Methods and systems for making carbon fibers for high temperature applications

    公开(公告)号:US09695525B1

    公开(公告)日:2017-07-04

    申请号:US14498754

    申请日:2014-09-26

    摘要: The present invention relates to a method for the continuous production of low thermal conductivity endless filament yarns with a compact, homogeneous structural morphology. The presently disclosed methods utilize safe and recyclable ionic liquids (IL) to produce carbon fiber precursors from cellulose. The fibers are produced by the carbonization of cellulose carbon fiber precursors. The precursor fiber filaments have an increased tear resistance with simultaneously sufficient elongation, a round or crenulated cross-section, and homogeneous fiber morphology. The filament yarns exhibit performance characteristics similar to those produced from traditional viscous rayon. The resulting fibers are especially suited for aerospace applications in composite materials used at the limits of high temperatures, for instance in structures found in rocket nozzles or atmospheric reentry heat shields on spacecraft.

    Flame-resistant molded cellulose bodies produced according to a direct dissolving method
    3.
    发明申请
    Flame-resistant molded cellulose bodies produced according to a direct dissolving method 审中-公开
    根据直接溶解法制造的耐火模制纤维素体

    公开(公告)号:US20170016148A1

    公开(公告)日:2017-01-19

    申请号:US15124872

    申请日:2015-03-05

    申请人: smartpolymer GmbH

    摘要: The invention relates to molded cellulose bodies, in particular fibers, filaments, directly spun nonwovens, films, or foams which have flame-resistant properties. The fibers and filaments can be further processed as textiles into yarns, wovens, knitted fabrics, and nonwovens. The molded bodies are produced from solutions of cellulose and melamine cyanurate or cellulose and crosslinked or partially crosslinked melamine resin particles in an organic solvent. The melamine cyanurate or the melamine resin particles provide the molded cellulose bodies with flame-retardant properties. The molded cellulose bodies made of cellulose and melamine cyanurate or melamine resin particles can further contain flame retardants, in particular flame retardants which act synergistically, in a particulate form. The obtained textile fibers and nonwoven materials have a soft touch and can be processed or finished as filaments or yarns on conventional textile machines.

    摘要翻译: 本发明涉及具有阻燃性能的成型纤维素体,特别是纤维,长丝,直接纺丝的无纺布,薄膜或泡沫体。 纤维和长丝可以作为纺织品进一步加工成纱线,织物,针织物和无纺布。 成型体由纤维素和氰尿酸三聚氰胺或纤维素和交联或部分交联的三聚氰胺树脂颗粒在有机溶剂中的溶液制成。 三聚氰胺氰尿酸酯或三聚氰胺树脂颗粒为模制的纤维素体提供阻燃性能。 由纤维素和三聚氰胺氰尿酸酯或三聚氰胺树脂颗粒制成的纤维素体可以进一步含有阻燃剂,特别是协同作用的阻燃剂,其为颗粒形式。 所获得的纺织纤维和非织造材料具有柔软的触感,并且可以在常规纺织机器上加工或加工成长丝或纱线。

    PREPARATION METHOD OF FIBER AND SPINNING VISCOSE
    4.
    发明申请
    PREPARATION METHOD OF FIBER AND SPINNING VISCOSE 审中-公开
    纤维和纺丝粘胶的制备方法

    公开(公告)号:US20160160390A1

    公开(公告)日:2016-06-09

    申请号:US14740279

    申请日:2015-06-16

    摘要: A preparation method of a fiber is provided. In the preparation method of the fiber, a polymer is dissolved in a mixing solution of an ionic liquid and a salt to form a spinning viscose, wherein the salt includes KCl, KBr, KOAc, NaBr, ZnCl2 or a combination thereof. Afterwards, the spinning viscose is used as a material to perform a spinning process so as to form a fiber.

    摘要翻译: 提供了纤维的制备方法。 在纤维的制备方法中,将聚合物溶解在离子液体和盐的混合溶液中以形成纺丝粘胶,其中所述盐包括KCl,KBr,KOAc,NaBr,ZnCl 2或其组合。 之后,使用纺丝粘胶作为进行纺丝工序的材料,形成纤维。

    ALKALI RECYCLE IN CELLULOSE SPINNING PROCESS
    5.
    发明申请
    ALKALI RECYCLE IN CELLULOSE SPINNING PROCESS 审中-公开
    纤维素纺丝工艺中的碱性回收

