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    PRODUCTION OF COMB POLYMERS BY MEANS OF ESTERIFICATION
    2.
    发明申请
    PRODUCTION OF COMB POLYMERS BY MEANS OF ESTERIFICATION 审中-公开
    通过纯化生产聚碳酸酯

    公开(公告)号：US20130217808A1

    公开(公告)日：2013-08-22

    申请号：US13879527

    申请日：2011-12-07

    Applicant: Ueli Sulser ,  Lukas Frunz ,  Jorg Zimmermann ,  Jurg Weidmann

    Inventor： Ueli Sulser ,  Lukas Frunz ,  Jorg Zimmermann ,  Jurg Weidmann

    IPC: C04B24/26

    CPC classification number: C04B24/2605 ,  C04B24/26 ,  C04B24/2647 ,  C04B24/2658 ,  C04B28/00 ,  C04B28/02 ,  C04B40/00 ,  C04B2103/32

    Abstract: The invention relates to a method for producing comb polymers, wherein at least one polycarboxylic acid or a salt thereof is esterified with at least one monohydroxy polyether, comprising the following steps: (a) preparing a reaction mixture containing at least one polycarboxylic acid; (b) heating the reaction mixture to at least 80° C.; (c) adding a base; and (d) esterifying the mixture at a reaction temperature of at least 80° C. obtaining a comb polymer, wherein at least one monohydroxy polyether is added to the reaction mixture in step (a) and/or (b). The invention further relates to comb polymers, cement compositions, molded bodies, and uses of comb polymers.

    Abstract translation: 本发明涉及一种生产梳形聚合物的方法，其中至少一种多元羧酸或其盐与至少一种单羟基聚醚酯化，包括以下步骤：（a）制备含有至少一种多元羧酸的反应混合物; （b）将反应混合物加热至至少80℃; （c）加入碱; 和（d）在至少80℃的反应温度下使混合物酯化，得到梳状聚合物，其中在步骤（a）和/或（b）中向反应混合物中加入至少一种单羟基聚醚。 本发明还涉及梳状聚合物，水泥组合物，成型体和梳状聚合物的用途。

    REGULATOR MOLECULE
    8.
    发明申请
    REGULATOR MOLECULE 有权
    调节器分子

    公开(公告)号：US20130109819A1

    公开(公告)日：2013-05-02

    申请号：US13806218

    申请日：2011-07-19

    Applicant: Ueli Sulser ,  Lukas Frunz ,  Jörg Zimmermann

    Inventor： Ueli Sulser ,  Lukas Frunz ,  Jörg Zimmermann

    IPC: C07F9/32 ,  C08F220/28

    CPC classification number: C07F9/3258 ,  C07F9/3264 ,  C07F9/4816 ,  C07F9/4825 ,  C07F9/485 ,  C07F9/5004 ,  C07F9/5018 ,  C07F9/5304 ,  C07F9/572 ,  C07F9/59 ,  C08F220/28 ,  C08K5/5313

    Abstract: The invention relates to a mono-substituted phosphinic acid and to the use thereof as a regulator in radical polymerization. Such regulators do not result in the formation of poorly soluble salts, and in addition, the polymers produced with the regulators according to the invention are characterized by a uniform polymerization degree having a narrow size distribution. In addition, the invention relates to a method for producing such mono-substituted phosphinic acids.

    Abstract translation: 本发明涉及单取代次膦酸及其在自由基聚合中作为调节剂的用途。 这种调节剂不会导致难溶性盐的形成，此外，用根据本发明的调节剂生产的聚合物的特征在于具有窄尺寸分布的均匀聚合度。 此外，本发明涉及一种制备这种单取代次膦酸的方法。

    Comb polymers with delayed alkaline hydrolysis
    9.
    发明授权
    Comb polymers with delayed alkaline hydrolysis 有权
    具有延迟碱性水解的梳理聚合物

    公开(公告)号：US09505861B2

    公开(公告)日：2016-11-29

    申请号：US14131938

    申请日：2012-08-31

    Applicant: Ueli Sulser ,  Jörg Zimmermann ,  Lukas Frunz

    Inventor： Ueli Sulser ,  Jörg Zimmermann ,  Lukas Frunz

    IPC: C08F220/06 ,  C04B24/26 ,  C08F216/14 ,  C08F220/36 ,  C04B103/40

    CPC classification number: C08F220/06 ,  C04B24/2647 ,  C04B2103/408 ,  C08F216/1416 ,  C08F220/36

