公开(公告)号：US20170073268A1

公开(公告)日：2017-03-16

申请号：US15123383

申请日：2015-02-16

Applicant: SAN NOPCO KOREA LTD.

Inventor： Oil KWEON ,  Jaeik JEON ,  Chanyong YU ,  Kyeong Hwan KIM ,  Youngju JEON

IPC: C04B24/32 ,  C04B24/26 ,  C04B28/04

CPC classification number: C04B24/32 ,  C04B24/2647 ,  C04B24/267 ,  C04B24/2694 ,  C04B28/02 ,  C04B28/04 ,  C04B2103/0059 ,  C04B2103/308 ,  C04B2103/408 ,  C08F290/062 ,  C08F220/06 ,  C08F220/20 ,  C08F222/06

Abstract: The present invention relates to a polycarbonic acid-based cement dispersant, a method for preparing the same, and a mortar-concrete admixture using the polycarbonic acid-based cement dispersant.The cement dispersant of the present invention and the mortar-concrete admixture using the cement dispersant are applied to a cement composition such as a cement paste, mortar, concrete, etc., enhance a dispersion and retention force between cement molecules, have excellent fluidity due to the suppression of slump loss, and have an effect of improving workability, such as shortening a concrete mixing time by 20% or more. Further, the mortar-concrete admixture using the cement dispersant of the present invention has an effect of providing a very good concrete condition and an appropriate compressive strength over time.

Abstract translation: 将本发明的水泥分散剂和使用水泥分散剂的砂浆混凝土外加剂施加到水泥组合物如水泥浆，砂浆，混凝土等上，增强了水泥分子之间的分散和保持力，具有优异的流动性 抑制坍落度损失，具有提高加工性的效果，例如将混凝土搅拌时间缩短20％以上。 此外，使用本发明的水泥分散剂的砂浆混凝土外加剂具有随时间提供非常好的混凝土条件和适当的抗压强度的效果。

公开(公告)号：US20140114030A1

公开(公告)日：2014-04-24

申请号：US13910785

申请日：2013-06-05

Applicant: BEIJING UNIVERSITY OF TECHNOLOGY

Inventor： XIAO LIU ,  ZIMING WANG ,  SUPING CUI ,  MINGZHANG LAN ,  QIANJIN MAO ,  HONGXIA GUO ,  YALI WANG ,  JINBO YANG ,  XIAOYU MA ,  JIE ZHU

IPC: C08F220/18

CPC classification number: C04B24/16 ,  C04B24/26 ,  C04B24/2641 ,  C04B24/2647 ,  C04B2103/308 ,  C04B2103/32 ,  C08F220/06 ,  C08F220/18 ,  C08F283/01 ,  C08F290/06

Abstract: This invention relates to a method for preparing a star-shaped polycarboxylate superplasticizer by the first esterification step with polyol and (meth)acrylic acid as main reactants and the second polymerization step. In the first step, the star-shaped polymerizable active ends were synthesized by esterification between polyol and (meth)acrylic acid in the presence of catalyst. In the second step, the final star-shaped polycarboxylate superplasticizer was prepared by radical polymerization among the product obtained in first step, unsaturated polyoxyethylene ethers, molecular weight regulator and unsaturated carboxylic acid in the presence of initiator. The production process of this invention exhibits some characteristics including simple, easily controllable, high polymerization degree, low cost and pollution free. The star-shaped molecular structure of polycarboxylate superplasticizer can be achieved through synthesizing active “core” by esterification and “arm” by radical polymerization. It showed better cement paste fluidity and fluidity retention, which manifested as better adaptability to cement and application performance in concrete, than both traditional linear and comb-shaped polycarboxylate superplasticizer at common or lower dosage.

Abstract translation: 本发明涉及通过第一酯化步骤制备星形聚羧酸酯超增塑剂的方法，其中多元醇和（甲基）丙烯酸作为主要反应物和第二聚合步骤。 在第一步中，在催化剂存在下，通过多元醇与（甲基）丙烯酸的酯化合成星形可聚合活性末端。 在第二步中，通过在引发剂存在下的第一步获得的产物，不饱和聚氧乙烯醚，分子量调节剂和不饱和羧酸之间的自由基聚合制备最终的星形聚羧酸酯超增塑剂。 本发明的制造方法具有简单，容易控制，聚合度高，成本低，无污染等特点。 聚羧酸酯超增塑剂的星形分子结构可以通过酯化反应合成活性“核”，通过自由基聚合“臂”来实现。 表现出较好的水泥浆流动性和流动性保持性，与常规或较低剂量的传统线性和梳状聚羧酸盐超增塑剂相比，其表现出较好的水泥适应性和混凝土的施用性能。

