Direct positive type silver halide photographic material comprising a
mixture of dyes
    1.
    发明授权
    Direct positive type silver halide photographic material comprising a mixture of dyes 失效
    包含染料混合物的直接正型卤化银照相材料

    公开(公告)号:US5547828A

    公开(公告)日:1996-08-20

    申请号:US373404

    申请日:1995-01-17

    IPC分类号: G03C1/485 G03C1/36

    CPC分类号: G03C1/4853 Y10S430/141

    摘要: A direct positive type silver halide photographic material is described, which contains at least one compound represented by the following formula (I) and at least one cyanine dye having a pyrazolo[5,1-b]quinazolone nucleus and a cyanine heterocycle nucleus, wherein a carbon atom at 3-position of the pyrazolo[5,1-b]quinazolone nucleus is bonded through a four-methine chain to an atom at the 2-position or 4-position of the cyanine heterocycle nucleus, provided that the 4-position is possible only when the cyanine heterocycle nucleus is a quinoline or pyridine nucleus: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group, an aryl group or a heterocyclic group, which may be substituted; V.sub.1, V.sub.2, V.sub.3, V.sub.4, V.sub.5, V.sub.6, V.sub.7 and V.sub.8 each represents a hydrogen atom or a monovalent substituent; L.sub.1, L.sub.2 and L.sub.3 each represents a substituted or unsubstituted methine group; M.sub.1 represents a charge-neutralizing counter ion; and m.sub.1 is a number of 0 or larger necessary for intramolecular charge neutralization.

    摘要翻译: 描述了直接正型卤化银照相材料,其包含至少一种由下式(I)表示的化合物和至少一种具有吡唑并[5,1-b]喹唑啉酮核和花青杂环核的花青染料,其中 吡唑并[5,1-b]喹唑啉酮核的3-位上的碳原子通过四次甲基链键合到花青杂环核的2-位或4-位的原子,条件是4- 位置可能只有当花青杂环核是喹啉或吡啶核时:其中R 1,R 2,R 3和R 4各自表示可以被取代的烷基,芳基或杂环基; V1,V2,V3,V4,V5,V6,V7和V8各自表示氢原子或一价取代基; L1,L2和L3各自表示取代或未取代的次甲基; M1表示电荷中和反离子; m1是分子内电荷中和所需的0以上的数。

    Supersensitizing direct positive dye combinations
    2.
    发明授权
    Supersensitizing direct positive dye combinations 失效
    超敏感直接染料组合

    公开(公告)号:US4355098A

    公开(公告)日:1982-10-19

    申请号:US233657

    申请日:1981-02-11

    申请人: James W. Wheeler

    发明人: James W. Wheeler

    IPC分类号: G03C1/28 G03C1/485 G03C5/24

    CPC分类号: G03C1/4853

    摘要: Direct positive photographic elements with improved spectral sensitivity in the green and red portion of the visible spectrum are obtained from emulsions containing a supersensitizing amount of a spectral sensitizing dye (a) having a solution absorption maximum less than 495 nm and the lowest vacant energy band less than -3.7 eV, and a sensitizing amount of a spectral sensitizing dye (b) having a lowest vacant energy band between -3.7 eV and 0.3 eV below the lowest vacant energy band of said spectral sensitizing dye (a) and with the highest occupied energy band between -5.9 eV and 0.3 eV above the highest occupied energy level of dye (a).

    摘要翻译: 含有超敏化量的溶液吸收最大值小于495nm的光谱增感染料(a)的乳液含有较低的空白能带,最低的空位能带 以及敏感量的光谱增感染料(b),其具有在所述光谱增感染料(a)的最低空位能带以下-3.7eV至0.3eV之间的最低空位能带,并具有最高的占有能量 在-5.9eV和0.3eV之间的频带高于染料(a)的最高占有能级。

    Direct-positive photographic silver halide emulsion
    3.
    发明授权
    Direct-positive photographic silver halide emulsion 失效
    直接摄影卤化银乳剂

    公开(公告)号:US4147554A

    公开(公告)日:1979-04-03

    申请号:US778328

    申请日:1977-03-16

    IPC分类号: C09B23/00 G03C1/485 G03C1/16

    CPC分类号: G03C1/4853

    摘要: Direct-positive photographic silver halide emulsion which contains a dye having a 5,6-dihydropyrrolo[2,1-a]isoquinoline ring is disclosed. Said emulsion has a high speed, produces high contrast images, has no color stain with any remaining dye after processing and causes only small depression in the maximum density.

