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    PROCESS FOR PRODUCTION OF OXYGEN-CONTAINING ORGANIC COMPOUND
    1.
    发明申请
    PROCESS FOR PRODUCTION OF OXYGEN-CONTAINING ORGANIC COMPOUND 失效
    生产含氧有机化合物的方法

    公开(公告)号：US20100331569A1

    公开(公告)日：2010-12-30

    申请号：US12919494

    申请日：2009-02-27

    Applicant: Minoru Takano ,  Naruhisa Hirai ,  Yasutaka Ishii

    Inventor： Minoru Takano ,  Naruhisa Hirai ,  Yasutaka Ishii

    IPC: C07C51/50

    CPC classification number: C07C45/33 ,  B01J27/053 ,  B01J37/0201 ,  C07C29/50 ,  C07C45/36 ,  C07C51/00 ,  C07C51/265 ,  C07C2603/74 ,  Y02P20/55 ,  C07C35/37 ,  C07C47/542 ,  C07C49/417 ,  C07C63/04

    Abstract: Disclosed is a process for the production of an oxygen-containing organic compound by oxidizing an organic compound with molecular oxygen in a liquid phase in the presence both of a catalytic nitrogen-containing cyclic compound and a catalyst including a solid superacid and, supported thereon, a transition metal compound, in which the nitrogen-containing cyclic compound contains, as a ring constituent, a skeleton represented by following Formula (1), wherein X represents an —OR group, and wherein R represents hydrogen atom or a hydroxyl-protecting group. The process gives the oxygen-containing organic compound in a high yield and enables easy recovery and reuse of the catalyst.

    Abstract translation: 本发明公开了一种在含有催化含氮环状化合物和含有固体超强酸的催化剂存在的条件下，通过在液相中用分子氧氧化有机化合物来制备含氧有机化合物的方法， 其中含氮环状化合物含有作为环成分的由下式（1）表示的骨架的过渡金属化合物，其中X表示-OR基，其中R表示氢原子或羟基保护基 。 该方法以高产率提供含氧有机化合物，并且能够容易地回收和再利用催化剂。

    Process for production of oxygen-containing organic compound
    3.
    发明授权
    Process for production of oxygen-containing organic compound 失效
    含氧有机化合物的制备方法

    公开(公告)号：US08410308B2

    公开(公告)日：2013-04-02

    申请号：US12919494

    申请日：2009-02-27

    Applicant: Minoru Takano ,  Naruhisa Hirai ,  Yasutaka Ishii

    Inventor： Minoru Takano ,  Naruhisa Hirai ,  Yasutaka Ishii

    IPC: C07C51/50

    CPC classification number: C07C45/33 ,  B01J27/053 ,  B01J37/0201 ,  C07C29/50 ,  C07C45/36 ,  C07C51/00 ,  C07C51/265 ,  C07C2603/74 ,  Y02P20/55 ,  C07C35/37 ,  C07C47/542 ,  C07C49/417 ,  C07C63/04

    Abstract: Disclosed is a process for the production of an oxygen-containing organic compound by oxidizing an organic compound with molecular oxygen in a liquid phase in the presence both of a catalytic nitrogen-containing cyclic compound and a catalyst including a solid superacid and, supported thereon, a transition metal compound, in which the nitrogen-containing cyclic compound contains, as a ring constituent, a skeleton represented by following Formula (1), wherein X represents an —OR group, and wherein R represents hydrogen atom or a hydroxyl-protecting group. The process gives the oxygen-containing organic compound in a high yield and enables easy recovery and reuse of the catalyst.

    Abstract translation: 本发明公开了一种在含有催化含氮环状化合物和含有固体超强酸的催化剂存在的条件下，通过在液相中用分子氧氧化有机化合物来制备含氧有机化合物的方法， 其中含氮环状化合物含有作为环成分的由下式（1）表示的骨架的过渡金属化合物，其中X表示-OR基，其中R表示氢原子或羟基保护基 。 该方法以高产率提供含氧有机化合物，并且能够容易地回收和再利用催化剂。

    Polymerizable adamantane derivatives and process for producing the same
    5.
    发明授权
    Polymerizable adamantane derivatives and process for producing the same 失效
    可聚合的金刚烷衍生物及其制备方法

    公开(公告)号：US06235851B1

    公开(公告)日：2001-05-22

    申请号：US09214724

    申请日：1999-01-11

    Applicant: Yasutaka Ishii ,  Tatsuya Nakano ,  Naruhisa Hirai

    Inventor： Yasutaka Ishii ,  Tatsuya Nakano ,  Naruhisa Hirai

    IPC: C08F2000

    CPC classification number: C07C67/03 ,  C07C2603/74 ,  C07C69/54

    Abstract: A compound shown by the following formula: wherein each of R1a, R2a, R3a and R4a represents a substituent selected from a non-reactive atom, a non-reactive group, a hydroxyl group and an amino group, and at least two members selected from R1a, R2a, R3a and R4a are a hydroxyl group, a carboxyl group or an amino group; is subjected to an esterification reaction or an amidation reaction with a polymerizable unsaturated compound (e.g., an alcohol, a carboxylic acid, an amine) in the presence of a catalyst comprising an element selected from the Group 3 elements, such as a samarium compound, to obtain a polymerizable adamantane derivative having at least one polymerizable unsaturated group in high yield.

    Abstract translation: 下式表示的化合物：其中R1a，R2a，R3a和R4a各自表示选自非反应性原子，非反应性基团，羟基和氨基的取代基，以及选自以下的至少两种： R1a，R2a，R3a和R4a是羟基，羧基或氨基; 在包含选自第3族元素的元素如钐化合物的催化剂存在下，与可聚合不饱和化合物（例如醇，羧酸，胺）进行酯化反应或酰胺化反应， 以高收率得到具有至少一个聚合性不饱和基团的聚合性金刚烷衍生物。

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