-
公开(公告)号：US09950313B2
公开(公告)日：2018-04-24
申请号：US15563381
申请日：2016-03-30
发明人： Satoshi Miike , Eri Tateno , Yusuke Ishii
IPC分类号： C07C253/24 , C07C253/26 , B01J23/30 , B01J23/00 , B01J37/08 , B01J35/02 , B01J37/04
CPC分类号： B01J23/30 , B01J23/002 , B01J35/023 , B01J37/04 , B01J37/08 , B01J2523/00 , C07B61/00 , C07C253/24 , C07C255/08 , Y02P20/52 , B01J2523/3712 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/69
摘要： The present invention provides a method for producing an oxide catalyst comprising Mo, V, Sb, and Nb for use in a gas-phase catalytic oxidation reaction or a gas-phase catalytic ammoxidation reaction of propane or isobutane, the method comprising: a preparation step of preparing a first aqueous mixed solution containing Mo, V, and Sb; a mixing step of mixing the first aqueous mixed solution with a support raw material comprising silica sol, and a Nb raw material to obtain a second aqueous mixed solution; a drying step of drying the second aqueous mixed solution to obtain a dry powder; and a calcination step of calcining the dry powder to obtain the oxide catalyst, wherein the support raw material comprises 25% by mass or more, based on SiO2, of the silica sol having an average primary particle size of 3.0 nm or larger and smaller than 11 nm based on a total amount of the support raw material, and the silica sol comprises 55% or more of silica sol particles having a primary particle size of smaller than 11 nm.
-
公开(公告)号：US20180085737A1
公开(公告)日：2018-03-29
申请号：US15563381
申请日：2016-03-30
发明人： Satoshi MIIKE , Eri TATENO , Yusuke ISHII
CPC分类号： B01J23/30 , B01J23/002 , B01J35/023 , B01J37/04 , B01J37/08 , B01J2523/00 , C07B61/00 , C07C253/24 , C07C255/08 , Y02P20/52 , B01J2523/3712 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/69
摘要： The present invention provides a method for producing an oxide catalyst comprising Mo, V, Sb, and Nb for use in a gas-phase catalytic oxidation reaction or a gas-phase catalytic ammoxidation reaction of propane or isobutane, the method comprising: a preparation step of preparing a first aqueous mixed solution containing Mo, V, and Sb; a mixing step of mixing the first aqueous mixed solution with a support raw material comprising silica sol, and a Nb raw material to obtain a second aqueous mixed solution; a drying step of drying the second aqueous mixed solution to obtain a dry powder; and a calcination step of calcining the dry powder to obtain the oxide catalyst, wherein the support raw material comprises 25% by mass or more, based on SiO2, of the silica sol having an average primary particle size of 3.0 nm or larger and smaller than 11 nm based on a total amount of the support raw material, and the silica sol comprises 55% or more of silica sol particles having a primary particle size of smaller than 11 nm.
-
公开(公告)号：US09815045B2
公开(公告)日：2017-11-14
申请号：US15061033
申请日：2016-03-04
申请人： CLARIANT CORPORATION
发明人： Claus G. Lugmair , Hailian Li
IPC分类号： B01J37/08 , B01J37/03 , C07C45/35 , B01J23/889 , B01J35/00 , B01J23/00 , C07C253/26 , B01J37/00 , B01J23/887 , B01J35/02
CPC分类号： B01J23/8898 , B01J23/002 , B01J23/8876 , B01J35/0013 , B01J35/023 , B01J37/0045 , B01J37/0081 , B01J37/03 , B01J37/08 , B01J2523/00 , C07C45/35 , C07C253/26 , Y02P20/52 , C07C255/08 , B01J2523/13 , B01J2523/15 , B01J2523/22 , B01J2523/3712 , B01J2523/41 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/72 , B01J2523/842 , B01J2523/845 , C07C253/28
摘要： The present disclosure relates to metal oxide catalyst materials useful, for example, in the ammoxidation of propylene or isobutylene, processes for making them, and processes for making acrylonitrile and methacrylonitrile using such catalyst materials. In certain aspects, a catalyst material is a fused composite of a metal oxide catalyst and nanoparticulate silica, the nanoparticulate silica comprising in the range of about 40 wt % to about 80 wt % of silica having a particle size in the range of 10 nm to 35 nm, and in the range of about 20 wt % to about 60 wt % of silica having a particle size in the range of 36 nm to 80 nm. The metal oxide catalyst can be, for example, a molybdenum-containing mixed metal oxide catalyst.
