摘要:
A direct positive type silver halide photographic material is described, which contains at least one compound represented by the following formula (I) and at least one cyanine dye having a pyrazolo[5,1-b]quinazolone nucleus and a cyanine heterocycle nucleus, wherein a carbon atom at 3-position of the pyrazolo[5,1-b]quinazolone nucleus is bonded through a four-methine chain to an atom at the 2-position or 4-position of the cyanine heterocycle nucleus, provided that the 4-position is possible only when the cyanine heterocycle nucleus is a quinoline or pyridine nucleus: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group, an aryl group or a heterocyclic group, which may be substituted; V.sub.1, V.sub.2, V.sub.3, V.sub.4, V.sub.5, V.sub.6, V.sub.7 and V.sub.8 each represents a hydrogen atom or a monovalent substituent; L.sub.1, L.sub.2 and L.sub.3 each represents a substituted or unsubstituted methine group; M.sub.1 represents a charge-neutralizing counter ion; and m.sub.1 is a number of 0 or larger necessary for intramolecular charge neutralization.
摘要:
Direct positive photographic elements with improved spectral sensitivity in the green and red portion of the visible spectrum are obtained from emulsions containing a supersensitizing amount of a spectral sensitizing dye (a) having a solution absorption maximum less than 495 nm and the lowest vacant energy band less than -3.7 eV, and a sensitizing amount of a spectral sensitizing dye (b) having a lowest vacant energy band between -3.7 eV and 0.3 eV below the lowest vacant energy band of said spectral sensitizing dye (a) and with the highest occupied energy band between -5.9 eV and 0.3 eV above the highest occupied energy level of dye (a).
摘要:
Direct-positive photographic silver halide emulsion which contains a dye having a 5,6-dihydropyrrolo[2,1-a]isoquinoline ring is disclosed. Said emulsion has a high speed, produces high contrast images, has no color stain with any remaining dye after processing and causes only small depression in the maximum density.
摘要:
Printabilities of offset printing plates which utilizes silver complex diffusion transfer process are improved by adding to silver halide emulsion at least one of betaine type cyanine dyes and anion type cyanine dyes.
摘要:
New cyanine dyes derived from di-halogen-benzoxazoles and benzothiazoles are desensitizers for silver halide negative emulsions and useful electron acceptor spectral sensitizers for direct positive silver halide emulsions.
摘要:
A direct positive silver halide photographic emulsion containing a combination of at least one halogen accepting cyanine sensitizing dye represented by the formula:
WHEREIN Z and Z1 each represents non-metallic atomic groups necessary to complete 5- or 6-membered heterocyclic nuclei which may be substituted in other positions except the N-position; R and R1 each represents an alkyl group, a substituted alkyl group of the type normally employed in cyanine dyes, or an aryl group; L1, L2 and L3 each represent a methine group or a substituted methine group, wherein the substituents in two of the substituted methine groups may join and form a ring represented by the following formula:
WHEREIN R6 represents a hydrogen atom or a methyl group and R7 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aralkyl group, a phenyl group, a substituted phenyl group or a furyl group; p and q each represents 1 or 2; n represents 1, 2 or 3; m represents 1 or 2; and x represents an anion; and at least one compound represented by the formula:
WHEREIN Y represents CH- or N-; R2, R3, R4 and R5 each represents a hydrogen atom, a hydroxy group, an alkoxy group, an aryloxy group, a halogen atom, a heterocyclic nucleus, an alkylthio group, an arylthio group, an amino group, an alkylamino group, a heterocyclylamino group, an aryl group, or a mercapto group; and -A- represents -A1-or -A2-wherein -A1- is WITH THE PROVISO THAT WHEN -A- is -A2- at least one of R2, R3, R4 and R5 is a substituent having a -SO3M group, wherein M has the same meaning as defined above.
WHEREIN M represents a hydrogen atom or a cation which affords water solubility, and wherein -A2- is
摘要:
1. A LIGHT SENSITIVE PHOTOGRAPHIC MATERIAL COMPRISING AT LEAST ONE DIRECT POSITIVE FOGGED SILVER HALIDE EMULSION LAYER, WHICH IS SPECTRALLY SENSITIZED WITH A POLYMETHENE SENSITIZING DYE OF ONE OF THE FOLLOWING FORMULAE:
WHEREIN Y=A CYANO, NITRO, ACYL GROUP OR HYDROGEN, AT LEAST ONE OF Y REPRESENTS A CYANO, NITRO OR ACYL GROUP, R1, R2=A SATURATED OR UNSATURATED ALIPHATIC GROUP OR ARYL, R3=HYDROOGEN, A SATURATED OR UNSATURATED ALIPHATIC GROUP OR ARYL, R4=SR7 OR NR5R9, R5=A PHENYL GROUP, R6=HYDROGEN, A SATURATED OR UNSATURATED ALIPHATIC GROUP, ARYL OR ALKOXY, R7, R8, R9=A SATURATED OR UNSATURATED ALIPHATIC GROUP OR PHENYL, N,P=0,1,2 OR 3, M=0,1, 2 OR 3, X=ANY ANION AND Z1, Z2 REPRESENT THE RING MEMBERS REQUIRED FOR COMPLETING ONE OF THE FOLLOWING RINGS: THIAZOE, BENZOTHIAZOLE, OXAZOLE, BENZOXAZOLE, THIAZOLINE, INDOLENINE, PYRIMIDONE, THIOOPYRIMIDONE, QUINOLINE, BENZSELENEAZOLE, OXADIAZOLE, 1,8-NAPHTHINDOLE AND IMIDAZOQUINOXALINE.
摘要:
DIRECT POSITIVE SILVER HALIDE EMULSIONS WHICH CONTAIN AT LEAST ONE DIMETHINECYANINE DYES IN WHICH THE 3-POSITION OFTHE INDOLE NUCLEUS HAVING A HYDROGEN ATOMS, CHLORINE ATOM, LOWER ALKYL GROUP, CARBOXYL GROUP OR LOWER ALKOXYCARBONYL GROUP IN THE 2-POSITION THEREOF JOINS TO THE 1-, 2-, 3- OR 4-POSITION OF THE CYANINE HETEROCYCLIC NUCLEOUS THROUGH A DIMETHINE CHAIN, WITH THE PROVISO THAT ONLY WHEN THE CYANINE NUCLEUS IS ISOQUINOLINE IS THE JOINING TO THE 1- OR 3-POSITION, AND WHEN JOINING IS TO THE 4-POSITION, THE CYANINE NUCLEUS COMPRISES A QUINOLINE OR PYRIDINE RING.
摘要:
A CLASS OF ENERGY-SENSITIVE COMPOUNDS CONTAINING HETEROCYCLIC NITROGEN ATOMS SUBSTITUTED WITH AN -OR GROUP FRAGMENT UNDER THE INFLUENCE OF VARIOUS FORMS OF ENERGY TO FORM A DYE BASE, A PROTON AND AN ALDEHYDE, THESE MATERIALS BEING USEFUL IN IMAGE REPRODUCTION.
摘要:
NOVEL CYANINE DYES ARE PROVIDED WHICH FEATURE A 1,2DIARYLINDOLE NUCLEUS. LIGHT SENSITIVE SILVER HALIDE EMULSIONS CONTAINING THESE DYES ARE ALSO PROVIDED.