公开(公告)号：US06218475B1

公开(公告)日：2001-04-17

申请号：US09205608

申请日：1998-12-04

申请人： Tomoki Hiiro ,  Shinji Ozawa ,  Taizo Aoyama

发明人： Tomoki Hiiro ,  Shinji Ozawa ,  Taizo Aoyama

IPC分类号： C08F29300

CPC分类号： C08L53/00 ,  C08F297/00 ,  C08L53/005 ,  C08L2666/04 ,  C08L2666/02

摘要： The present invention has its object to provide an isobutylene group block copolymer containing a highly reactive alkenyl group with a high rate of introduction of an alkenyl, and process for producing the same. An alkenyl-group-containing isobutylene group block copolymer comprising a polymer block derived from (a) a monomer component containing isobutylene group as a predominant monomer and (b) a monomer component not containing isobutylene group as a predominant monomer, in which said block copolymer has an alkenyl group of the following general formula (1).

摘要翻译： 本发明的目的是提供一种含有引入链烯基的高反应性链烯基的异丁烯基嵌段共聚物及其制备方法。含烯基基团的异丁烯基嵌段共聚物包含聚合物嵌段 衍生自（a）含有异丁烯基作为主要单体的单体组分和（b）不含异丁烯基作为主要单体的单体组分，其中所述嵌段共聚物具有以下通式（1）的链烯基。

公开(公告)号：US06515083B2

公开(公告)日：2003-02-04

申请号：US09788525

申请日：2001-02-21

申请人： Shinji Ozawa ,  Toshinobu Nakata ,  Tomoki Hiiro ,  Taizo Aoyama

发明人： Shinji Ozawa ,  Toshinobu Nakata ,  Tomoki Hiiro ,  Taizo Aoyama

IPC分类号： C08F29700

CPC分类号： C08F297/00

摘要： A process for producing an isobutylene block copolymer, which comprises performing cationic polymerization of a monomer component containing isobutylene as a major monomer and a monomer component whose major monomer is not isobutylene in the presence of an initiator, wherein the polymerization is carried out in a mixed solvent containing a monohalogenated hydrocarbon solvent and a non-halogenated hydrocarbon solvent the monohalogenated hydrocarbon solvent containing a primary monohalogenated hydrocarbon having three to eight carbon atoms and/or a secondary monohalogenated hydrocarbon having three to eight carbon atoms, the non-halogenated hydrocarbon solvent containing an aliphatic hydrocarbon and/or an aromatic hydrocarbon.

公开(公告)号：US06348546B2

公开(公告)日：2002-02-19

申请号：US09785179

申请日：2001-02-20

申请人： Tomoki Hiiro ,  Shinji Ozawa ,  Taizo Aoyama

发明人： Tomoki Hiiro ,  Shinji Ozawa ,  Taizo Aoyama

IPC分类号： C08F29300

CPC分类号： C08F297/06 ,  C08F255/08 ,  C08F230/08

摘要： The present invention has its object to provide an isobutylene group block copolymer containing a highly reactive alkenyl group with a high rate of introduction of an alkenyl, and process for producing the same. An alkenyl-group-containing isobutylene group block copolymer comprising a polymer block derived from (a) a monomer component containing isobutylene group as a predominant monomer and (b) a monomer component not containing isobutylene group as a predominant monomer, in which said block copolymer has an alkenyl group of the following general formula (1).