    摘要翻译: 公开了含有具有5,6-二氢吡咯并[2,1-a]异喹啉环的染料的直接正性照相卤化银乳剂。 所述乳液具有高速度,产生高对比度的图像,在加工后与任何剩余的染料没有染色,并且仅产生最小密度的小凹陷。

    Direct positive silver halide photographic emulsion
    6.
    发明授权
    Direct positive silver halide photographic emulsion 失效
    直接正卤化银照相乳剂

    公开(公告)号:US3887380A

    公开(公告)日:1975-06-03

    申请号:US39026473

    申请日:1973-08-21

    摘要: A direct positive silver halide photographic emulsion containing a combination of at least one halogen accepting cyanine sensitizing dye represented by the formula:

    WHEREIN Z and Z1 each represents non-metallic atomic groups necessary to complete 5- or 6-membered heterocyclic nuclei which may be substituted in other positions except the N-position; R and R1 each represents an alkyl group, a substituted alkyl group of the type normally employed in cyanine dyes, or an aryl group; L1, L2 and L3 each represent a methine group or a substituted methine group, wherein the substituents in two of the substituted methine groups may join and form a ring represented by the following formula:

    WHEREIN R6 represents a hydrogen atom or a methyl group and R7 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aralkyl group, a phenyl group, a substituted phenyl group or a furyl group; p and q each represents 1 or 2; n represents 1, 2 or 3; m represents 1 or 2; and x represents an anion; and at least one compound represented by the formula:

    WHEREIN Y represents CH- or N-; R2, R3, R4 and R5 each represents a hydrogen atom, a hydroxy group, an alkoxy group, an aryloxy group, a halogen atom, a heterocyclic nucleus, an alkylthio group, an arylthio group, an amino group, an alkylamino group, a heterocyclylamino group, an aryl group, or a mercapto group; and -A- represents -A1-or -A2-wherein -A1- is
    WITH THE PROVISO THAT WHEN -A- is -A2- at least one of R2, R3, R4 and R5 is a substituent having a -SO3M group, wherein M has the same meaning as defined above.

    WHEREIN M represents a hydrogen atom or a cation which affords water solubility, and wherein -A2- is

    D R A W I N G

    摘要翻译: 含有至少一种由下式表示的卤素接受花青增感染料的组合的直接正卤化银照相乳剂:

    Spectrally sensitized direct positive emulsion
    7.
    发明授权
    Spectrally sensitized direct positive emulsion 失效
    光谱敏感的直接阳性乳液

    公开(公告)号:US3846137A

    公开(公告)日:1974-11-05

    申请号:US28296872

    申请日:1972-08-23

    申请人: AGFA GEVAERT AG

    摘要: 1. A LIGHT SENSITIVE PHOTOGRAPHIC MATERIAL COMPRISING AT LEAST ONE DIRECT POSITIVE FOGGED SILVER HALIDE EMULSION LAYER, WHICH IS SPECTRALLY SENSITIZED WITH A POLYMETHENE SENSITIZING DYE OF ONE OF THE FOLLOWING FORMULAE:

    (-Z1-N(+)(-R1)=(CH-CH)N=)>C-(C(-Y)=CH)M-C(-Y)=C
    N(-R2)-(CH=CH)P-) X(-)

    2-R4,4-R3,5-((-Z1-N(+)(-R1)=(CH-CH)N=)>C-C(-Y)=CH-)-

    THIAZOLE X(-)

    1-R6,2-R5,3-((-Z1-N(+)(-R1)=(CH-CH)N=)>C-C(-Y)=CH-)-

    INDOLE X(-)

    WHEREIN Y=A CYANO, NITRO, ACYL GROUP OR HYDROGEN, AT LEAST ONE OF Y REPRESENTS A CYANO, NITRO OR ACYL GROUP, R1, R2=A SATURATED OR UNSATURATED ALIPHATIC GROUP OR ARYL, R3=HYDROOGEN, A SATURATED OR UNSATURATED ALIPHATIC GROUP OR ARYL, R4=SR7 OR NR5R9, R5=A PHENYL GROUP, R6=HYDROGEN, A SATURATED OR UNSATURATED ALIPHATIC GROUP, ARYL OR ALKOXY, R7, R8, R9=A SATURATED OR UNSATURATED ALIPHATIC GROUP OR PHENYL, N,P=0,1,2 OR 3, M=0,1, 2 OR 3, X=ANY ANION AND Z1, Z2 REPRESENT THE RING MEMBERS REQUIRED FOR COMPLETING ONE OF THE FOLLOWING RINGS: THIAZOE, BENZOTHIAZOLE, OXAZOLE, BENZOXAZOLE, THIAZOLINE, INDOLENINE, PYRIMIDONE, THIOOPYRIMIDONE, QUINOLINE, BENZSELENEAZOLE, OXADIAZOLE, 1,8-NAPHTHINDOLE AND IMIDAZOQUINOXALINE.