Cycloaliphatic epoxy (meth)acrylates, preparation processes thereof, and copolymers
    5.
    发明申请
    Cycloaliphatic epoxy (meth)acrylates, preparation processes thereof, and copolymers 审中-公开
    环脂肪族环氧(甲基)丙烯酸酯,其制备方法和共聚物

    公开(公告)号:US20090124776A1

    公开(公告)日:2009-05-14

    申请号:US11666943

    申请日:2005-11-28

    Applicant: Hideyuki Takai

    Inventor: Hideyuki Takai

    Abstract: There are provided a novel compound having an 3,4-epoxytricyclo[5.2.1.02,6]decane skeleton and a polymerizable unsaturated bond, and a process for the preparation of the compound.There is also provided a copolymer including a monomeric unit (A) containing an alkali-soluble group, and a monomeric unit (B) corresponding to an epoxy-containing polymerizable unsaturated compound, or a copolymer including, in addition to the monomeric units (A) and (B), a monomeric unit (C) corresponding to an epoxy-free polymerizable unsaturated compound such as a N-substituted maleimide, in which the monomeric unit (B) occupies 40 to 90 percent by weight of total monomeric units, and 30 percent by weight or more of the monomeric unit (B) is a monomeric unit corresponding to a specific 3,4-epoxytricyclo[5.2.1.02,6]decane skeleton-containing compound. The copolymer can yield a film excellent typically in thermal stability, yield a resin composition having very high storage stability, and be easily synthetically prepared.

    Abstract translation: 提供了具有3,4-环氧三环[5.2.1.02,6]癸烷骨架和可聚合不饱和键的新化合物及其制备方法。 还提供了包含含有碱溶性基团的单体单元(A)和对应于含环氧基的可聚合不饱和化合物的单体单元(B)的共聚物,或包含除单体单元(A )和(B)中,单体单元(C)对应于不含环氧基的可聚合不饱和化合物如N-取代马来酰亚胺,其中单体单元(B)占总单体单元的40〜90重量%,以及 单体单元(B)的30重量%以上是对应于特定的3,4-环氧三环[5.2.1.02,6]癸烷骨架的化合物的单体单元。 共聚物可以产生通常在热稳定性方面优异的膜,产生具有非常高的储存稳定性的树脂组合物,并且可以容易地合成制备。

    NOVEL NORBORNENE DERIVATIVE
    6.
    发明申请
    NOVEL NORBORNENE DERIVATIVE 有权
    新奥尔卑斯派代理

    公开(公告)号:US20150307467A1

    公开(公告)日:2015-10-29

    申请号:US14647825

    申请日:2013-11-28

    CPC classification number: C07D303/16 C07D301/14 C07D303/14 C07D303/17

    Abstract: A novel compound useful as a raw material for a resist material is described. A norbornene derivative having epoxy and a methylene-mediated reactive group in a norbornane skeleton is represented by the following formula. In the formula, R1 represents a hydrogen atom, acryloyl, methacryloyl or hydroxymethylacryloyl, and R2 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.

    Abstract translation: 描述了可用作抗蚀剂材料的原料的新型化合物。 在降冰片烷骨架中具有环氧基和亚甲基介导的反应性基团的降冰片烯衍生物由下式表示。 在该式中,R 1表示氢原子,丙烯酰基,甲基丙烯酰基或羟甲基丙烯酰基,R 2表示氢原子或碳原子数为1〜4的烷基。

    Synergistic anticoagulant composition
    7.
    发明授权
    Synergistic anticoagulant composition 有权
    协同抗凝组合物

    公开(公告)号:US08765982B2

    公开(公告)日:2014-07-01

    申请号:US12895103

    申请日:2010-09-30

    CPC classification number: C07D303/17 A61K31/336 C07D303/14 C07D303/32

    Abstract: A composition is provided that, when utilized in combination with warfarin, greatly improves the anticoagulant effects of warfarin in mammalian subjects. The composition is a compound having a naphthohydroquinone ring system substantially similar to the ring system of the reduced form of vitamin K1 and has the general formula: where R1 and R4 are hydrogen or acyl, R2 is a saturated or unsaturated alkyl group with up to 6 carbons, and R3 is a saturated or unsaturated alkyl group with up to 20 carbons, or R2 and R3 are part of a cyclic or polycyclic ring system.