-
公开(公告)号：US09731285B2
公开(公告)日：2017-08-15
申请号：US12810493
申请日：2008-12-11
申请人： Eri Tateno , Masatoshi Kaneta
发明人： Eri Tateno , Masatoshi Kaneta
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J35/02 , B01J23/28 , B01J23/30 , B01J23/34 , B01J27/057 , B01J37/00 , B01J37/08 , C07C253/24
CPC分类号： B01J35/023 , B01J23/002 , B01J23/28 , B01J23/30 , B01J23/34 , B01J27/0576 , B01J37/0045 , B01J37/08 , B01J2523/00 , C07C253/24 , Y02P20/52 , C07C255/08 , B01J2523/305 , B01J2523/3712 , B01J2523/41 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/47 , B01J2523/69 , B01J2523/31 , B01J2523/72 , B01J2523/64 , B01J2523/57
摘要： An object of the present invention is to provide a process for producing an oxide catalyst used in a vapor-phase catalytic oxidation or vapor-phase catalytic ammoxidation reaction of propane or isobutene, which enables a catalyst demonstrating favorable yield to be stably produced. According to the present invention, there is provided a process for producing an oxide catalyst used in a vapor-phase catalytic oxidation or vapor-phase catalytic ammoxidation reaction of propane or isobutane, comprising the steps of: (i) preparing a catalyst raw material mixture containing Mo, V and Nb and satisfying the relationships of 0.1≦a≦1 and 0.01≦b≦1 when atomic ratios of V and Nb to one atom of Mo are defined as a and b, respectively; (ii) drying the catalyst raw material mixture; and (iii) calcining a particle, in which a content of the particle having a particle diameter of 25 μm or less is 20% by mass or less and a mean particle diameter is from 35 to 70 μm, in an inert gas atmosphere.
-
5.发明申请OXIDE CATALYST AND METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING UNSATURATED NITRILE 审中-公开氧化物催化剂及其生产方法，以及生产不饱和硝酸盐的方法公开(公告)号：US20160297753A1
公开(公告)日：2016-10-13
申请号：US15102950
申请日：2015-03-04
发明人： Yusuke ISHII , Kazushi OKADA
CPC分类号： C07C253/24 , B01J21/08 , B01J23/002 , B01J23/30 , B01J35/0006 , B01J37/0045 , B01J37/009 , B01J37/0215 , B01J37/0236 , B01J37/04 , B01J37/088 , B01J2523/00 , Y02P20/52 , C07C255/08 , B01J2523/3712 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/69
摘要： There is provided a method for producing an oxide catalyst, the method including a step (a) of obtaining an aqueous mixed liquid A containing Mo, V and Sb, a step (b) of mixing a Nb raw material, water and an organic acid to obtain a Nb aqueous solution, a step (c) of mixing the Nb aqueous solution and a silica raw material to obtain an aqueous mixed liquid B, a step (d) of mixing the aqueous mixed liquid A and the aqueous mixed liquid B to obtain an aqueous mixed liquid (C), a step (e) of drying the aqueous mixed liquid C to obtain a dried powder D, and a step (f) of calcining the dried powder D to obtain the oxide catalyst.
摘要翻译： 提供一种生产氧化物催化剂的方法，该方法包括步骤（a）获得含有Mo，V和Sb的水性混合液A，将Nb原料，水和有机酸混合的步骤（b） 得到Nb水溶液，将Nb水溶液与二氧化硅原料混合以得到含水混合液B的工序（c），将含水混合液A与含水混合液B混合的工序（d） 得到含水混合液（C），干燥含水混合液C的工序（e），得到干燥粉末D，煅烧干燥粉末D的工序（f）得到氧化物催化剂。
-
公开(公告)号：US09464039B2
公开(公告)日：2016-10-11
申请号：US13994230
申请日：2011-10-13
申请人： Sho Tamura , Sadao Shoji
发明人： Sho Tamura , Sadao Shoji
IPC分类号： C07C253/24 , B01J23/30 , B01J23/00 , B01J23/28 , B01J27/057
CPC分类号： C07C253/24 , B01J23/002 , B01J23/28 , B01J23/30 , B01J27/0576 , B01J2523/00 , Y02P20/52 , B01J2523/41 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/69 , B01J2523/3706 , B01J2523/3712 , C07C255/08
摘要： A method for producing an unsaturated nitrile by subjecting propane to a vapor-phase catalytic ammoxidation reaction using a fluidized bed reactor in the presence of a composite oxide catalyst containing Mo, V, and Nb, the method comprising the step of: adding a tungsten compound into the fluidized bed reactor to adjust a molar ratio (W/Mo ratio) of tungsten contained in a tungsten compound to molybdenum contained in the composite oxide catalyst that exist within the fluidized bed reactor so that the molar ratio is in the range of 0.0001 to 0.1.