    Abstract: Comb polymers having carboxyl/carboxylate and ester groups, containing a) 0.1-0.9 mol fractions of a partial structural unit S1, which is derived from an acrylic/methacrylic or maleic acid unit, b) 0-0.4 mol fractions of a partial structural unit S2, which is derived, for example, from an acrylic/methacrylic or maleic acid unit, which is esterified by means of a C1 to C20-alkanol or a polyalkylene glycol, alkyl-capped on one end, preferably a polyethylene glycol, and c) 0.1-0.4 mol fractions of a partial structural unit S3, which is derived from an acrylic/methacrylic or maleic acid unit, which is esterified by means of a polyalkylene glycol monoalkyl ether, which has a terminal, secondary hydroxyl group of the form-CH(R3)OH, wherein R3 is bulky alkyl group, preferably a methyl group.

    Abstract translation: 具有羧基/羧酸酯和酯基的梳理聚合物，其包含a）0.1-0.9摩尔部分结构单元S1的部分，其衍生自丙烯酸/甲基丙烯酸或马来酸单元，b）0-0.4摩尔部分结构单元 S2，其衍生自例如丙烯酸/甲基丙烯酸或马来酸单元，其通过C1至C20链烷醇或聚亚烷基二醇酯化，一端烷基封端，优选聚乙二醇，c ）0.1-0.4摩尔部分结构单元S3，其衍生自丙烯酸/甲基丙烯酸或马来酸单元，其通过聚亚烷基二醇单烷基醚酯化，所述聚亚烷基二醇单烷基醚具有末端的形成羟基的仲羟基， CH（R3）OH，其中R3是大体积烷基，优选甲基。

    COMB POLYMERS WITH DELAYED ALKALINE HYDROLYSIS
    10.
    发明申请
    COMB POLYMERS WITH DELAYED ALKALINE HYDROLYSIS 有权
    具有延迟碱性水解的COMB聚合物

    公开(公告)号：US20140163161A1

    公开(公告)日：2014-06-12

    申请号：US14131938

    申请日：2012-08-31

    Applicant: Ueli Sulser ,  Jörg Zimmermann ,  Lukas Frunz

    Inventor： Ueli Sulser ,  Jörg Zimmermann ,  Lukas Frunz

    IPC: C08F220/06

    CPC classification number: C08F220/06 ,  C04B24/2647 ,  C04B2103/408 ,  C08F216/1416 ,  C08F220/36

    Abstract: Comb polymers having carboxyl/carboxylate and ester groups, containing a) 0.1-0.9 mol fractions of a partial structural unit S1, which is derived from an acrylic/methacrylic or maleic acid unit, b) 0-0.4 mol fractions of a partial structural unit S2, which is derived, for example, from an acrylic/methacrylic or maleic acid unit, which is esterified by means of a C1 to C20-alkanol or a polyalkylene glycol, alkyl-capped on one end, preferably a polyethylene glycol, and c) 0.1-0.4 mol fractions of a partial structural unit S3, which is derived from an acrylic/methacrylic or maleic acid unit, which is esterified by means of a polyalkylene glycol monoalkyl ether, which has a terminal, secondary hydroxyl group of the form-CH(R3)OH, wherein R3 is bulky alkyl group, preferably a methyl group.

    Abstract translation: 具有羧基/羧酸酯和酯基的梳理聚合物，其包含a）0.1-0.9摩尔部分结构单元S1的部分，其衍生自丙烯酸/甲基丙烯酸或马来酸单元，b）0-0.4摩尔部分结构单元 S2，其衍生自例如丙烯酸/甲基丙烯酸或马来酸单元，其通过C1至C20链烷醇或聚亚烷基二醇酯化，一端烷基封端，优选聚乙二醇，c ）0.1-0.4摩尔部分结构单元S3，其衍生自丙烯酸/甲基丙烯酸或马来酸单元，其通过聚亚烷基二醇单烷基醚酯化，所述聚亚烷基二醇单烷基醚具有末端的形成羟基的仲羟基， CH（R3）OH，其中R3是大体积烷基，优选甲基。

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