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公开(公告)号：US20150129504A1
公开(公告)日：2015-05-14
申请号：US14080311
申请日：2013-11-14
IPC分类号： C02F1/28
CPC分类号： C02F1/281 , B01J20/10 , B01J20/12 , B01J20/186 , B01J20/3204 , B01J20/3251 , B01J20/3259 , C02F1/288 , C02F2101/006 , C02F2101/12 , C02F2103/06 , G21F9/04 , G21F9/162
摘要： Methods are described for the removal of highly soluble radioactive anions, e.g., radioactive technetium and/or radioiodide, from an aqueous solution. The methods utilize a sequestering agent that includes an organoclay, i.e., a clay with an intercalated cationic quaternary amine, as a sorbent for highly soluble radioactive anions that are present within an aqueous solution. In exemplary embodiments, the method can be utilized to treat aqueous waste at a nuclear power facility or to treat a groundwater contamination site or a soil or sediment contaminated site.
摘要翻译： 描述了从水溶液中去除高度可溶的放射性阴离子，例如放射性锝和/或放射性碘的方法。 该方法利用包含有机粘土的螯合剂，即具有插层阳离子季胺的粘土作为存在于水溶液中的高度可溶性放射性阴离子的吸附剂。 在示例性实施例中，该方法可用于处理核电设施处的含水废物或处理地下水污染场所或土壤或沉积物污染场地。
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