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公开(公告)号：US11708438B2
公开(公告)日：2023-07-25
申请号：US17330942
申请日：2021-05-26
发明人： Timothy M. Boller , Ching-Tai Lue , Francis C. Rix , Daniel P. Zilker, Jr. , C. Jeff Harlan , James M. Farley , Fathi David Hussein , Dongming Li , Steven A. Best
IPC分类号： C08F4/6592 , C08F4/653 , C08F210/16 , C08L23/08 , C08F4/659 , C07F17/00 , C08J5/18 , C08F4/643 , C08F210/02 , C08F4/76 , C08F2/00 , C08F2/34 , C08F210/14 , C08F210/08
CPC分类号： C08F210/16 , C07F17/00 , C08F2/00 , C08F2/34 , C08F4/6432 , C08F4/65904 , C08F4/76 , C08F210/02 , C08J5/18 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F210/08 , C08F210/14 , C08F2410/02 , C08F2420/00 , C08F2420/01 , C08F2500/01 , C08F2500/02 , C08F2500/08 , C08F2500/09 , C08F2500/10 , C08F2500/11 , C08F2500/12 , C08F2500/13 , C08F2500/18 , C08F2800/20 , C08J2323/08 , C08L23/0815 , C08F210/16 , C08F4/65904 , C08F210/16 , C08F210/14 , C08F2500/12 , C08F2500/10 , C08F2500/08 , C08F210/16 , C08F210/14 , C08F2500/08 , C08F2500/12 , C08F210/16 , C08F210/14 , C08F2500/12 , C08F2500/10 , C08F2500/08 , C08F2500/03 , C08F210/16 , C08F2/00 , C08F210/16 , C08F2/34
摘要： A system and method of producing polyethylene, including: polymerizing ethylene in presence of a catalyst system in a reactor to form polyethylene, wherein the catalyst system includes a first catalyst and a second catalyst; and adjusting reactor conditions and an amount of the second catalyst fed to the reactor to control melt index (MI), density, and melt flow ratio (MFR) of the polyethylene.
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公开(公告)号：US10308742B2
公开(公告)日：2019-06-04
申请号：US15116309
申请日：2015-02-10
发明人： Ching-Tai Lue , Francis C. Rix , Timothy M. Boller , Garth R. Giesbrecht , Mark G. Goode , Sun-Chueh Kao , Dongming Li , R. Eric Pequeno , Daniel P. Zilker, Jr.
IPC分类号： C08F210/16 , C08F4/653 , C08F4/6592 , C08L23/08 , C08F4/659 , C07F17/00 , C08F210/02 , C08F4/76 , C08F2/00 , C08F2/34 , C08J5/18 , C08F210/14 , C08F210/08
摘要： Polymers, and systems and methods for making and using the same are described herein. A polymer includes ethylene and at least one alpha olefin having from 4 to 20 carbon atoms. The polymer is formed by a trimmed catalyst system including a supported catalyst including bis(n-propylcyclopentadienyl) hafnium (R1)(R2) and a trim catalyst comprising meso-O(SiMe2Ind)2Zr(R1)(R2), wherein R1 and R2 are each, independently, methyl, chloro, fluoro, or a hydrocarbyl group.
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公开(公告)号：US09902790B2
公开(公告)日：2018-02-27
申请号：US15117789
申请日：2015-02-10
发明人： Daniel D. Vanderlende , C. Jeff Harlan , Haiqing Peng , Michael D. Awe , Roger L. Kuhlman , Ching-Tai Lue , Timothy R. Lynn , Wesley R. Mariott , Daniel P. Zilker, Jr.
IPC分类号： C08F4/653 , C08F4/6592 , C08L23/08 , C08F210/16 , C08F4/659 , C07F17/00 , C08F210/02 , C08F4/76 , C08F210/14 , C08F210/08
CPC分类号： C08F210/16 , C07F17/00 , C08F2/00 , C08F2/34 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F4/76 , C08F210/02 , C08F210/08 , C08F210/14 , C08F2410/02 , C08F2420/00 , C08F2420/01 , C08F2500/01 , C08F2500/02 , C08F2500/08 , C08F2500/09 , C08F2500/10 , C08F2500/11 , C08F2500/12 , C08F2500/13 , C08F2500/18 , C08F2800/20 , C08J5/18 , C08J2323/08 , C08L23/0815 , C08F2500/03
摘要： A method of polymerizing olefins is disclosed. The method comprises contacting ethylene and at least one comonomer with a catalyst system to produce a polyolefin polymer that is multimodal. The catalyst system comprises a first catalyst that promotes polymerization of the ethylene into a low molecular weight (LMW) portion of the polyolefin polymer and a second catalyst that promotes polymerization of the ethylene into a high molecular weight (HMW) portion of the polyolefin polymer. The first catalyst and at least a portion of the second catalyst are co-supported to form a commonly-supported catalyst system and at least a portion of the second catalyst is added as a catalyst trim feed to the catalyst system.
