A METHOD OF PRODUCING FILLER
    5.
    发明申请

    公开(公告)号:US20180112360A1

    公开(公告)日:2018-04-26

    申请号:US15562943

    申请日:2016-03-31

    Applicant: Stora Enso OYJ

    Abstract: The invention provides a method of producing a filler comprising calcium carbonate (PCC), preferably to be used in paper or paper board production or in fibre based composites. The method of the invention comprises the steps of; —providing fly ash generated in paper or paper board production; —fractionating said fly ash in at least one step, whereby a coarser fraction is separated from a finer fraction; —forming a suspension of said coarser fraction; —adding carbon dioxide to said suspension to form precipitated calcium carbonate. The method of the invention avoids problems with high amounts of arsenic and heavy metals in the production of filler comprising PCC, when using ash generated in paper or paper board production as a raw material. It has been shown that harmful elements, such as arsenic and heavy metals, are primarily accumulated in the finer fractions of the fly ash. Thus, by using the coarser fraction in the step of carbonation, the amount of arsenic and heavy metals in the final product is reduced.

    Surface treatment method for making high durability universal titanium dioxide rutile pigment
    7.
    发明授权
    Surface treatment method for making high durability universal titanium dioxide rutile pigment 有权
    表面处理方法制造高耐久性通用二氧化钛金红石颜料

    公开(公告)号:US09505022B2

    公开(公告)日:2016-11-29

    申请号:US13693667

    申请日:2012-12-04

    CPC classification number: B05D1/18 C01P2002/80 C01P2002/84 C09C1/3661 C09D7/62

    Abstract: A method is provided for the wet surface treatment of titanium dioxide, in order to produce durable universal grade titanium dioxide rutile pigment with superior optical properties. The method is characterized in that, a hydrous zirconia and silica composite layer is co-precipitated at acidic pH. Then, a layer of alumina is precipitated under a range of pH required for complete precipitation above the initial composite layer. The upper pH limit of the slurry during the alumina precipitation can be well controlled to avoid any chance for dissolution or damage of the composite zirconia-silica layer formed. Zirconia-silica composite layers and alumina thus precipitated advantageously improve the competence of the layers formed over a TiO2 base and provide improved durability with superior optical performance. The total surface treatment cycle time and chemicals used are minimal compared to conventional methods. Improvements in throughput and washing efficiency are also realized.

    Abstract translation: 提供了一种用于二氧化钛的湿表面处理的方法,以便产生具有优异光学性能的耐久的通用级二氧化钛金红石颜料。 该方法的特征在于,水合氧化锆和二氧化硅复合层在酸性pH下共沉淀。 然后,在初始复合层之上的完全沉淀所需的pH范围内沉淀出一层氧化铝。 氧化铝沉淀期间浆料的上限pH值可以很好地控制,以避免形成的复合氧化锆 - 二氧化硅层的任何溶解或损坏的机会。 氧化锆 - 二氧化硅复合层和由此沉淀的氧化铝有利地提高了形成在TiO 2基体上的层的能力,并提供了优异的光学性能的改善的耐久性。 与常规方法相比,总的表面处理循环时间和所用的化学品是最小的。 吞吐量和洗涤效率的提高也得以实现。

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