公开(公告)号：US08519029B2

公开(公告)日：2013-08-27

申请号：US12477637

申请日：2009-06-03

Applicant: Klaus K. Lorenz ,  Alexander Kraus ,  Thomas M. Vickers, Jr. ,  Suzanne Lianopoulos ,  Viswanath Mahadevan

Inventor： Klaus K. Lorenz ,  Alexander Kraus ,  Thomas M. Vickers, Jr. ,  Suzanne Lianopoulos ,  Viswanath Mahadevan

IPC: C04B24/26 ,  C08F220/18

CPC classification number: C04B28/02 ,  C04B24/2647 ,  C04B24/2694 ,  C04B2103/308 ,  C08F216/1416 ,  C08F220/26 ,  Y10S526/915 ,  C04B2103/302

Abstract: A non-ionic polyether-polyester copolymer for extending workability to a cementitious mixture containing hydraulic cement and water, wherein the copolymer includes residues of at least the following monomers: Component A including an ethylenically unsaturated carboxylic acid ester monomer having a moiety hydrolysable in the cementitious mixture, wherein the hydrolyzed monomer residue has an active binding site for a component of the cementitious mixture; and, at least one of: Component B including an ethylenically unsaturated, carboxylic acid ester or alkenyl ether monomer having at least one C2-4 oxyalkylene side group of about 1 to 30 units; or, Component C including an ethylenically unsaturated, carboxylic acid ester or alkenyl ether monomer having at least one C2-4 oxyalkylene side group of 31 to about 350 units; wherein the molar ratio of Component A to the sum of the molar ratios of Component B and Component C is about 1:1 to about 10:1.

Abstract translation: 一种用于将可加工性延伸到含水硬性水泥和水的水泥混合物的非离子聚醚 - 聚酯共聚物，其中所述共聚物包括至少以下单体的残基：组分A，包括具有水解性可水解部分的烯键式不饱和羧酸酯单体 混合物，其中水解单体残余物具有水泥混合物组分的活性结合位点; 以及至少一种：包含具有约1至30个单元的具有至少一个C 2-4亚烷基侧基的烯键式不饱和羧酸酯或链烯基醚单体的组分B; 或包含具有31至约350单元的具有至少一个C 2-4亚烷基侧基的烯键式不饱和羧酸酯或链烯基醚单体的组分C; 其中组分A与组分B和组分C的摩尔比之和的摩尔比为约1:1至约10:1。

公开(公告)号：US08491717B2

公开(公告)日：2013-07-23

申请号：US13512466

申请日：2012-05-29

Applicant: Eric Koehler ,  Mark F. Roberts

Inventor： Eric Koehler ,  Mark F. Roberts

IPC: C04B7/36

CPC classification number: B28C5/08 ,  B28C7/024 ,  B29C35/0272 ,  B29C70/882 ,  C04B28/02 ,  C04B40/0032 ,  C04B2103/308 ,  C04B40/0028 ,  C04B2103/304 ,  C04B2103/408 ,  C04B2103/50 ,  C04B24/2641

Abstract: The invention relates to a method and system for monitoring and adjusting both air content and rheology (e.g., slump, slump flow) properties of a hydratable concrete mix contained within a concrete mixer. The system simultaneously tracks dosage of both rheology-modifying admixture (e.g., polycarboxylate polymer cement dispersant) and air control agent or “ACA” (e.g., air entraining agent) by reference to at least four nominal dose response (“NDR”) curves or profiles, which at least four NDR profiles are based on the respective behaviors of each of the ACA and rheology-modifying agent on air content and rheology.

Abstract translation: 本发明涉及用于监测和调节包含在混凝土搅拌机内的可水合混凝土混合物的空气含量和流变性（例如坍落度，坍落度流动）性质的方法和系统。 通过参考至少四个标称剂量反应（“NDR”）曲线，该系统同时跟踪流变改性混合物（例如，聚羧酸盐聚合物水泥分散剂）和空气控制剂或“ACA”（例如，加气剂） 轮廓，其中至少四个NDR轮廓基于每个ACA和流变改性剂对空气含量和流变学的各自行为。

公开(公告)号：US08242218B2

公开(公告)日：2012-08-14

申请号：US13114356

申请日：2011-05-24

Applicant: Klaus K. Lorenz ,  Alexander Kraus ,  Barbara Wimmer ,  Petra Wagner ,  Christian Scholz ,  Manfred Bichler

Inventor： Klaus K. Lorenz ,  Alexander Kraus ,  Barbara Wimmer ,  Petra Wagner ,  Christian Scholz ,  Manfred Bichler