摘要翻译： 本发明的目的是提供一种含有引入链烯基的高反应性链烯基的异丁烯基嵌段共聚物及其制备方法。含烯基基团的异丁烯基嵌段共聚物包含聚合物嵌段 衍生自（a）含有异丁烯基作为主要单体的单体组分和（b）不含异丁烯基作为主要单体的单体组分，其中所述嵌段共聚物具有以下通式（1）的链烯基。

公开(公告)号：US07056983B2

公开(公告)日：2006-06-06

申请号：US09446521

申请日：1999-04-28

申请人： Yoshiki Nakagawa ,  Masayuki Fujita ,  Kenichi Kitano ,  Tomoki Hiiro ,  Katsuhiko Kimura

发明人： Yoshiki Nakagawa ,  Masayuki Fujita ,  Kenichi Kitano ,  Tomoki Hiiro ,  Katsuhiko Kimura

IPC分类号： C08F20/18 ,  C08F255/00

CPC分类号： C08F290/02 ,  C08F293/005 ,  C08F297/00 ,  C08F2438/01

摘要： Processes for producing an AB block copolymer, an ABA block copolymer or a multiblock copolymer are provided, which comprises adding an alkenyl-containing polymer (I) to a living or to an atom transfer radical polymerization system or a living cationic polymerization system.

摘要翻译： 提供了制备AB嵌段共聚物，ABA嵌段共聚物或多嵌段共聚物的方法，其包括向活性或原子转移自由基聚合体系或活性阳离子聚合体系中加入含链烯基的聚合物（I）。

公开(公告)号：US20050085592A1

公开(公告)日：2005-04-21

申请号：US10503024

申请日：2003-02-12

申请人： Akio Taniguchi ,  Kentaro Takesada ,  Yutaka Keneda ,  Tadashi Kokubo ,  Nobuaki Ohshiro ,  Atsushi Kumasaki ,  Takeshi Chiba ,  Tomoki Hiiro

发明人： Akio Taniguchi ,  Kentaro Takesada ,  Yutaka Keneda ,  Tadashi Kokubo ,  Nobuaki Ohshiro ,  Atsushi Kumasaki ,  Takeshi Chiba ,  Tomoki Hiiro

IPC分类号： C08F293/00 ,  C08F2/00

CPC分类号： C08F293/00 ,  C08F293/005 ,  Y10T428/1352 ,  Y10T428/1386 ,  Y10T428/139

摘要： The present invention relates to a block copolymer (A) including a (meth)acrylic polymer block (a) and an acrylic polymer block (b). The (meth)acrylic polymer block (a) is preferably copolymerized with a monomer having a functional group having high cohesive force, such as a carboxyl group, so that the 5%-weight-loss temperature is 300° C. or more or the tensile strength is 3 MPa or more, and the hardness measured by a type A durometer according to JIS K6253 is 50 or less, and a compression set measured after 22 hours at 70° C. is 45% or less. The block copolymer (A) exhibits excellent thermal decomposition resistance and low compression set at high temperatures. The block copolymer (A) can be used as a soft material for automobile, and has low hardness, high adhesion, high oil resistance, high weather resistance, high heat resistance, high recycling property, high tensile properties, and high wax remover resistance.

公开(公告)号：US20050004318A1

公开(公告)日：2005-01-06

申请号：US10492359

申请日：2002-11-13

申请人： Nobuaki Ohshiro ,  Ryotaro Tsuji ,  Tomoki Hiiro

发明人： Nobuaki Ohshiro ,  Ryotaro Tsuji ,  Tomoki Hiiro

IPC分类号： C08F2/38 ,  C08F8/42 ,  C08F220/00 ,  C08L101/00 ,  C08L101/10 ,  C08F220/02 ,  C08F220/62

CPC分类号： C08L101/10 ,  C08F2/38 ,  C08F220/00

摘要： The present invention provides a curable composition that comprises a polymer (A) containing a cross-linkable silyl group and a condensation catalyst (B). The polymer (A) containing a cross-linkable silyl group is obtained by a process comprising the steps of conducting a radical polymerizable monomer in the presence of a thiocarbonylthio compound. For example, the polymer (A) is obtained by (i) initiating a reversible addition-fragmentation chain transfer polymerization of a radical polymerizable monomer in the presence of a thiocarbonylthio compound, and (ii) adding an unsaturated compound containing a cross-linkable silyl group for copolymerization when a consumed amount of the radical polymerizable monomer by the polymerization has reached a level of 80% or more.