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公开(公告)号：US11034783B2
公开(公告)日：2021-06-15
申请号：US16278212
申请日：2019-02-18
发明人： Timothy M. Boller , Ching-Tai Lue , Francis C. Rix , Daniel P. Zilker, Jr. , C. Jeff Harlan , James M. Farley , Fathi David Hussein , Dongming Li , Steven A. Best
IPC分类号： C08L23/08 , C08F210/16 , C08F4/6592 , C08F4/659 , C07F17/00 , C08J5/18 , C08F210/02 , C08F4/76 , C08F2/00 , C08F2/34 , C08F210/14 , C08F210/08
摘要： A system and method of producing polyethylene, including: polymerizing ethylene in presence of a catalyst system in a reactor to form polyethylene, wherein the catalyst system includes a first catalyst and a second catalyst; and adjusting reactor conditions and an amount of the second catalyst fed to the reactor to control melt index (MI), density, and melt flow ratio (MFR) of the polyethylene.
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公开(公告)号：US10399052B2
公开(公告)日：2019-09-03
申请号：US15528976
申请日：2015-11-24
发明人： Bruce J. Savatsky , Natarajan Muruganandam , Timothy R. Lynn , James M. Farley , Daniel P. Zilker, Jr. , Fathi David Hussein
摘要： The use of induced condensing agent (ICA) in fluidized bed gas phase reactor systems enables higher production rates but can affect the resulting polyolefins melt index. The effect the increased ICA concentration may have on a melt index may be counteracted, if necessary, by altering the concentration of olefin monomer within the reactor system.
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公开(公告)号：US10167351B2
公开(公告)日：2019-01-01
申请号：US15527023
申请日：2015-11-24
发明人： Bruce J. Savatsky , Natarajan Muruganandam , Timothy R. Lynn , James M. Farley , Daniel P. Zilker, Jr. , Fathi David Hussein
IPC分类号： B01J8/18 , C08F2/34 , C08F110/02 , C08F10/02
摘要： The catalyst productivity of a polyolefin catalyst in the methods disclosed herein may be increased by increasing the concentration of an induced condensing agent (ICA) in the reactor system. The effect the increased ICA concentration may have on a melt index may be counteracted, if necessary, in various ways.
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公开(公告)号：US20170259236A1
公开(公告)日：2017-09-14
申请号：US15528976
申请日：2015-11-24
发明人： Bruce J. Savatsky , Natarajan Muruganandam , Timothy R. Lynn , James M. Farley , Daniel P. Zilker, Jr. , Fathi David Hussein
CPC分类号： B01J8/1809 , B01J8/24 , B01J2208/00539 , C08F2/001 , C08F2/34 , C08F10/02 , C08F110/02 , C08F2500/12
摘要： The use of induced condensing agent (ICA) in fluidized bed gas phase reactor systems enables higher production rates but can affect the resulting polyolefins melt index. The effect the increased ICA concentration may have on a melt index may be counteracted, if necessary, by altering the concentration of olefin monomer within the reactor system.
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公开(公告)号：US09850332B2
公开(公告)日：2017-12-26
申请号：US15116250
申请日：2015-02-10
发明人： Ching-Tai Lue , Francis C. Rix , Timothy M. Boller , Garth R. Giesbrecht , Mark G. Goode , Sun-Chueh Kao , Dongming Li , R. Eric Pequeno , James M. Farley , Daniel P. Zilker, Jr.
IPC分类号： C08F210/02 , C08F210/08 , C08F210/14 , C08F4/76 , C08F210/16 , C08F4/659 , C07F17/00 , C08L23/08 , C08F4/6592
CPC分类号： C08F210/16 , C07F17/00 , C08F2/00 , C08F2/34 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F4/76 , C08F210/02 , C08F210/08 , C08F210/14 , C08F2410/02 , C08F2420/00 , C08F2420/01 , C08F2500/01 , C08F2500/02 , C08F2500/08 , C08F2500/09 , C08F2500/10 , C08F2500/11 , C08F2500/12 , C08F2500/13 , C08F2500/18 , C08F2800/20 , C08J5/18 , C08J2323/08 , C08L23/0815 , C08F2500/03
摘要： Polymers, and systems and methods for making and using the same are described herein. A polymer includes ethylene and at least one alpha olefin having from 4 to 20 carbon atoms. The polymer has a melt index ratio (MIR) greater than about 40. The polymer also has a value for Mw1/Mw2 of at least about 2.0, wherein Mw1/Mw2 is a ratio of a weight average molecular weight (Mw) for a first half of a temperature rising elution (TREF) curve from a cross-fractionation (CFC) analysis to an Mw for a second half of the TREF curve. The polymer also has a value for Tw1−Tw2 of less than about −15° C., wherein Tw1−Tw2 is a difference of a weight average elution temperature (Tw) for the first half of the TREF curve to a Tw for the second half of the TREF curve.