    Abstract translation: 提供了组合物,当与华法林组合使用时,大大提高了华法林在哺乳动物受试者中的抗凝作用。 该组合物是具有与还原形式的维生素K1的环系统基本相似的萘氢醌环体系的化合物,具有以下通式:其中R 1和R 4是氢或酰基,R 2是饱和或不饱和的烷基,最多6个 碳和R3是饱和或不饱和的具有多达20个碳的烷基,或者R 2和R 3是环状或多环系统的一部分。

    RENEWABLE MODIFIED NATURAL COMPOUNDS
    8.
    发明申请
    RENEWABLE MODIFIED NATURAL COMPOUNDS 有权
    可再生改性天然化合物

    公开(公告)号:US20130289284A1

    公开(公告)日:2013-10-31

    申请号:US13811561

    申请日:2011-07-25

    CPC classification number: C07D207/27 C07D303/17 C07D303/42 C08L91/00 C09F7/00

    Abstract: Provided are modified natural compounds that are produced, at least in part, from (A) at least one epoxidized and/or maleated natural fatty acid, or epoxidized and/or maleated natural oil, and (B) at least one lactam having at least one hydroxyl functional group, wherein the lactam may be in a blend with one or more optional alcohol(s). Among other properties, the modified natural compounds may exhibit dispersibility or solubility characteristics in water and/or alcohols. The invention further provides a wide variety of compositions comprising the modified natural compounds.

    Abstract translation: 提供至少部分由(A)至少一种环氧化和/或马来化天然脂肪酸或环氧化和/或马来酸化天然油生产的改性天然化合物,和(B)至少一种至少具有至少一种 一个羟基官能团,其中内酰胺可以与一种或多种任选的醇的共混物。 在其它性质中,改性天然化合物可表现出在水和/或醇中的分散性或溶解性。 本发明还提供了包含改性天然化合物的各种组合物。

    Process for the preparation of pyrazole carboxylic acid amides
    9.
    发明授权
    Process for the preparation of pyrazole carboxylic acid amides 有权
    制备吡唑羧酸酰胺的方法

    公开(公告)号:US08519152B2

    公开(公告)日:2013-08-27

    申请号:US13642406

    申请日:2011-04-14

    Abstract: The invention relates to a process for the preparation of the compound of formula (I), which process comprises a) reacting a compound of formula (II), wherein X is chloro or bromo, with an organometallic species in an inert atmosphere to a halobenzyne of formula (X), reacting the halobenzyne of formula X so formed with cyclopentadiene to (III), b) reacting III in the presence of an inert solvent with an oxidant to (IV), c) reacting IV in the presence of a Lewis acid and a hydride source to (V), d) reacting V in the presence of an oxidizing agent, a base and an inert solvent to (VI), e) converting VI in the presence of a phosphane and CCl4 or CHCl3 to (VII), and either f1) reacting VII with NH3 in the presence of a catalyst to the compound of formula (VIII); and g) reacting VIII in the presence of a base with a compound of formula (IX), to the compound of formula (I); or f2) reacting the compound of formula (VII), in the presence of a solvent, a base, a copper catalyst and at least one ligand with the compound of formula (IXa), to the compound of formula (I).

    Abstract translation: 本发明涉及一种制备式(I)化合物的方法,该方法包括:a)使惰性气氛下的有机金属物质使式(II)化合物(其中X为氯或溴)与卤代苯 使式(X)所示的卤代苯与环戊二烯反应,得到(III),b)使III在惰性溶剂存在下与氧化剂反应,得到(Ⅳ),c)使IV在Lewis 酸和氢化物源至(V),d)使V在氧化剂,碱和惰性溶剂的存在下与(VI)反应,e)在磷烷和CCl 4或CHCl 3存在下将VI转化为(VII ),并且f1)使VII与NH 3在催化剂存在下与式(VIII)化合物反应; 和g)在碱存在下使VIII与式(IX)化合物反应,得到式(I)化合物; 或者f2)使式(Ⅶ)化合物在溶剂存在下,碱,铜催化剂和至少一种配体与式(Ⅸa)化合物反应,得到式(I)化合物。

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