    公开(公告)号:US20160138200A1

    公开(公告)日:2016-05-19

    申请号:US14900904

    申请日:2014-06-27

    申请人: IHK FIBRE AB

    IPC分类号: D01F13/02 C01D1/28 C08B16/00

    摘要: The present invention concerns a method for the recovery of solvent in a process for preparation of regenerated cellulosic fibers using sodium hydroxide as solvent for cellulose dissolving in the manufacturing of a cellulose spinning dope wherein sodium hydroxide present in the spinning dope is at least partially recovered and recycled as sodium hydroxide from a cellulose fiber regeneration or cellulose coagulation step and wherein said cellulose fiber regeneration or cellulose coagulation step consists of a bath into which cellulose spinning dope is injected. Recovered sodium hydroxide may be directly or indirectly recycled from a cellulose fiber regeneration or cellulose coagulation step to a cellulose dissolving step.

    摘要翻译: 本发明涉及一种在制备再生纤维素纤维的方法中回收溶剂的方法,该方法使用氢氧化钠作为纤维素溶剂的溶剂来溶解制备纤维素纺丝原液,其中存在于纺丝原液中的氢氧化钠至少部分回收, 从纤维素纤维再生或纤维素凝固步骤循环使用氢氧化钠,其中所述纤维素纤维再生或纤维素凝固步骤由注入纤维素纺丝原液的浴组成。 回收的氢氧化钠可以直接或间接地从纤维素纤维再生或纤维素凝结步骤再循环到纤维素溶解步骤。

    METHOD OF PRODUCING REGENERATED CELLULOSE AND HEMICELLULOSE
    7.
    发明申请
    METHOD OF PRODUCING REGENERATED CELLULOSE AND HEMICELLULOSE 审中-公开
    生产再生纤维素和血细胞的方法

    公开(公告)号:US20160032021A1

    公开(公告)日:2016-02-04

    申请号:US14784457

    申请日:2014-04-15

    申请人: METSÄ FIBRE OY

    IPC分类号: C08B16/00 D21C9/00

    摘要: A method of producing regenerated cellulose and hemicellulose from a fibre pulp which is prepared by using chemical cooking. Hemicellulose and, correspondingly, cellulose is separated from the pulp, in order to form separate fractions, by dissolving them in such a solvent or an aqueous solution of it, from which they are precipitated by adding water, after which the regenerated hemicellulose and cellulose can be recovered. Hemicellulose-containing pulp, which for example is used as raw material of paper, can be efficiently fractionated into polymeric hemicellulose-rich fractions and very pure cellulose fractions, such as regenerated cellulose fibre, various cellulose particles or cellulose films.

    摘要翻译: 由使用化学烹调制备的纤维纸浆生产再生纤维素和半纤维素的方法。 通过将半纤维素和相应的纤维素从纸浆中分离出来,通过将它们溶解在它们的溶剂或其水溶液中形成分离的级分,通过加入水使它们沉淀,之后再生的半纤维素和纤维素可以 被收回。 例如用作纸的原料的含半纤维素的纸浆可以有效地分级成聚合的富含半纤维素的级分和非常纯的纤维素级分,例如再生纤维素纤维,各种纤维素颗粒或纤维素膜。

    BIODEGRADABLE FIBRE AND ITS PROCESS OF MANUFACTURE
    10.
    发明申请
    BIODEGRADABLE FIBRE AND ITS PROCESS OF MANUFACTURE 审中-公开
    生物可变光纤及其制造工艺

    公开(公告)号:US20120202398A1

    公开(公告)日:2012-08-09

    申请号:US13497209

    申请日:2010-10-21

    IPC分类号: C08L1/12 D03D15/00 D01F6/18

    摘要: The present invention concerns a biodegradable fibre comprising composite filaments of cellulose and cellulose acetate, and a process for making such a fibre comprising providing a solution dope comprising a blend of cellulose and cellulose acetate in an ionic liquid or in N-methylmorphilone-N-oxide (NMMO), and spinning casting the blend into a protic solvent to generate fibres. The invention also concerns materials made from such a fibre, and garments or soft furnishings made from such a material.

    摘要翻译: 本发明涉及包含纤维素和乙酸纤维素的复合长丝的生物可降解纤维,以及制备这种纤维的方法,包括提供溶液涂料,所述溶液涂料包含离子液体中的纤维素和乙酸纤维素的混合物或N-甲基吗啉酮-N-氧化物 (NMMO),并将共混物旋转浇铸成质子溶剂以产生纤维。 本发明还涉及由这种纤维制成的材料,以及由这种材料制成的衣服或软的家具。