Abstract:
The invention relates to a method for the production of films in the thickness range of 20 ?m 1,000 ?m from thermoplastic plastics by extrusion of the plastic through a broad slot nozzle (4) and polishing of the melt film (5), escaping from the broad slot nozzle in a polishing unit, comprising at least three or four rollers (1, 2, 3), whereby a first roller pair (1, 2) forms a polishing gap for holding the melt film and the melt film is then run behind said polishing unit gap through a subsequent polishing gap or a subsequent pressing gap. The above is characterised in that the ratio of the width of the nozzle gap and the film thickness lies on the range 1:1 to 6:1 and the quotient of the film web speed in the subsequent polishing gap or the subsequent pressing gap divided by the film web speed in the polishing gap formed by the roller pair (1, 2) lies in the range 0.8 to 1.05.
Abstract:
The present invention describes a process for the surface finishing of materials via application of specific polymethacrylate layers. The polymethacrylate layers are composed of blends of at least two (co)polymers of polymethacrylates, and specific “reactive monomers” are present here in a polymerized mixture which forms the polymethacrylate layer. At the application temperature established, these form a chemical and, where appropriate, also a physical bond to the substrate, and therefore have adhesion-promoting action.
Abstract:
The invention relates to a moulding composition, comprising a) 50 to 99.9% by weight of a matrix composed of a thermoplastic polymer and b) from 0.1 to 50% by weight of a matting agent in the form of a (meth)acrylate copolymer dispersed in the matrix, characterized in that the matting agent is a (meth)acrylate copolymer which has been prepared from the following monomers, b1) from 50 to 95% by weight of methyl methacrylate b2) from 5 to 50% by weight of C1-C6-alkyl acrylates b3) from 0.01 to less than 0.5% by weight of a crosslinking monomer and/or graft-linking agent having two or more ethylenically unsaturated radicals capable of free-radical polymerization, b4) from 0 to 20% by weight of one or more other, non-crosslinking ethylenically unsaturated monomers capable of free-radical polymerization, where the entirety of the constituents b1) and b2) and, where appropriate, b3) and/or b4) gives 100% by weight, and the glass transition temperature Tmg of the matting agent is at least 20° C.
Abstract:
The invention concerns a mixture or polymer composite of a copolymer (CP) comprising between 70 and 99.9 wt % methylmethacrylate, between 0.1 and 5 wt % maleic acid anhydride and between 0 and 25 wt % further vinylically copolymerizable monomers which, apart from the vinyl function, have no further function groups, with a polymethacrylate-compatible plastics (VK) and a polymer (PN) which contains at least one terminal nucleophilic groups.
Abstract:
The invention relates to composites VS comprising at least two plastic layers A and C, suitable for the production of articles which, on one surface, come into contact with water at temperatures between 0.degree. and 90.degree. C., wherein the layer A, which comes into contact with water, comprises a thermoplastic, impact-resistant polymethyl methacrylate plastic SP having a Vicat softening temperature of at least 95.degree. C. according to ISO 306 procedure B and a notch impact resistance of at least 3.0 kJm.sup.-2 according to ISO 180 1A, and layer C comprises an impact-resistant acrylonitrile-styrene copolymer VP. In a preferred specific embodiment of the invention, another layer B, made of a thermoplastic polymethyl methacrylate plastic P, is placed between layers A and C.
Abstract:
The invention relates to surface enhancements for composite mouldings made from polymeric materials and to the use thereof in solar systems. These solar systems may be solar reflectors for concentrating solar radiation, flexible photovoltaic composite films, or CPV (Concentrated Photovoltaics) lenses for concentrating solar radiation.The surface enhancement comprises a self-healing coating based on crosslinkable fluoropolymers, e.g. PFEVE (polyfluoroethylene alkylvinyl ethers). These coatings exhibit good optical properties, can be used in outdoor applications, more particularly in solar applications, over very long periods of time, exhibit self-cleaning properties, and in particular are self-healing in relation to mechanical damage—such as scratching.
Abstract:
The invention describes a composite in which solar cells can be encapsulated, being a photovoltaic module, composed of the following elements: an outer layer made of a transparent thermoplastic and/or a barrier foil, and an elastic layer into which the solar cells have been embedded and a barrier foil or a barrier sheet.
Abstract:
The present invention relates to a plastics mixture comprising at least one thermoplastic polyurethane A) and at least one impact-modified poly(meth)acrylate B), where the impact-modified poly(meth)acrylate comprises a hard phase whose glass transition temperature is at least 70° C. and a tough phase whose glass transition temperature is at most −10° C., the average particle size of the tough phase is at most 130 nm, and at least a portion of the tough phase has covalent linkage to the hard phase.
Abstract:
The invention describes a transparent foil composed of plastic with improved weathering resistance and increased intrinsic stability where the foil encompassesa) poly(meth)acrylate and polyvinylidene fluoride in a ratio of from 1:0.01 to 1:1 (w/w); andb) a mixture composed of UV stabilizers and of UV absorbers.PMMA matrix plastics with high molecular weights and with a certain selected coacrylate proportion are preferably used in order to achieve excellent weathering resistance, and also improved intrinsic stability of the surface-protection foils.
Abstract:
An impact resistant provided PMMA moulding material according to DE 195 44 563 is process into a surface-hardened film which is highly glossy, essentially free of gel bodies and can be processed in the “in-mould-film-decoration” method. The melted mass is generated by means of an extruder and fed to the inventive glazing rolls via a flexible lip nozzle, saild rolls being configured in order to generate an especially high locking pressure in the roll slit. The smoothing rolls are cambered. The films are used for decorating surfaces of high-value thermoplastic moulded parts.