摘要翻译： 在含有Mo，V和Nb的复合氧化物催化剂存在下，使用流化床反应器对丙烷进行气相催化氨氧化反应的方法，该方法包括以下步骤：加入钨化合物 进入流化床反应器以调节钨化合物中所含的钨与存在于流化床反应器内的复合氧化物催化剂中所含的钼的摩尔比（W / Mo比），使得摩尔比在0.0001至 0.1。
-
公开(公告)号：US09433929B2
公开(公告)日：2016-09-06
申请号：US13200219
申请日：2011-09-21
IPC分类号： B01J27/19 , B01J23/887 , B01J37/03 , B01J23/00 , B01J35/00 , C07C253/26 , B01J21/08 , B01J37/00
CPC分类号： C07C253/26 , B01J21/08 , B01J23/002 , B01J23/8876 , B01J23/8878 , B01J35/002 , B01J37/0045 , B01J37/031 , B01J2523/00 , G01N23/20 , Y02P20/52 , B01J2523/14 , B01J2523/22 , B01J2523/3712 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/41 , C07C255/08
摘要： Catalytic compositions are provided that are effective for providing increased acrylonitrile product without a significant decrease in hydrogen cyanide and/or acetonitrile production and provide an overall increase in production of acrylonitrile, hydrogen cyanide and acetonitrile. The catalytic compositions include a complex of metal oxides and include at least about 15% m-phase plus t-phase by weight and have a weight ratio of m-phase to m-phase plus t-phase of 0.45 or greater.
-
8.发明授权公开(公告)号：US09295977B2
公开(公告)日：2016-03-29
申请号：US14456598
申请日：2014-08-11
申请人： INEOS USA LLC
发明人： James Frank Brazdil , Charles James Besecker , Michael J. Seely , Muin S. Haddad , Mark A. Toft
IPC分类号： B01J23/887 , C07C51/25 , C07C45/35 , C07C253/26 , B01J37/03 , B01J37/08 , B01J23/00 , B01J23/889 , B01J37/00 , B01J35/00
CPC分类号： B01J23/8878 , B01J23/002 , B01J23/8898 , B01J35/0006 , B01J37/0045 , B01J37/038 , B01J37/088 , B01J2523/00 , B01J2523/14 , B01J2523/22 , B01J2523/3712 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/847 , C07C45/35 , C07C51/252 , C07C253/26 , Y02P20/52 , C07C255/08
摘要： A process for preparation of catalysts for the production of acrylonitrile, acetonitrile and hydrogen cyanide comprising contacting at an elevated temperature, propylene, ammonia and oxygen in the vapor phase in the presence of a catalyst, said catalyst comprising a complex of metal oxides wherein a heat-decomposable nitrogen containing compound is added during the process for the preparation of the catalyst.
摘要翻译： 一种制备用于生产丙烯腈，乙腈和氰化氢的催化剂的方法，包括在催化剂存在下，在升高的温度下使气相中的丙烯，氨和氧接触，所述催化剂包含金属氧化物的复合物，其中热量 在制备催化剂的过程中加入可分解的含氮化合物。
-
9.发明申请CATALYST FOR ACRYLONITRILE PRODUCTION AND METHOD FOR PRODUCING ACRYLONITRILE 审中-公开丙烯腈生产催化剂和生产丙烯腈的方法公开(公告)号：US20160008794A1
公开(公告)日：2016-01-14
申请号：US14768281
申请日：2014-02-19
IPC分类号： B01J27/19 , C07C253/26 , B01J37/08
CPC分类号： B01J27/19 , B01J23/8885 , B01J27/199 , B01J37/0045 , B01J37/08 , B01J2523/00 , C07C253/26 , Y02P20/52 , B01J2523/11 , B01J2523/17 , B01J2523/23 , B01J2523/305 , B01J2523/41 , B01J2523/51 , B01J2523/53 , B01J2523/64 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/847 , B01J2523/13 , B01J2523/33 , B01J2523/3718 , B01J2523/44 , C07C255/08
摘要： A catalyst for acrylonitrile production, which is produced by the vapor phase contact ammoxidation of propylene by molecular oxygen and ammonia, and a method for producing acrylonitrile using the catalyst.
摘要翻译： 丙烯腈生产催化剂，其通过用分子氧和氨气相接触丙烯氧化制备，以及使用该催化剂生产丙烯腈的方法。
-
公开(公告)号：US09211527B1
公开(公告)日：2015-12-15
申请号：US14290341
申请日：2014-05-29
申请人： INEOS USA, LLC
IPC分类号： B01J23/887 , C07C253/26 , C07C253/18
CPC分类号： B01J23/8993 , B01J23/002 , B01J23/887 , B01J23/8878 , B01J2523/00 , C07C253/18 , C07C253/26 , Y02P20/52 , C07C255/08
摘要： A catalytic composition useful for the conversion of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile, and mixtures thereof. The catalytic composition comprises a complex of metal oxides comprising bismuth, molybdenum, iron, cerium and other promoters, wherein the ratio of bismuth to cerium ratio in the composition is greater than or equal to 0.45 and less than or equal to 1.5.
摘要翻译： 用于将选自丙烯，异丁烯或其混合物的烯烃转化成丙烯腈，甲基丙烯腈及其混合物的催化组合物。 催化剂组合物包含包含铋，钼，铁，铈和其它助催化剂的金属氧化物的复合物，其中组合物中铋与铈的比例大于或等于0.45且小于或等于1.5。
-
-
-
-
-
-
-
-
-
搜索结果
1008 条记录 (耗时 0.027 秒)
