摘要:
Embodiments relate to a polythiol composition for a plastic optical lens and a polythiourethane-based plastic optical lens prepared therefrom. In the embodiments, a first polythiol compound having mercapto groups only as a hydrogen-bondable functional group and a second polythiol compound having mercapto groups as a hydrogen-bondable functional group and a hydrogen-bondable functional group other than a mercapto group are used in an appropriate amount. Thus, not only is it possible to control the viscosity of a polymerizable composition at the initial stage of polymerization at a low temperature of 5 to 15° C. and to stabilize the rate of increase in the viscosity of the composition and the reaction rate thereof, but also the change in the viscosity at a low temperature is low, thereby preventing the generation of striae, bubbles, and the like. Further, various plastic lenses such as eyeglass lenses, camera lenses, and the like having excellent appearance characteristics (without striae and bubbles) and excellent optical characteristics can be obtained from the composition.
摘要:
The present invention relates to a process for the production of flexible polyurethane foams, wherein there is used as starting material a polyester polyol component which is composed of at least two dicarboxylic acids.
摘要:
A method of manufacturing a modified polyhydroxy compound, which is characterized in that a polyhydroxy compound is heated for 30 minutes or more at a temperature ranging from 150.degree. to 250.degree. C. under stirring and in the presence of tin, tin compounds such as tin halogenide, tin hydroxide and tin oxide. The polyhydroxy compound modified by this method is effective in improving the foamability and mechanical strength of urethane foam, when it is used as a raw material in the manufacture of urethane foam.
摘要:
A process for producing polyurethane foam by reacting at least one polyol component with at least one isocyanate component in the presence of at least one blowing agent and of one or more catalysts that catalyze the isocyanate-polyol and/or isocyanate-water reactions and/or the isocyanate trimerization, wherein the reaction is conducted in the presence of selected polyether-siloxane copolymers, is described.
摘要:
A composition comprising an isocyanate component A) comprising at least one cycloaliphatic or araliphatic diisocyanate, a polyol component B) comprising at least one polyol having an OH number of 80 to 1000 mg KOH/g, an additive component C) comprising at least one internal demoulding agent, and a catalyst component D) comprising at least one inorganic metal complex as thermally latent catalyst, characterized in that the thermally latent catalyst has a quotient of reaction rates between catalysed reaction and uncatalysed reaction at 30° C. of =5.0 and at 60° C. of =1.1. The present invention further provides a process for producing an elastomer and for the use of the composition for production of transparent shaped bodies.
摘要:
This invention relates to polyurethane/polyureas with improved catalysis and to a process for the preparation of these polyurethane/polyureas. These materials comprise the reaction product of (A) a (cyclo)aliphatic polyisocyanate or (cyclo)aliphatic polyisocyanate prepolymer, with (B) an isocyanate-reactive component comprising at least one aromatic diamine compound containing from 1 to 8 thiomethyl groups, in the presence of (C) one or more catalysts selected from the group consisting of tin (II) catalysts, bismuth (III) catalysts and mixtures thereof. Preferably, the materials are optically clear.