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9.发明申请公开(公告)号：US20170355790A1
公开(公告)日：2017-12-14
申请号：US15527957
申请日：2015-11-24
IPC分类号： C08F110/02 , B01J13/00 , B01J8/18
CPC分类号： C08F110/02 , B01J8/003 , B01J8/0055 , B01J8/006 , B01J8/1809 , B01J8/1818 , B01J8/1827 , B01J8/1836 , B01J13/0065 , B01J2208/00053 , B01J2208/00061 , B01J2208/00274 , B01J2208/00557 , B01J2208/00628 , B01J2208/00637 , B01J2208/00982 , B01J2208/00991 , B01J2219/002 , B01J2219/00213 , B01J2219/00238 , C08F210/16 , C08F2/34 , C08F2/001 , C08F210/14 , C08F2500/12 , C08F2500/26
摘要： The number of small gels that form in polyolefin thin films may be reduced by altering certain production parameters of the polyolefin. In some instances, the number of small gels may be influenced by the melt index of the polyolefin. However, in many instances, melt index is a critical part of the polyolefin product specification and, therefore, is not manipulated. Two parameters that may be manipulated to mitigate small gel count while maintaining the melt index are polyolefin residence time in the reactor and ICA concentration in the reactor.
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10.发明申请PRODUCING POLYOLEFIN PRODUCTS WITH IMPROVED STIFFNESS, TOUGHNESS, AND PROCESSABILITY 有权生产具有改善的韧性，韧性和可加工性的聚烯烃产品公开(公告)号：US20160347888A1
公开(公告)日：2016-12-01
申请号：US15116250
申请日：2015-02-10
发明人： Ching-Tai Lue , Francis C. Rix , Timothy M. Boller , Garth R. Giesbrecht , Mark G. Goode , Sun-Chueh Kao , Dongming Li , R. Eric Pequeno , James M. Farley , Daniel P. Zilker, Jr.
IPC分类号： C08F210/16
CPC分类号： C08F210/16 , C07F17/00 , C08F2/00 , C08F2/34 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F4/76 , C08F210/02 , C08F210/08 , C08F210/14 , C08F2410/02 , C08F2420/00 , C08F2420/01 , C08F2500/01 , C08F2500/02 , C08F2500/08 , C08F2500/09 , C08F2500/10 , C08F2500/11 , C08F2500/12 , C08F2500/13 , C08F2500/18 , C08F2800/20 , C08J5/18 , C08J2323/08 , C08L23/0815 , C08F2500/03
摘要： Polymers, and systems and methods for making and using the same are described herein. A polymer includes ethylene and at least one alpha olefin having from 4 to 20 carbon atoms. The polymer has a melt index ratio (MIR) greater than about 40. The polymer also has a value for Mw1/Mw2 of at least about 2.0, wherein Mw1/Mw2 is a ratio of a weight average molecular weight (Mw) for a first half of a temperature rising elution (TREF) curve from a cross-fractionation (CFC) analysis to an Mw for a second half of the TREF curve. The polymer also has a value for Tw1−Tw2 of less than about −15° C., wherein Tw1−Tw2 is a difference of a weight average elution temperature (Tw) for the first half of the TREF curve to a Tw for the second half of the TREF curve.
摘要翻译： 本文描述了聚合物，以及用于制备和使用聚合物的系统和方法。 聚合物包括乙烯和至少一种具有4至20个碳原子的α-烯烃。 聚合物具有大于约40的熔体指数比（MIR）。该聚合物还具有至少约2.0的Mw1 / Mw2的值，其中Mw1 / Mw2是第一个（重量）的重均分子量（Mw） 从循环分馏（CFC）分析到TREF曲线的后半段的Mw的升温洗脱（TREF）曲线的一半。 所述聚合物还具有小于约-15℃的Tw1-Tw2的值，其中Tw1-Tw2是TREF曲线的前半部分的重均平均洗脱温度（Tw）与第二次的Tw之间的Tw的差值 一半的TREF曲线。
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