IPC: C08F2/16 ,  C08F2/10 ,  C08F216/14

CPC classification number: C04B28/02 ,  C04B24/2647 ,  C04B24/2694 ,  C04B2103/308 ,  C08F216/1416 ,  C08F220/26 ,  Y10S526/915 ,  C04B2103/302

Abstract: Preparing a non-ionic copolymer having a hydrolysable monomer residue and a polyether macromonomer residue in a semicontinuous mode in a polymerization reactor associated with a metering device, including introducing polyether macromonomer and water into the reactor, wherein hydrolysable monomer which is added thereto forms a polymerization reaction mixture; introducing hydrolysable monomer into the metering device; adding hydrolysable monomer into the reactor from the metering device; passing a free radical polymerization initiator into the reactor before and/or during the addition of the hydrolysable monomer, the hydrolysable monomer and the polyether macromonomer reacting by free radical polymerization to form the non-ionic copolymer; and, subjecting the reaction mixture to polymerization while an addition rate of the hydrolysable monomer and/or at least a component of the polymerization initiator is varied stepwise or continuously. No monomer is introduced to incorporate ionic cement binding sites into the non-ionic copolymer.

Abstract translation: 在与计量装置相关联的聚合反应器中制备具有可水解单体残基和聚醚大分子单体残基的非离子共聚物，其包括将聚醚大分子单体和水引入反应器，其中加入的可水解单体形成聚合 反应混合物; 将可水解单体引入计量装置; 从计量装置将可水解单体加入到反应器中; 在可水解单体加入之前和/或期间将自由基聚合引发剂通入自由基聚合引发剂，可水解单体和聚醚大分子单体通过自由基聚合反应形成非离子共聚物; 并且使反应混合物进行聚合，同时可水解单体和/或至少一种聚合引发剂组分的添加速率逐步或连续地改变。 没有引入单体以将离子水泥结合位点引入非离子共聚物。

公开(公告)号：US20120041157A9

公开(公告)日：2012-02-16

申请号：US12681795

申请日：2008-10-09

Applicant: Takumi Sugamata ,  Tomomi Sugiyama ,  Raita Iwata

Inventor： Takumi Sugamata ,  Tomomi Sugiyama ,  Raita Iwata

IPC: C08L33/10 ,  C08L33/08

CPC classification number: C04B40/0039 ,  C04B2103/308 ,  C04B2103/32 ,  C04B2103/58 ,  C04B2111/29 ,  C04B24/2647 ,  C04B24/267 ,  C04B24/32

Abstract: To provide cement additives which render high fluidity and the retention thereof, excellent shrinkage reducing effect and frost-thaw resistance to cement compositions such as mortar and concrete without entraining excessive air, and exhibit excellent solution stability.The present cement additives contain alkenyl group-containing polyalkylene compounds (SR), ester-based polycarboxylic acid copolymers (PC1) and ether-based polycarboxylic acid copolymers (PC2).

Abstract translation: 提供赋予高流动性和保留性的水泥添加剂，优异的收缩减少效果和对水泥组合物如研钵和混凝土的抗冻融性，而不会引起过量的空气，并且表现出优异的溶液稳定性。 本发明的水泥添加剂含有含链烯基的聚亚烷基化合物（SR），酯类聚羧酸共聚物（PC1）和醚类聚羧酸共聚物（PC2）。

公开(公告)号：US20110160349A1

公开(公告)日：2011-06-30

申请号：US13061247

申请日：2009-08-26

Applicant: Lukas Frunz ,  Ueli Sulser ,  Jorg Zimmermann ,  Jurgen Gresser

Inventor： Lukas Frunz ,  Ueli Sulser ,  Jorg Zimmermann ,  Jurgen Gresser

IPC: C04B16/04 ,  C07C31/20 ,  C08G65/08 ,  C04B18/06 ,  C04B28/08 ,  C04B28/10 ,  C04B28/14

CPC classification number: C04B24/2647 ,  C04B24/2658 ,  C04B40/0039 ,  C04B2103/302 ,  C04B2103/308 ,  C04B24/06 ,  C04B24/10 ,  C04B24/18 ,  C04B24/223 ,  C04B24/226

Abstract: A polymer P for prolonging the flowability of water-reduced aqueous hydraulically setting compositions, and a method for prolonging the flowability of water-reduced aqueous hydraulically setting compositions.