摘要翻译： 本发明提供一种包含含有可交联甲硅烷基的聚合物（A）和缩合催化剂（B）的固化性组合物。 含有可交联甲硅烷基的聚合物（A）通过包括以下步骤的方法获得：在硫代羰基硫代化合物的存在下进行自由基聚合单体。 例如，聚合物（A）通过（i）在硫代羰基硫代化合物的存在下引发可自由基聚合的单体的可逆加成 - 断裂链转移聚合而获得，和（ii）加入含有可交联甲硅烷基 当通过聚合反应的自由基聚合性单体的消耗量达到80％以上时，进行共聚。

公开(公告)号：US20090227738A1

公开(公告)日：2009-09-10

申请号：US11915407

申请日：2006-05-26

申请人： Katsuyuki Tanaka ,  Hirosuke Kawabata ,  Tomoki Hiiro

发明人： Katsuyuki Tanaka ,  Hirosuke Kawabata ,  Tomoki Hiiro

IPC分类号： C08L39/04

CPC分类号： C08L33/24 ,  C08F8/32 ,  C08F8/48 ,  C08F2800/20 ,  C08L35/06 ,  C08L2666/04 ,  C08F120/14 ,  C08F220/14

摘要： It is an object of the present invention to provide a resin composition whose birefringence has been controlled. The object can be attained by a resin composition composed essentially of a resin (A) containing glutarimide units and acrylic ester units and a resin (B) containing glutarimide units, acrylic ester units, and aromatic vinyl units. The resin composition of the present invention is easy to manufacture, inexpensive, excellent in terms of transparency and heat resistance, and easily controllable in terms of orientation birefringence. Further, the resin composition of the present invention can be developed to be applied to an optical molding product of which transparency and heat resistance are required.

摘要翻译： 本发明的目的是提供一种其双折射已被控制的树脂组合物。 该目的可以通过基本上由含有戊二酰亚胺单元和丙烯酸酯单元的树脂（A）和含有戊二酰亚胺单元，丙烯酸酯单元和芳族乙烯基单元的树脂（B）组成的树脂组合物来实现。 本发明的树脂组合物易于制造，廉价，透明性和耐热性优异，并且在取向双折射方面容易控制。 此外，本发明的树脂组合物可以开发适用于需要透明性和耐热性的光学成型产品。

公开(公告)号：US20080318072A1

公开(公告)日：2008-12-25

申请号：US10581267

申请日：2004-12-01

申请人： Hirosuke Kawabata ,  Tomoki Hiiro ,  Yasuhiro Sekiguchi ,  Kazuhito Wada ,  Kimihide Nishimura ,  Norito Doi

发明人： Hirosuke Kawabata ,  Tomoki Hiiro ,  Yasuhiro Sekiguchi ,  Kazuhito Wada ,  Kimihide Nishimura ,  Norito Doi

IPC分类号： B32B15/08 ,  C08F120/06 ,  C08F8/32

CPC分类号： C08G73/10 ,  C08F8/48 ,  C08F2800/20 ,  Y10T428/31692 ,  C08F8/32 ,  C08F220/14 ,  C08F212/08

摘要： To realize an imide resin which is favorable in optical use.The imide resin according to the present invention includes: a repeating unit represented by General Formula (1); a repeating unit represented by General Formula (2); and a repeating unit represented by General Formula (3), wherein an orientation birefringence of the imide resin ranges from −0.1×10−3 to 0.1×10−3, where each of R1 and R2 independently represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and R3 represents a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms, or an aryl group having 6 to 10 carbon atoms, where each of R4 and R5 independently represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and R6 represents an alkyl group having 1 to 18 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms, or an aryl group having 6 to 10 carbon atoms, where R7 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and R8 represents an aryl group having 6 to 10 carbon atoms.