Abstract translation: 用于延长水分降低水硬性组合物的流动性的聚合物P，以及用于延长水分降低的水硬性组合物的流动性的方法。

公开(公告)号：US20110088599A1

公开(公告)日：2011-04-21

申请号：US12997723

申请日：2009-07-10

Applicant: Hideo Koyata ,  Shuqiang Zhang ,  Byong-wa Chun

Inventor： Hideo Koyata ,  Shuqiang Zhang ,  Byong-wa Chun

IPC: C04B7/32

CPC classification number: C04B40/0039 ,  C04B20/023 ,  C04B2103/308 ,  C04B14/10 ,  C04B14/06 ,  C04B14/104 ,  C04B24/06 ,  C04B24/12 ,  C04B28/02 ,  C04B2103/40 ,  C04B24/005 ,  C04B24/2641 ,  C04B24/02 ,  C04B2103/0005 ,  C04B2103/32 ,  C04B24/2647 ,  C04B24/281 ,  C04B24/2652

Abstract: The present invention relates to the use of polycationic compound in combination with a hydroxycarboxylic acid or salt thereof to enhance slump retention in cements and concretes having clay-bearing aggregates, wherein the clay otherwise absorbs or diminishes the dosage efficiency of polycarboxylate superplasticizers.

Abstract translation: 本发明涉及聚阳离子化合物与羟基羧酸或其盐的组合用于增强具有含粘土聚集体的水泥和混凝土中的坍落度保留性，其中该粘土另外吸收或降低多羧酸盐超增塑剂的剂量效率。

公开(公告)号：US20110004332A1

公开(公告)日：2011-01-06

申请号：US12496529

申请日：2009-07-01

Applicant: Per Just Andersen

Inventor： Per Just Andersen

IPC: G06F17/50 ,  G05D11/13

CPC classification number: C04B40/0032 ,  C04B2103/308 ,  C04B28/02

Abstract: Methods of preparing design-optimized concrete compositions having target compressive strengths and slumps with a minimal amount of water are disclosed. In particular, the optimized concrete compositions are produced by analyzing pre-existing mix designs from a manufacture and determining the optimum amount of water required in the mix (i.e., optimized water to cement ratio) to obtain a target slump, yet allowing for the end-produced concrete composition to have a target compressive strength.

Abstract translation: 公开了以最小量的水制备具有目标抗压强度和坍落度的设计优化的混凝土组合物的方法。 特别地，优化的混凝土组合物通过分析来自制造商的预先存在的混合物设计并确定混合物中所需的最佳水量（即，优化的水与水泥比））来获得目标坍落度，但允许结束 产生具有目标抗压强度的混凝土组合物。

公开(公告)号：US20100113651A1

公开(公告)日：2010-05-06

申请号：US12593837

申请日：2008-05-22

Applicant: Daisuke Hamada ,  Kenichiro Yabe ,  Keiichiro Sagawa ,  Masaaki Shimoda ,  Yoshiaki Tanisho ,  Yoshinao Kono ,  Toshimasa Hamai

Inventor： Daisuke Hamada ,  Kenichiro Yabe ,  Keiichiro Sagawa ,  Masaaki Shimoda ,  Yoshiaki Tanisho ,  Yoshinao Kono ,  Toshimasa Hamai

IPC: C08K3/00 ,  C08F220/26 ,  C08F120/00

CPC classification number: C08F290/06 ,  C04B24/2647 ,  C04B28/02 ,  C04B2103/308 ,  C04B2103/408 ,  C08F220/06 ,  C08F220/14 ,  C08F220/28 ,  C08F290/00 ,  C08F290/061 ,  C08F290/062 ,  C08F2220/285

Abstract: The present invention provides a dispersion-retaining agent for a hydraulic composition being excellent in both fluidity retainability and viscosity retainability and further a dispersion-retaining agent exhibiting fluidity retainability and viscosity retainability regardless of the type of hydraulic powder. The present invention relates to a dispersion-retaining agent for a hydraulic composition, containing a copolymer obtained by polymerizing specific monomer 1 represented by formula (1), with monomer 2 represented by formula (2), the corresponding alcohol compound of which satisfies specific physical properties, wherein, in the constituent monomers of the copolymer, the proportion of the monomer 1 is in a specific range, a specified monomers is used as at least a part of the monomer 2, and the proportion of monomers having an acid group or a neutralized group thereof is 5% by weight or less.

Abstract translation: 本发明提供了一种水硬性组合物的分散保留剂，其流动性保持性和粘度保持性都优异，而且与液压粉末的种类无关，还具有表现出流动性保持性和粘度保持性的分散保留剂。 本发明涉及用于水硬性组合物的分散保留剂，其含有通过将由式（1）表示的特定单体1聚合而获得的共聚物与由式（2）表示的单体2相应，其相应的醇化合物满足特定的物理 性质，其中，在共聚物的构成单体中，单体1的比例在特定范围内，特定单体用作单体2的至少一部分，并且具有酸基或单体的比例 中和基团为5重量％以下。