摘要翻译： 实现光学用途有利的酰亚胺树脂。 根据本发明的酰亚胺树脂包括：由通式（1）表示的重复单元; 由通式（2）表示的重复单元; 和由通式（3）表示的重复单元，其中酰亚胺树脂的取向双折射率为-0.1×10-3至0.1×10-3，其中R1和R2各自独立地表示氢原子或具有1个 至8个碳原子，并且R 3表示氢原子，具有1至18个碳原子的烷基，具有3至12个碳原子的环烷基或具有6至10个碳原子的芳基，其中R 4和R 5各自独立地 表示氢原子或碳原子数1〜8的烷基，R 6表示碳原子数1〜18的烷基，碳原子数3〜12的环烷基或碳原子数6〜10的芳基， R7表示氢原子或碳原子数1〜8的烷基，R8表示碳原子数6〜10的芳基。

公开(公告)号：US07094833B2

公开(公告)日：2006-08-22

申请号：US10482963

申请日：2002-07-01

申请人： Ryotaro Tsuji ,  Tomoki Hiiro

发明人： Ryotaro Tsuji ,  Tomoki Hiiro

IPC分类号： C08F251/00 ,  C08F255/02

CPC分类号： C08L53/00 ,  C08F293/00 ,  C08F293/005

摘要： Provided are a block copolymer including a polymer block containing acrylonitrile or methacrylonitrile as a principal constituent, which is excellent in heat resistance, weatherability, oil resistance, flame retardancy, and low-temperature resistance and which can be economically produced; and a thermoplastic resin composition and an elastomer composition each containing the block copolymer. The block copolymer is produced by reversible addition-fragmentation chain transfer polymerization in the presence of a thiocarbonylthio group-containing compound.

摘要翻译： 提供一种包含含有丙烯腈或甲基丙烯腈作为主要成分的聚合物嵌段的嵌段共聚物，其耐热性，耐候性，耐油性，阻燃性和耐低温性优异，可以经济地制备; 以及各自含有嵌段共聚物的热塑性树脂组合物和弹性体组合物。 嵌段共聚物是通过在含有硫代羰基硫基的化合物的存在下进行的可逆加成 - 断裂链转移聚合来制备的。

公开(公告)号：US20060004171A1

公开(公告)日：2006-01-05

申请号：US11207792

申请日：2005-08-22

申请人： Ryotaro Tsuji ,  Tomoki Hiiro

发明人： Ryotaro Tsuji ,  Tomoki Hiiro

IPC分类号： C08G77/12 ,  C08G77/04

CPC分类号： C08F291/00 ,  C08F2/38 ,  C08F8/30 ,  C08F8/32 ,  C08F8/34 ,  C08F8/42 ,  C08F257/02 ,  C08F261/04 ,  C08F265/04 ,  C08F273/00 ,  C08F283/008 ,  C08F290/04 ,  C08F290/06

摘要： Objects of the present invention are to provide a process for easily producing an alkenyl-terminated vinyl polymer without using a metal compound requiring a complicated purification step, and to provide a curable composition containing the vinyl polymer. An alkenyl group is incorporated into an end of a vinyl polymer having a thiocarbonylthio structure at the end to produce an alkenyl-terminated vinyl polymer. Mixing this vinyl polymer with a compound having a hydrogen-silicon bond and a hydrosilylation catalyst gives the curable composition.

摘要翻译： 本发明的目的是提供一种在不使用需要复杂的纯化步骤的金属化合物的情况下容易地制备烯基封端的乙烯基聚合物的方法，并提供含有乙烯基聚合物的可固化组合物。 将烯基末端加入至具有硫代羰硫基结构的乙烯基聚合物的末端以产生烯基封端的乙烯基聚合物。 将该乙烯基聚合物与具有氢 - 硅键和氢化硅烷化催化剂的化合物混合，得到可固化组合物。